The ways to form midi-fullerens structure exemplified by С22, С24 and С26 isomers
In this paper, the possible ways of forming the midi-fullerene isomers, namely C22, C24 and C26, have been systematized. Three simplest mechanisms for their synthesizing are known. They are the fusion of carbon cupolas having the same symmetry; the fusion of fullerenes having compatible symmetry; em...
| Main Author: | |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Peter the Great St.Petersburg Polytechnic University
2023-03-01
|
| Series: | St. Petersburg Polytechnical University Journal: Physics and Mathematics |
| Subjects: | |
| Online Access: | https://physmath.spbstu.ru/article/2023.62.10/ |
| _version_ | 1797846582684549120 |
|---|---|
| author | Matvienko Aleksandra |
| author_facet | Matvienko Aleksandra |
| author_sort | Matvienko Aleksandra |
| collection | DOAJ |
| description | In this paper, the possible ways of forming the midi-fullerene isomers, namely C22, C24 and C26, have been systematized. Three simplest mechanisms for their synthesizing are known. They are the fusion of carbon cupolas having the same symmetry; the fusion of fullerenes having compatible symmetry; embedding carbon dimers into initial fullerenes. The structures with minimal energy were formed through the use of the third mechanism retaining the topological three-fold symmetry. The symmetry order of studied fullerenes changed from the third to the sixth. The geometric modeling carried out in conjunction with the analysis of structures’ formation energies gives researchers a clear idea of the structure of the resulting fullerenes. |
| first_indexed | 2024-04-09T17:57:19Z |
| format | Article |
| id | doaj.art-d562e5aaf52c4e1e817182de46c13303 |
| institution | Directory Open Access Journal |
| issn | 2405-7223 |
| language | English |
| last_indexed | 2024-04-09T17:57:19Z |
| publishDate | 2023-03-01 |
| publisher | Peter the Great St.Petersburg Polytechnic University |
| record_format | Article |
| series | St. Petersburg Polytechnical University Journal: Physics and Mathematics |
| spelling | doaj.art-d562e5aaf52c4e1e817182de46c133032023-04-14T16:17:48ZengPeter the Great St.Petersburg Polytechnic UniversitySt. Petersburg Polytechnical University Journal: Physics and Mathematics2405-72232023-03-0116110.18721/JPM.1611020714726The ways to form midi-fullerens structure exemplified by С22, С24 and С26 isomersMatvienko Aleksandra0https://orcid.org/0000-0002-3012-1407Peter the Great St. Petersburg Polytechnic UniversityIn this paper, the possible ways of forming the midi-fullerene isomers, namely C22, C24 and C26, have been systematized. Three simplest mechanisms for their synthesizing are known. They are the fusion of carbon cupolas having the same symmetry; the fusion of fullerenes having compatible symmetry; embedding carbon dimers into initial fullerenes. The structures with minimal energy were formed through the use of the third mechanism retaining the topological three-fold symmetry. The symmetry order of studied fullerenes changed from the third to the sixth. The geometric modeling carried out in conjunction with the analysis of structures’ formation energies gives researchers a clear idea of the structure of the resulting fullerenes.https://physmath.spbstu.ru/article/2023.62.10/isomerperiodic systemfusion reactiongrowthfullereneenergy |
| spellingShingle | Matvienko Aleksandra The ways to form midi-fullerens structure exemplified by С22, С24 and С26 isomers St. Petersburg Polytechnical University Journal: Physics and Mathematics isomer periodic system fusion reaction growth fullerene energy |
| title | The ways to form midi-fullerens structure exemplified by С22, С24 and С26 isomers |
| title_full | The ways to form midi-fullerens structure exemplified by С22, С24 and С26 isomers |
| title_fullStr | The ways to form midi-fullerens structure exemplified by С22, С24 and С26 isomers |
| title_full_unstemmed | The ways to form midi-fullerens structure exemplified by С22, С24 and С26 isomers |
| title_short | The ways to form midi-fullerens structure exemplified by С22, С24 and С26 isomers |
| title_sort | ways to form midi fullerens structure exemplified by с22 с24 and с26 isomers |
| topic | isomer periodic system fusion reaction growth fullerene energy |
| url | https://physmath.spbstu.ru/article/2023.62.10/ |
| work_keys_str_mv | AT matvienkoaleksandra thewaystoformmidifullerensstructureexemplifiedbys22s24ands26isomers AT matvienkoaleksandra waystoformmidifullerensstructureexemplifiedbys22s24ands26isomers |