Effect of Trace Elements on the Crystallization Temperature Interval and Properties of 5xxx Series Aluminum Alloys

The influence of alloying elements Er, Zr, Cu, Si and Zn on the crystallization temperature interval, microstructure, mechanical properties and corrosion behavior of Al-Mg-Mn alloy were studied by differential scanning calorimetry (DSC), electron backscatter diffraction (EBSD), X-ray diffraction (XR...

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Main Authors: Qianqian Li, Mengjia Li, Guangxi Lu, Shaokang Guan, Engui Zhang, Cong Xu
Format: Article
Language:English
Published: MDPI AG 2020-04-01
Series:Metals
Subjects:
Online Access:https://www.mdpi.com/2075-4701/10/4/483
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author Qianqian Li
Mengjia Li
Guangxi Lu
Shaokang Guan
Engui Zhang
Cong Xu
author_facet Qianqian Li
Mengjia Li
Guangxi Lu
Shaokang Guan
Engui Zhang
Cong Xu
author_sort Qianqian Li
collection DOAJ
description The influence of alloying elements Er, Zr, Cu, Si and Zn on the crystallization temperature interval, microstructure, mechanical properties and corrosion behavior of Al-Mg-Mn alloy were studied by differential scanning calorimetry (DSC), electron backscatter diffraction (EBSD), X-ray diffraction (XRD), tensile testing, electrochemical measurements and nitric acid mass loss test (NAMLT). The results show that the crystallization temperature range of Al-Mg-Mn alloy with addition of Zn decreased 4.7 °C. Cold rolled alloys mainly contain S texture, Copper texture, Brass texture, and Goss texture; the content of the S texture is the highest. With the addition of trace elements, the second phase Al<sub>3</sub>Er, Al<sub>3</sub>Zr, Al<sub>2</sub>CuMg, Mg<sub>2</sub>Si and MgZn<sub>2</sub> can be formed, which can improve the tensile strength and yield strength of Al-Mg-Mn alloy. The addition of the alloying element Zn can also improve the intergranular corrosion resistance of the Al-Mg-Mn alloy.
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spelling doaj.art-d58f0f13a5224e708822ac7b81bf7c912023-11-19T20:46:38ZengMDPI AGMetals2075-47012020-04-0110448310.3390/met10040483Effect of Trace Elements on the Crystallization Temperature Interval and Properties of 5xxx Series Aluminum AlloysQianqian Li0Mengjia Li1Guangxi Lu2Shaokang Guan3Engui Zhang4Cong Xu5School of Materials Science and Engineering & Henan Key Laboratory of Advanced Magnesium Alloy & Key Laboratory of Materials Processing and Mold Technology (Ministry of Education), Zhengzhou University, 100 Science Road, Zhengzhou 450001, ChinaSchool of Materials Science and Engineering & Henan Key Laboratory of Advanced Magnesium Alloy & Key Laboratory of Materials Processing and Mold Technology (Ministry of Education), Zhengzhou University, 100 Science Road, Zhengzhou 450001, ChinaSchool of Materials Science and Engineering & Henan Key Laboratory of Advanced Magnesium Alloy & Key Laboratory of Materials Processing and Mold Technology (Ministry of Education), Zhengzhou University, 100 Science Road, Zhengzhou 450001, ChinaSchool of Materials Science and Engineering & Henan Key Laboratory of Advanced Magnesium Alloy & Key Laboratory of Materials Processing and Mold Technology (Ministry of Education), Zhengzhou University, 100 Science Road, Zhengzhou 450001, ChinaSchool of Materials Science and Engineering & Henan Key Laboratory of Advanced Magnesium Alloy & Key Laboratory of Materials Processing and Mold Technology (Ministry of Education), Zhengzhou University, 100 Science Road, Zhengzhou 450001, ChinaSchool of Materials Science and Engineering & Henan Key Laboratory of Advanced Magnesium Alloy & Key Laboratory of Materials Processing and Mold Technology (Ministry of Education), Zhengzhou University, 100 Science Road, Zhengzhou 450001, ChinaThe influence of alloying elements Er, Zr, Cu, Si and Zn on the crystallization temperature interval, microstructure, mechanical properties and corrosion behavior of Al-Mg-Mn alloy were studied by differential scanning calorimetry (DSC), electron backscatter diffraction (EBSD), X-ray diffraction (XRD), tensile testing, electrochemical measurements and nitric acid mass loss test (NAMLT). The results show that the crystallization temperature range of Al-Mg-Mn alloy with addition of Zn decreased 4.7 °C. Cold rolled alloys mainly contain S texture, Copper texture, Brass texture, and Goss texture; the content of the S texture is the highest. With the addition of trace elements, the second phase Al<sub>3</sub>Er, Al<sub>3</sub>Zr, Al<sub>2</sub>CuMg, Mg<sub>2</sub>Si and MgZn<sub>2</sub> can be formed, which can improve the tensile strength and yield strength of Al-Mg-Mn alloy. The addition of the alloying element Zn can also improve the intergranular corrosion resistance of the Al-Mg-Mn alloy.https://www.mdpi.com/2075-4701/10/4/483Al-Mg-Mn alloymicroalloyingcrystallization temperature intervalmechanical propertiescorrosion behavior
spellingShingle Qianqian Li
Mengjia Li
Guangxi Lu
Shaokang Guan
Engui Zhang
Cong Xu
Effect of Trace Elements on the Crystallization Temperature Interval and Properties of 5xxx Series Aluminum Alloys
Metals
Al-Mg-Mn alloy
microalloying
crystallization temperature interval
mechanical properties
corrosion behavior
title Effect of Trace Elements on the Crystallization Temperature Interval and Properties of 5xxx Series Aluminum Alloys
title_full Effect of Trace Elements on the Crystallization Temperature Interval and Properties of 5xxx Series Aluminum Alloys
title_fullStr Effect of Trace Elements on the Crystallization Temperature Interval and Properties of 5xxx Series Aluminum Alloys
title_full_unstemmed Effect of Trace Elements on the Crystallization Temperature Interval and Properties of 5xxx Series Aluminum Alloys
title_short Effect of Trace Elements on the Crystallization Temperature Interval and Properties of 5xxx Series Aluminum Alloys
title_sort effect of trace elements on the crystallization temperature interval and properties of 5xxx series aluminum alloys
topic Al-Mg-Mn alloy
microalloying
crystallization temperature interval
mechanical properties
corrosion behavior
url https://www.mdpi.com/2075-4701/10/4/483
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AT guangxilu effectoftraceelementsonthecrystallizationtemperatureintervalandpropertiesof5xxxseriesaluminumalloys
AT shaokangguan effectoftraceelementsonthecrystallizationtemperatureintervalandpropertiesof5xxxseriesaluminumalloys
AT enguizhang effectoftraceelementsonthecrystallizationtemperatureintervalandpropertiesof5xxxseriesaluminumalloys
AT congxu effectoftraceelementsonthecrystallizationtemperatureintervalandpropertiesof5xxxseriesaluminumalloys