Hemi(4,4′-bipyridinium) hexafluoridophosphate bis(4-aminobenzoic acid) 4,4′-bipyridine monohydrate
In the title compound, 0.5C10H10N22+·PF6−·C10H8N2·2C7H7NO2·H2O, the cation is located on a center of symmetry. The crystal structure is determined by a complex three-dimensional network of intermolecular O—H...O, O—H...N, N—...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-02-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808043900 |
| _version_ | 1828143518666719232 |
|---|---|
| author | Yi-Fan Luo Rong-Hua Zeng Jie-Xuan Huang Chun-De Huang Yi-Yi Wu |
| author_facet | Yi-Fan Luo Rong-Hua Zeng Jie-Xuan Huang Chun-De Huang Yi-Yi Wu |
| author_sort | Yi-Fan Luo |
| collection | DOAJ |
| description | In the title compound, 0.5C10H10N22+·PF6−·C10H8N2·2C7H7NO2·H2O, the cation is located on a center of symmetry. The crystal structure is determined by a complex three-dimensional network of intermolecular O—H...O, O—H...N, N—H...N and N—H...F hydrogen bonds. π–π stacking interactions between neighboring pyridyl rings are also present; the centroid–centroid distance is 3.643 (5) Å. The hexafluoridophosphate anion is disordered over two positions with site-occupancy factors of ca 0.6 and 0.4. |
| first_indexed | 2024-04-11T19:58:32Z |
| format | Article |
| id | doaj.art-d5267cc9862c4167b5a4c665b3ad807b |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T19:58:32Z |
| publishDate | 2009-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-d5267cc9862c4167b5a4c665b3ad807b2022-12-22T04:05:50ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-02-01652o278o27810.1107/S1600536808043900Hemi(4,4′-bipyridinium) hexafluoridophosphate bis(4-aminobenzoic acid) 4,4′-bipyridine monohydrateYi-Fan LuoRong-Hua ZengJie-Xuan HuangChun-De HuangYi-Yi WuIn the title compound, 0.5C10H10N22+·PF6−·C10H8N2·2C7H7NO2·H2O, the cation is located on a center of symmetry. The crystal structure is determined by a complex three-dimensional network of intermolecular O—H...O, O—H...N, N—H...N and N—H...F hydrogen bonds. π–π stacking interactions between neighboring pyridyl rings are also present; the centroid–centroid distance is 3.643 (5) Å. The hexafluoridophosphate anion is disordered over two positions with site-occupancy factors of ca 0.6 and 0.4.http://scripts.iucr.org/cgi-bin/paper?S1600536808043900 |
| spellingShingle | Yi-Fan Luo Rong-Hua Zeng Jie-Xuan Huang Chun-De Huang Yi-Yi Wu Hemi(4,4′-bipyridinium) hexafluoridophosphate bis(4-aminobenzoic acid) 4,4′-bipyridine monohydrate Acta Crystallographica Section E |
| title | Hemi(4,4′-bipyridinium) hexafluoridophosphate bis(4-aminobenzoic acid) 4,4′-bipyridine monohydrate |
| title_full | Hemi(4,4′-bipyridinium) hexafluoridophosphate bis(4-aminobenzoic acid) 4,4′-bipyridine monohydrate |
| title_fullStr | Hemi(4,4′-bipyridinium) hexafluoridophosphate bis(4-aminobenzoic acid) 4,4′-bipyridine monohydrate |
| title_full_unstemmed | Hemi(4,4′-bipyridinium) hexafluoridophosphate bis(4-aminobenzoic acid) 4,4′-bipyridine monohydrate |
| title_short | Hemi(4,4′-bipyridinium) hexafluoridophosphate bis(4-aminobenzoic acid) 4,4′-bipyridine monohydrate |
| title_sort | hemi 4 4 8242 bipyridinium hexafluoridophosphate bis 4 aminobenzoic acid 4 4 8242 bipyridine monohydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808043900 |
| work_keys_str_mv | AT yifanluo hemi448242bipyridiniumhexafluoridophosphatebis4aminobenzoicacid448242bipyridinemonohydrate AT ronghuazeng hemi448242bipyridiniumhexafluoridophosphatebis4aminobenzoicacid448242bipyridinemonohydrate AT jiexuanhuang hemi448242bipyridiniumhexafluoridophosphatebis4aminobenzoicacid448242bipyridinemonohydrate AT chundehuang hemi448242bipyridiniumhexafluoridophosphatebis4aminobenzoicacid448242bipyridinemonohydrate AT yiyiwu hemi448242bipyridiniumhexafluoridophosphatebis4aminobenzoicacid448242bipyridinemonohydrate |