Development of a Sustainable Metallurgical Process to Valorize Copper Smelting Wastes with Olive Stones-Based Biochar

Flue dust waste coming from a copper (Cu) smelting company has been valorized using a newly developed metallurgical process with the aim of recovering a dust concentrated in valuable metals, such as lead (Pb) and zinc (Zn), and studying the feasibility of replacing anthracite with biochar as reducin...

全面介绍

书目详细资料
Main Authors: Aitziber Adrados, Mikel Merchán, Alejandro Obregón, Antxon Artola, Jon Ander Iparraguirre, Maider García de Cortázar, David Eguizabal, Hary Demey
格式: 文件
语言:English
出版: MDPI AG 2022-10-01
丛编:Metals
主题:
在线阅读:https://www.mdpi.com/2075-4701/12/10/1756
_version_ 1827648847133802496
author Aitziber Adrados
Mikel Merchán
Alejandro Obregón
Antxon Artola
Jon Ander Iparraguirre
Maider García de Cortázar
David Eguizabal
Hary Demey
author_facet Aitziber Adrados
Mikel Merchán
Alejandro Obregón
Antxon Artola
Jon Ander Iparraguirre
Maider García de Cortázar
David Eguizabal
Hary Demey
author_sort Aitziber Adrados
collection DOAJ
description Flue dust waste coming from a copper (Cu) smelting company has been valorized using a newly developed metallurgical process with the aim of recovering a dust concentrated in valuable metals, such as lead (Pb) and zinc (Zn), and studying the feasibility of replacing anthracite with biochar as reducing agent. Metallurgical trials using different mixtures of reducing agents have been performed in a furnace at 1400 °C. This furnace employs a high-power thermal plasma (HPTP) system as energy source. Using copper as the base metal, pellets containing a mixture of the waste, different reducing agents, and binder were introduced into the furnace for their dissolution. Recovery yields in the range of 45–85 wt.% for Pb and Zn were obtained in the flue dusts. All the trials proved the effectiveness of the developed process to enrich the flue dusts in valuable metals, including those only using biochar as reducing agent. Further trials will be carried out in order to better control the parameters involved in the metallurgical process developed and improve its efficiency.
first_indexed 2024-03-09T19:47:41Z
format Article
id doaj.art-d587c146411143c38e24ec03041c799b
institution Directory Open Access Journal
issn 2075-4701
language English
last_indexed 2024-03-09T19:47:41Z
publishDate 2022-10-01
publisher MDPI AG
record_format Article
series Metals
spelling doaj.art-d587c146411143c38e24ec03041c799b2023-11-24T01:20:14ZengMDPI AGMetals2075-47012022-10-011210175610.3390/met12101756Development of a Sustainable Metallurgical Process to Valorize Copper Smelting Wastes with Olive Stones-Based BiocharAitziber Adrados0Mikel Merchán1Alejandro Obregón2Antxon Artola3Jon Ander Iparraguirre4Maider García de Cortázar5David Eguizabal6Hary Demey7Tecnalia, Basque Research and Technology Alliance (BRTA), Parque Científico y Tecnológico de Bizkaia, Astondo Bidea 700, 48160 Derio, SpainTecnalia, Basque Research and Technology Alliance (BRTA), Parque Científico y Tecnológico de Bizkaia, Astondo Bidea 700, 48160 Derio, SpainTecnalia, Basque Research and Technology Alliance (BRTA), Parque Científico y Tecnológico de Bizkaia, Astondo Bidea 700, 48160 Derio, SpainTecnalia, Basque Research and Technology Alliance (BRTA), Parque Científico y Tecnológico de Bizkaia, Astondo Bidea 700, 48160 Derio, SpainTecnalia, Basque Research and Technology Alliance (BRTA), Parque Científico y Tecnológico de Bizkaia, Astondo Bidea 700, 48160 Derio, SpainTecnalia, Basque Research and Technology Alliance (BRTA), Parque Científico y Tecnológico de Bizkaia, Astondo Bidea 700, 48160 Derio, SpainDIGIMET 2013 S.L., Industrialdea Ventas, Gabiria Kalea 82-84, 20305 Irún, SpainLaboratoire Réacteurs et Procédés (LRP), Département Thermique Conversion et Hydrogène (DTCH), LITEN, CEA, University Grenoble Alpes, F-38000 Grenoble, FranceFlue dust waste coming from a copper (Cu) smelting company has been valorized using a newly developed metallurgical process with the aim of recovering a dust concentrated in valuable metals, such as lead (Pb) and zinc (Zn), and studying the feasibility of replacing anthracite with biochar as reducing agent. Metallurgical trials using different mixtures of reducing agents have been performed in a furnace at 1400 °C. This furnace employs a high-power thermal plasma (HPTP) system as energy source. Using copper as the base metal, pellets containing a mixture of the waste, different reducing agents, and binder were introduced into the furnace for their dissolution. Recovery yields in the range of 45–85 wt.% for Pb and Zn were obtained in the flue dusts. All the trials proved the effectiveness of the developed process to enrich the flue dusts in valuable metals, including those only using biochar as reducing agent. Further trials will be carried out in order to better control the parameters involved in the metallurgical process developed and improve its efficiency.https://www.mdpi.com/2075-4701/12/10/1756biocharolive stonesreducing agentmetal recoverywaste valorizationpyrometallurgy
spellingShingle Aitziber Adrados
Mikel Merchán
Alejandro Obregón
Antxon Artola
Jon Ander Iparraguirre
Maider García de Cortázar
David Eguizabal
Hary Demey
Development of a Sustainable Metallurgical Process to Valorize Copper Smelting Wastes with Olive Stones-Based Biochar
Metals
biochar
olive stones
reducing agent
metal recovery
waste valorization
pyrometallurgy
title Development of a Sustainable Metallurgical Process to Valorize Copper Smelting Wastes with Olive Stones-Based Biochar
title_full Development of a Sustainable Metallurgical Process to Valorize Copper Smelting Wastes with Olive Stones-Based Biochar
title_fullStr Development of a Sustainable Metallurgical Process to Valorize Copper Smelting Wastes with Olive Stones-Based Biochar
title_full_unstemmed Development of a Sustainable Metallurgical Process to Valorize Copper Smelting Wastes with Olive Stones-Based Biochar
title_short Development of a Sustainable Metallurgical Process to Valorize Copper Smelting Wastes with Olive Stones-Based Biochar
title_sort development of a sustainable metallurgical process to valorize copper smelting wastes with olive stones based biochar
topic biochar
olive stones
reducing agent
metal recovery
waste valorization
pyrometallurgy
url https://www.mdpi.com/2075-4701/12/10/1756
work_keys_str_mv AT aitziberadrados developmentofasustainablemetallurgicalprocesstovalorizecoppersmeltingwasteswitholivestonesbasedbiochar
AT mikelmerchan developmentofasustainablemetallurgicalprocesstovalorizecoppersmeltingwasteswitholivestonesbasedbiochar
AT alejandroobregon developmentofasustainablemetallurgicalprocesstovalorizecoppersmeltingwasteswitholivestonesbasedbiochar
AT antxonartola developmentofasustainablemetallurgicalprocesstovalorizecoppersmeltingwasteswitholivestonesbasedbiochar
AT jonanderiparraguirre developmentofasustainablemetallurgicalprocesstovalorizecoppersmeltingwasteswitholivestonesbasedbiochar
AT maidergarciadecortazar developmentofasustainablemetallurgicalprocesstovalorizecoppersmeltingwasteswitholivestonesbasedbiochar
AT davideguizabal developmentofasustainablemetallurgicalprocesstovalorizecoppersmeltingwasteswitholivestonesbasedbiochar
AT harydemey developmentofasustainablemetallurgicalprocesstovalorizecoppersmeltingwasteswitholivestonesbasedbiochar