Formation potentiality and source apportionment analysis of secondary organic aerosol in urban and suburban area, Thailand

Ambient volatile organic compounds (VOCs) concentrations measured in Bangkok and its suburb in Thailand were estimated for their secondary organic aerosol formation potential (SOAP) to elucidate the major compounds contributing to the formation of secondary fine particulates. VOCs were collected t...

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Main Authors: Lalidaporn Punya, Sarawut Thepanondh, Suphaphat Kwonpongsagoon, Wanna Laowagul, Nuttakit Sukjit, Pattaranan Hanma
Format: Article
Language:English
Published: Prince of Songkla University 2022-02-01
Series:Songklanakarin Journal of Science and Technology (SJST)
Subjects:
Online Access:https://rdo.psu.ac.th/sjst/journal/44-1/28.pdf
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author Lalidaporn Punya
Sarawut Thepanondh
Suphaphat Kwonpongsagoon
Wanna Laowagul
Nuttakit Sukjit
Pattaranan Hanma
author_facet Lalidaporn Punya
Sarawut Thepanondh
Suphaphat Kwonpongsagoon
Wanna Laowagul
Nuttakit Sukjit
Pattaranan Hanma
author_sort Lalidaporn Punya
collection DOAJ
description Ambient volatile organic compounds (VOCs) concentrations measured in Bangkok and its suburb in Thailand were estimated for their secondary organic aerosol formation potential (SOAP) to elucidate the major compounds contributing to the formation of secondary fine particulates. VOCs were collected to evacuated canisters and analyzed by Gas Chromatography - Mass Spectrophotometer (GC-MS) in accordance with US-EPA TO15. Measured data from January 2013 to December 2019 were used in this study. The results indicate that the top five species of VOCs contributing to SOAP were toluene (66-54%), m- ,p-xylene (11-7%), ethylbenzene (9-8%), benzene (12-5%), o-xylene (5-4%) and styrene (9-4%), in rank order. These VOCs accounted for more than 90 % of total SOAP. Positive Matrix Factorization (PMF) was then used to identify the potential emission sources of these compounds. The results clearly indicated a high contribution from mobile sources at roadside monitoring stations. As for the suburban area, most of the total VOC concentrations were from mobile source emissions, chemical use in the households, and open burning. The results of this study highlight the necessity to control these emission groups to reduce the formation potentiality of secondary organic aerosols and PM2.5 pollution.
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spelling doaj.art-d52ec485a5d6418091b96709cac2952c2022-12-22T00:37:12ZengPrince of Songkla UniversitySongklanakarin Journal of Science and Technology (SJST)0125-33952022-02-0144119120010.14456/sjst-psu.2022.28Formation potentiality and source apportionment analysis of secondary organic aerosol in urban and suburban area, ThailandLalidaporn Punya0Sarawut Thepanondh1Suphaphat Kwonpongsagoon2Wanna Laowagul3Nuttakit SukjitPattaranan Hanma4Department of Sanitary Engineering, Faculty of Public Health, Mahidol University, Ratchathewi, Bangkok, 10400 ThailandDepartment of Sanitary Engineering, Faculty of Public Health, Mahidol University, Ratchathewi, Bangkok, 10400 ThailandDepartment of Sanitary Engineering, Faculty of Public Health, Mahidol University, Ratchathewi, Bangkok, 10400 ThailandEnvironmental Research and Training Center, Department of Environmental Quality Promotion, Ministry of Natural Resources and Environment, Khlong Luang, Pathum Thani, 12120 ThailandDepartment of Sanitary Engineering, Faculty of Public Health, Mahidol University, Ratchathewi, Bangkok, 10400 ThailandAmbient volatile organic compounds (VOCs) concentrations measured in Bangkok and its suburb in Thailand were estimated for their secondary organic aerosol formation potential (SOAP) to elucidate the major compounds contributing to the formation of secondary fine particulates. VOCs were collected to evacuated canisters and analyzed by Gas Chromatography - Mass Spectrophotometer (GC-MS) in accordance with US-EPA TO15. Measured data from January 2013 to December 2019 were used in this study. The results indicate that the top five species of VOCs contributing to SOAP were toluene (66-54%), m- ,p-xylene (11-7%), ethylbenzene (9-8%), benzene (12-5%), o-xylene (5-4%) and styrene (9-4%), in rank order. These VOCs accounted for more than 90 % of total SOAP. Positive Matrix Factorization (PMF) was then used to identify the potential emission sources of these compounds. The results clearly indicated a high contribution from mobile sources at roadside monitoring stations. As for the suburban area, most of the total VOC concentrations were from mobile source emissions, chemical use in the households, and open burning. The results of this study highlight the necessity to control these emission groups to reduce the formation potentiality of secondary organic aerosols and PM2.5 pollution.https://rdo.psu.ac.th/sjst/journal/44-1/28.pdfvolatile organic compoundsecondary organic aerosol formationpositive matrix factorizationreceptor oriented modelair pollution
spellingShingle Lalidaporn Punya
Sarawut Thepanondh
Suphaphat Kwonpongsagoon
Wanna Laowagul
Nuttakit Sukjit
Pattaranan Hanma
Formation potentiality and source apportionment analysis of secondary organic aerosol in urban and suburban area, Thailand
Songklanakarin Journal of Science and Technology (SJST)
volatile organic compound
secondary organic aerosol formation
positive matrix factorization
receptor oriented model
air pollution
title Formation potentiality and source apportionment analysis of secondary organic aerosol in urban and suburban area, Thailand
title_full Formation potentiality and source apportionment analysis of secondary organic aerosol in urban and suburban area, Thailand
title_fullStr Formation potentiality and source apportionment analysis of secondary organic aerosol in urban and suburban area, Thailand
title_full_unstemmed Formation potentiality and source apportionment analysis of secondary organic aerosol in urban and suburban area, Thailand
title_short Formation potentiality and source apportionment analysis of secondary organic aerosol in urban and suburban area, Thailand
title_sort formation potentiality and source apportionment analysis of secondary organic aerosol in urban and suburban area thailand
topic volatile organic compound
secondary organic aerosol formation
positive matrix factorization
receptor oriented model
air pollution
url https://rdo.psu.ac.th/sjst/journal/44-1/28.pdf
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