A Case Study of Landfill Leachate Using Coal Bottom Ash for the Removal of Cd2+, Zn2+ and Ni2+

The removal of Cd2+, Zn2+ and Ni2+ by coal bottom ash has been investigated. In single metal system, metal uptake was studied in batch adsorption experiments as a function of pH (2–3), contact time (5–180 min), initial metal concentration (50–400 mg/L), adsorbent concentration (5–40 g/L), particle s...

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Main Authors: Julia Ayala, Begoña Fernández
Format: Article
Language:English
Published: MDPI AG 2016-11-01
Series:Metals
Subjects:
Online Access:http://www.mdpi.com/2075-4701/6/12/300
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author Julia Ayala
Begoña Fernández
author_facet Julia Ayala
Begoña Fernández
author_sort Julia Ayala
collection DOAJ
description The removal of Cd2+, Zn2+ and Ni2+ by coal bottom ash has been investigated. In single metal system, metal uptake was studied in batch adsorption experiments as a function of pH (2–3), contact time (5–180 min), initial metal concentration (50–400 mg/L), adsorbent concentration (5–40 g/L), particle size, and ionic strength (0–1 M NaCl). Removal percentages of metals ions increased with increasing pH and dosage. Removal efficiency at lower concentrations was greater than at higher values. The maximum amount of metal ion adsorbed in milligrams per gram was 35.4, 35.1 and 34.6 mg/g for Zn2+, Cd2+ and Ni2+, respectively, starting out from an initial solution at pH 3. Simultaneous removal of Zn2+, Cd2+ and Ni2+ ions from ternary systems was also investigated and compared with that from single systems. Cd2+ uptake was significantly affected by the presence of competing ions at pH 2. The results obtained in the tests with landfill leachate showed that bottom ash is effective in simultaneously removing several heavy metals such as Ni, Zn, Cd, As, Mn, Cu, Co, Se, Hg, Ag, and Pb.
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spelling doaj.art-d54c6c2e0bcd411c9a2715630017c48f2022-12-22T03:51:10ZengMDPI AGMetals2075-47012016-11-0161230010.3390/met6120300met6120300A Case Study of Landfill Leachate Using Coal Bottom Ash for the Removal of Cd2+, Zn2+ and Ni2+Julia Ayala0Begoña Fernández1Laboratorio de Metalurgia, Escuela de Minas Energía y Materiales, Universidad de Oviedo, Independencia 13, 33004 Oviedo, SpainLaboratorio de Metalurgia, Escuela de Minas Energía y Materiales, Universidad de Oviedo, Independencia 13, 33004 Oviedo, SpainThe removal of Cd2+, Zn2+ and Ni2+ by coal bottom ash has been investigated. In single metal system, metal uptake was studied in batch adsorption experiments as a function of pH (2–3), contact time (5–180 min), initial metal concentration (50–400 mg/L), adsorbent concentration (5–40 g/L), particle size, and ionic strength (0–1 M NaCl). Removal percentages of metals ions increased with increasing pH and dosage. Removal efficiency at lower concentrations was greater than at higher values. The maximum amount of metal ion adsorbed in milligrams per gram was 35.4, 35.1 and 34.6 mg/g for Zn2+, Cd2+ and Ni2+, respectively, starting out from an initial solution at pH 3. Simultaneous removal of Zn2+, Cd2+ and Ni2+ ions from ternary systems was also investigated and compared with that from single systems. Cd2+ uptake was significantly affected by the presence of competing ions at pH 2. The results obtained in the tests with landfill leachate showed that bottom ash is effective in simultaneously removing several heavy metals such as Ni, Zn, Cd, As, Mn, Cu, Co, Se, Hg, Ag, and Pb.http://www.mdpi.com/2075-4701/6/12/300bottom ashheavy metalremovallandfill leachatewastewater treatment
spellingShingle Julia Ayala
Begoña Fernández
A Case Study of Landfill Leachate Using Coal Bottom Ash for the Removal of Cd2+, Zn2+ and Ni2+
Metals
bottom ash
heavy metal
removal
landfill leachate
wastewater treatment
title A Case Study of Landfill Leachate Using Coal Bottom Ash for the Removal of Cd2+, Zn2+ and Ni2+
title_full A Case Study of Landfill Leachate Using Coal Bottom Ash for the Removal of Cd2+, Zn2+ and Ni2+
title_fullStr A Case Study of Landfill Leachate Using Coal Bottom Ash for the Removal of Cd2+, Zn2+ and Ni2+
title_full_unstemmed A Case Study of Landfill Leachate Using Coal Bottom Ash for the Removal of Cd2+, Zn2+ and Ni2+
title_short A Case Study of Landfill Leachate Using Coal Bottom Ash for the Removal of Cd2+, Zn2+ and Ni2+
title_sort case study of landfill leachate using coal bottom ash for the removal of cd2 zn2 and ni2
topic bottom ash
heavy metal
removal
landfill leachate
wastewater treatment
url http://www.mdpi.com/2075-4701/6/12/300
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