Crystal structure of anhydrous poly[bis(μ2-sarcosinato-κ3O,N:O′)copper(II)]
The title compound, [Cu(C3H6NO2)2]n, is a bis-complex of the anion of sarcosine (N-methylglycine). The asymmetric unit consists of a copper(II) ion, located on a center of inversion, and one molecule of the uninegative sarcosinate anion. The copper(II) ion exhibits a typical Jahn–Teller distorted [4...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014-10-01
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| Series: | Acta Crystallographica Section E |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814020418 |
| _version_ | 1798017807881863168 |
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| author | Ray J. Butcher Greg Brewer Matthew Zemba |
| author_facet | Ray J. Butcher Greg Brewer Matthew Zemba |
| author_sort | Ray J. Butcher |
| collection | DOAJ |
| description | The title compound, [Cu(C3H6NO2)2]n, is a bis-complex of the anion of sarcosine (N-methylglycine). The asymmetric unit consists of a copper(II) ion, located on a center of inversion, and one molecule of the uninegative sarcosinate anion. The copper(II) ion exhibits a typical Jahn–Teller distorted [4 + 2] coordination geometry. The four shorter equatorial bonds are to the nitrogen and carboxylate O atoms of two sarcosinate anions, and the longer axial bonds are to carboxylate O atoms of neighboring complexes. The overall structure is made up from two chains formed by these longer axial Cu—O bonds, one extending parallel to [011] and the other parallel to [0-11]. Each one-dimensional array is connected by the equatorial bridging moieties to the chains on either side, creating an extended two-dimensional framework parallel to (100). There is a single intermolecular hydrogen-bonding interaction within the sheets between the amino NH group and an O atom of an adjacent molecule. |
| first_indexed | 2024-04-11T16:13:39Z |
| format | Article |
| id | doaj.art-d4e1fc208f484359ac4497ea82b90b66 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:13:39Z |
| publishDate | 2014-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-d4e1fc208f484359ac4497ea82b90b662022-12-22T04:14:37ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-10-01701020720910.1107/S1600536814020418wm5056Crystal structure of anhydrous poly[bis(μ2-sarcosinato-κ3O,N:O′)copper(II)]Ray J. Butcher0Greg Brewer1Matthew Zemba2Department of Chemistry, Howard University, 525 College Street NW, Washington, DC 20059, USADepartment of Chemistry, The Catholic University of America, 620 Michigan Ave., N.E., Washington, DC 20064, USADepartment of Chemistry, The Catholic University of America, 620 Michigan Ave., N.E., Washington, DC 20064, USAThe title compound, [Cu(C3H6NO2)2]n, is a bis-complex of the anion of sarcosine (N-methylglycine). The asymmetric unit consists of a copper(II) ion, located on a center of inversion, and one molecule of the uninegative sarcosinate anion. The copper(II) ion exhibits a typical Jahn–Teller distorted [4 + 2] coordination geometry. The four shorter equatorial bonds are to the nitrogen and carboxylate O atoms of two sarcosinate anions, and the longer axial bonds are to carboxylate O atoms of neighboring complexes. The overall structure is made up from two chains formed by these longer axial Cu—O bonds, one extending parallel to [011] and the other parallel to [0-11]. Each one-dimensional array is connected by the equatorial bridging moieties to the chains on either side, creating an extended two-dimensional framework parallel to (100). There is a single intermolecular hydrogen-bonding interaction within the sheets between the amino NH group and an O atom of an adjacent molecule.http://scripts.iucr.org/cgi-bin/paper?S1600536814020418crystal structureanhydrous bis(sarcosinato)copper(II)non-proteinogenic amino acid |
| spellingShingle | Ray J. Butcher Greg Brewer Matthew Zemba Crystal structure of anhydrous poly[bis(μ2-sarcosinato-κ3O,N:O′)copper(II)] Acta Crystallographica Section E crystal structure anhydrous bis(sarcosinato)copper(II) non-proteinogenic amino acid |
| title | Crystal structure of anhydrous poly[bis(μ2-sarcosinato-κ3O,N:O′)copper(II)] |
| title_full | Crystal structure of anhydrous poly[bis(μ2-sarcosinato-κ3O,N:O′)copper(II)] |
| title_fullStr | Crystal structure of anhydrous poly[bis(μ2-sarcosinato-κ3O,N:O′)copper(II)] |
| title_full_unstemmed | Crystal structure of anhydrous poly[bis(μ2-sarcosinato-κ3O,N:O′)copper(II)] |
| title_short | Crystal structure of anhydrous poly[bis(μ2-sarcosinato-κ3O,N:O′)copper(II)] |
| title_sort | crystal structure of anhydrous poly bis μ2 sarcosinato κ3o n o copper ii |
| topic | crystal structure anhydrous bis(sarcosinato)copper(II) non-proteinogenic amino acid |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536814020418 |
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