Development of a Sustainable Metallurgical Process to Valorize Copper Smelting Wastes with Olive Stones-Based Biochar
Flue dust waste coming from a copper (Cu) smelting company has been valorized using a newly developed metallurgical process with the aim of recovering a dust concentrated in valuable metals, such as lead (Pb) and zinc (Zn), and studying the feasibility of replacing anthracite with biochar as reducin...
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MDPI AG
2022-10-01
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在线阅读: | https://www.mdpi.com/2075-4701/12/10/1756 |
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author | Aitziber Adrados Mikel Merchán Alejandro Obregón Antxon Artola Jon Ander Iparraguirre Maider García de Cortázar David Eguizabal Hary Demey |
author_facet | Aitziber Adrados Mikel Merchán Alejandro Obregón Antxon Artola Jon Ander Iparraguirre Maider García de Cortázar David Eguizabal Hary Demey |
author_sort | Aitziber Adrados |
collection | DOAJ |
description | Flue dust waste coming from a copper (Cu) smelting company has been valorized using a newly developed metallurgical process with the aim of recovering a dust concentrated in valuable metals, such as lead (Pb) and zinc (Zn), and studying the feasibility of replacing anthracite with biochar as reducing agent. Metallurgical trials using different mixtures of reducing agents have been performed in a furnace at 1400 °C. This furnace employs a high-power thermal plasma (HPTP) system as energy source. Using copper as the base metal, pellets containing a mixture of the waste, different reducing agents, and binder were introduced into the furnace for their dissolution. Recovery yields in the range of 45–85 wt.% for Pb and Zn were obtained in the flue dusts. All the trials proved the effectiveness of the developed process to enrich the flue dusts in valuable metals, including those only using biochar as reducing agent. Further trials will be carried out in order to better control the parameters involved in the metallurgical process developed and improve its efficiency. |
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institution | Directory Open Access Journal |
issn | 2075-4701 |
language | English |
last_indexed | 2024-03-09T19:47:41Z |
publishDate | 2022-10-01 |
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series | Metals |
spelling | doaj.art-d587c146411143c38e24ec03041c799b2023-11-24T01:20:14ZengMDPI AGMetals2075-47012022-10-011210175610.3390/met12101756Development of a Sustainable Metallurgical Process to Valorize Copper Smelting Wastes with Olive Stones-Based BiocharAitziber Adrados0Mikel Merchán1Alejandro Obregón2Antxon Artola3Jon Ander Iparraguirre4Maider García de Cortázar5David Eguizabal6Hary Demey7Tecnalia, Basque Research and Technology Alliance (BRTA), Parque Científico y Tecnológico de Bizkaia, Astondo Bidea 700, 48160 Derio, SpainTecnalia, Basque Research and Technology Alliance (BRTA), Parque Científico y Tecnológico de Bizkaia, Astondo Bidea 700, 48160 Derio, SpainTecnalia, Basque Research and Technology Alliance (BRTA), Parque Científico y Tecnológico de Bizkaia, Astondo Bidea 700, 48160 Derio, SpainTecnalia, Basque Research and Technology Alliance (BRTA), Parque Científico y Tecnológico de Bizkaia, Astondo Bidea 700, 48160 Derio, SpainTecnalia, Basque Research and Technology Alliance (BRTA), Parque Científico y Tecnológico de Bizkaia, Astondo Bidea 700, 48160 Derio, SpainTecnalia, Basque Research and Technology Alliance (BRTA), Parque Científico y Tecnológico de Bizkaia, Astondo Bidea 700, 48160 Derio, SpainDIGIMET 2013 S.L., Industrialdea Ventas, Gabiria Kalea 82-84, 20305 Irún, SpainLaboratoire Réacteurs et Procédés (LRP), Département Thermique Conversion et Hydrogène (DTCH), LITEN, CEA, University Grenoble Alpes, F-38000 Grenoble, FranceFlue dust waste coming from a copper (Cu) smelting company has been valorized using a newly developed metallurgical process with the aim of recovering a dust concentrated in valuable metals, such as lead (Pb) and zinc (Zn), and studying the feasibility of replacing anthracite with biochar as reducing agent. Metallurgical trials using different mixtures of reducing agents have been performed in a furnace at 1400 °C. This furnace employs a high-power thermal plasma (HPTP) system as energy source. Using copper as the base metal, pellets containing a mixture of the waste, different reducing agents, and binder were introduced into the furnace for their dissolution. Recovery yields in the range of 45–85 wt.% for Pb and Zn were obtained in the flue dusts. All the trials proved the effectiveness of the developed process to enrich the flue dusts in valuable metals, including those only using biochar as reducing agent. Further trials will be carried out in order to better control the parameters involved in the metallurgical process developed and improve its efficiency.https://www.mdpi.com/2075-4701/12/10/1756biocharolive stonesreducing agentmetal recoverywaste valorizationpyrometallurgy |
spellingShingle | Aitziber Adrados Mikel Merchán Alejandro Obregón Antxon Artola Jon Ander Iparraguirre Maider García de Cortázar David Eguizabal Hary Demey Development of a Sustainable Metallurgical Process to Valorize Copper Smelting Wastes with Olive Stones-Based Biochar Metals biochar olive stones reducing agent metal recovery waste valorization pyrometallurgy |
title | Development of a Sustainable Metallurgical Process to Valorize Copper Smelting Wastes with Olive Stones-Based Biochar |
title_full | Development of a Sustainable Metallurgical Process to Valorize Copper Smelting Wastes with Olive Stones-Based Biochar |
title_fullStr | Development of a Sustainable Metallurgical Process to Valorize Copper Smelting Wastes with Olive Stones-Based Biochar |
title_full_unstemmed | Development of a Sustainable Metallurgical Process to Valorize Copper Smelting Wastes with Olive Stones-Based Biochar |
title_short | Development of a Sustainable Metallurgical Process to Valorize Copper Smelting Wastes with Olive Stones-Based Biochar |
title_sort | development of a sustainable metallurgical process to valorize copper smelting wastes with olive stones based biochar |
topic | biochar olive stones reducing agent metal recovery waste valorization pyrometallurgy |
url | https://www.mdpi.com/2075-4701/12/10/1756 |
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