Fabrication of Needle-Like Silicon Nanowires by Using a Nanoparticles-Assisted Bosch Process for Both High Hydrophobicity and Anti-Reflection

In this work, a modified Bosch etching process is developed to create silicon nanowires. Au nanoparticles (NPs) formed by magnetron sputtering film deposition and thermal annealing were employed as the hard mask to achieve controllable density and high aspect ratios. Such silicon nanowire exhibits t...

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Main Authors: Zengxing Zhang, Guohua Liu, Kaiying Wang
Format: Article
Language:English
Published: MDPI AG 2021-08-01
Series:Micromachines
Subjects:
Online Access:https://www.mdpi.com/2072-666X/12/9/1009
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author Zengxing Zhang
Guohua Liu
Kaiying Wang
author_facet Zengxing Zhang
Guohua Liu
Kaiying Wang
author_sort Zengxing Zhang
collection DOAJ
description In this work, a modified Bosch etching process is developed to create silicon nanowires. Au nanoparticles (NPs) formed by magnetron sputtering film deposition and thermal annealing were employed as the hard mask to achieve controllable density and high aspect ratios. Such silicon nanowire exhibits the excellent anti-reflection ability of a reflectance value of below 2% within a broad light wave range between 220 and 1100 nm. In addition, Au NPs-induced surface plasmons significantly enhance the near-unity anti-reflection characteristics, achieving a reflectance below 3% within the wavelength range of 220 to 2600 nm. Furthermore, the nanowire array exhibits super-hydrophobic behavior with a contact angle over ~165.6° without enforcing any hydrophobic chemical treatment. Such behavior yields in water droplets bouncing off the surface many times. These properties render this silicon nanowire attractive for applications such as photothermal, photocatalysis, supercapacitor, and microfluidics.
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spelling doaj.art-d56b3e4c27b74183987681b57275a7af2023-11-22T14:15:12ZengMDPI AGMicromachines2072-666X2021-08-01129100910.3390/mi12091009Fabrication of Needle-Like Silicon Nanowires by Using a Nanoparticles-Assisted Bosch Process for Both High Hydrophobicity and Anti-ReflectionZengxing Zhang0Guohua Liu1Kaiying Wang2Department of microsystems, University of South-Eastern Norway, 3184 Horten, NorwayBeijing Key Laboratory of Multiphase Flow and Heat Transfer for Low Grade Energy Utilization, North China Electric Power University, Beijing 102206, ChinaDepartment of microsystems, University of South-Eastern Norway, 3184 Horten, NorwayIn this work, a modified Bosch etching process is developed to create silicon nanowires. Au nanoparticles (NPs) formed by magnetron sputtering film deposition and thermal annealing were employed as the hard mask to achieve controllable density and high aspect ratios. Such silicon nanowire exhibits the excellent anti-reflection ability of a reflectance value of below 2% within a broad light wave range between 220 and 1100 nm. In addition, Au NPs-induced surface plasmons significantly enhance the near-unity anti-reflection characteristics, achieving a reflectance below 3% within the wavelength range of 220 to 2600 nm. Furthermore, the nanowire array exhibits super-hydrophobic behavior with a contact angle over ~165.6° without enforcing any hydrophobic chemical treatment. Such behavior yields in water droplets bouncing off the surface many times. These properties render this silicon nanowire attractive for applications such as photothermal, photocatalysis, supercapacitor, and microfluidics.https://www.mdpi.com/2072-666X/12/9/1009silicon nanowiresnanoparticlesBosch processanti-reflectionhydrophobicity
spellingShingle Zengxing Zhang
Guohua Liu
Kaiying Wang
Fabrication of Needle-Like Silicon Nanowires by Using a Nanoparticles-Assisted Bosch Process for Both High Hydrophobicity and Anti-Reflection
Micromachines
silicon nanowires
nanoparticles
Bosch process
anti-reflection
hydrophobicity
title Fabrication of Needle-Like Silicon Nanowires by Using a Nanoparticles-Assisted Bosch Process for Both High Hydrophobicity and Anti-Reflection
title_full Fabrication of Needle-Like Silicon Nanowires by Using a Nanoparticles-Assisted Bosch Process for Both High Hydrophobicity and Anti-Reflection
title_fullStr Fabrication of Needle-Like Silicon Nanowires by Using a Nanoparticles-Assisted Bosch Process for Both High Hydrophobicity and Anti-Reflection
title_full_unstemmed Fabrication of Needle-Like Silicon Nanowires by Using a Nanoparticles-Assisted Bosch Process for Both High Hydrophobicity and Anti-Reflection
title_short Fabrication of Needle-Like Silicon Nanowires by Using a Nanoparticles-Assisted Bosch Process for Both High Hydrophobicity and Anti-Reflection
title_sort fabrication of needle like silicon nanowires by using a nanoparticles assisted bosch process for both high hydrophobicity and anti reflection
topic silicon nanowires
nanoparticles
Bosch process
anti-reflection
hydrophobicity
url https://www.mdpi.com/2072-666X/12/9/1009
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AT guohualiu fabricationofneedlelikesiliconnanowiresbyusingananoparticlesassistedboschprocessforbothhighhydrophobicityandantireflection
AT kaiyingwang fabricationofneedlelikesiliconnanowiresbyusingananoparticlesassistedboschprocessforbothhighhydrophobicityandantireflection