Dichlorido(2,3-di-2-pyridylpyrazine-κ2N1,N2)platinum(II)
The PtII ion in the title complex, [PtCl2(C14H10N4)], is four-coordinated in a distorted square-planar environment by two N atoms of a chelating 2,3-di-2-pyridylpyrazine ligand and two chloride anions. The pyridyl ring coordinated to the PtII atom is inclined slightly to its carrier pyrazine ring [d...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811038906 |
| _version_ | 1818974324682391552 |
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| author | Kwang Ha |
| author_facet | Kwang Ha |
| author_sort | Kwang Ha |
| collection | DOAJ |
| description | The PtII ion in the title complex, [PtCl2(C14H10N4)], is four-coordinated in a distorted square-planar environment by two N atoms of a chelating 2,3-di-2-pyridylpyrazine ligand and two chloride anions. The pyridyl ring coordinated to the PtII atom is inclined slightly to its carrier pyrazine ring [dihedral angle = 13.5 (1)°], whereas the uncoordinated pyridyl ring is inclined considerably to the pyrazine ring [dihedral angle = 54.3 (2)°]. The dihedral angle between the two pyridyl rings is 59.2 (2)°. In the crystal, the complexes are assembled through intermolecular C—H...N and C—H...Cl hydrogen bonds, forming a three-dimensional network. Intramolecular C—H...N and C—H...Cl hydrogen bonds are also present. |
| first_indexed | 2024-12-20T15:38:15Z |
| format | Article |
| id | doaj.art-d5a1de9585ef4fa8adab062711827e55 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T15:38:15Z |
| publishDate | 2011-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-d5a1de9585ef4fa8adab062711827e552022-12-21T19:35:20ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-10-016710m1454m145410.1107/S1600536811038906Dichlorido(2,3-di-2-pyridylpyrazine-κ2N1,N2)platinum(II)Kwang HaThe PtII ion in the title complex, [PtCl2(C14H10N4)], is four-coordinated in a distorted square-planar environment by two N atoms of a chelating 2,3-di-2-pyridylpyrazine ligand and two chloride anions. The pyridyl ring coordinated to the PtII atom is inclined slightly to its carrier pyrazine ring [dihedral angle = 13.5 (1)°], whereas the uncoordinated pyridyl ring is inclined considerably to the pyrazine ring [dihedral angle = 54.3 (2)°]. The dihedral angle between the two pyridyl rings is 59.2 (2)°. In the crystal, the complexes are assembled through intermolecular C—H...N and C—H...Cl hydrogen bonds, forming a three-dimensional network. Intramolecular C—H...N and C—H...Cl hydrogen bonds are also present.http://scripts.iucr.org/cgi-bin/paper?S1600536811038906 |
| spellingShingle | Kwang Ha Dichlorido(2,3-di-2-pyridylpyrazine-κ2N1,N2)platinum(II) Acta Crystallographica Section E |
| title | Dichlorido(2,3-di-2-pyridylpyrazine-κ2N1,N2)platinum(II) |
| title_full | Dichlorido(2,3-di-2-pyridylpyrazine-κ2N1,N2)platinum(II) |
| title_fullStr | Dichlorido(2,3-di-2-pyridylpyrazine-κ2N1,N2)platinum(II) |
| title_full_unstemmed | Dichlorido(2,3-di-2-pyridylpyrazine-κ2N1,N2)platinum(II) |
| title_short | Dichlorido(2,3-di-2-pyridylpyrazine-κ2N1,N2)platinum(II) |
| title_sort | dichlorido 2 3 di 2 pyridylpyrazine amp 954 2n1 n2 platinum ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811038906 |
| work_keys_str_mv | AT kwangha dichlorido23di2pyridylpyrazineamp9542n1n2platinumii |