catena-Poly[[nickel(II)-μ3-1,1-dicyanoethene-2,2-dithiolato-κ4S,S′:N:N′-bis[(15-crown-5)magnesium(II)]-μ3-1,1-dicyanoethene-2,2-dithiolato-κ4N:N′:S,S′] dichloride]
The reaction of MgCl2, NiCl2, and Na2(i-mnt) (i-mnt is 1,1-dicyanothene-2,2-dithiolate) with 15-crown-5 (15-C-5) leads to an infinite chain polymer, {[NiMg2(C4N2S2)2(C10H20O5)2]Cl2}n or {[Mg(15-C-5)]2[Ni(i-mnt)2]Cl2}n, which consists of two [Mg(15-C-5)]2+ complex cations, one [Ni(i-mnt)2]2−...
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Format: | Article |
Language: | English |
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International Union of Crystallography
2008-01-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536807065622 |
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author | Junli Yang Chengjuan Li Dacheng Li Daqi Wang |
author_facet | Junli Yang Chengjuan Li Dacheng Li Daqi Wang |
author_sort | Junli Yang |
collection | DOAJ |
description | The reaction of MgCl2, NiCl2, and Na2(i-mnt) (i-mnt is 1,1-dicyanothene-2,2-dithiolate) with 15-crown-5 (15-C-5) leads to an infinite chain polymer, {[NiMg2(C4N2S2)2(C10H20O5)2]Cl2}n or {[Mg(15-C-5)]2[Ni(i-mnt)2]Cl2}n, which consists of two [Mg(15-C-5)]2+ complex cations, one [Ni(i-mnt)2]2− complex anion and two Cl− ions per formula unit. In the [Ni(i-mnt)2]2− complex anion, Ni2+ is located on a crystallographic mirror plane with a slightly distorted square-planar coordination by four S atoms. In the [Mg(15-C-5)]2+ complex cations, the Mg and one O atom of the crown lie on mirror planes and the Mg atoms are in sevenfold coordination environments of five O atoms from the crown and two N atoms from two i-mnt anions. The bridging of the two complexes via the Mg—N bonds leads to the formation of one-dimensional chains along the a axis. |
first_indexed | 2024-04-11T19:58:32Z |
format | Article |
id | doaj.art-d5a38aa4829949d5b473203c08c8c5b1 |
institution | Directory Open Access Journal |
issn | 1600-5368 |
language | English |
last_indexed | 2024-04-11T19:58:32Z |
publishDate | 2008-01-01 |
publisher | International Union of Crystallography |
record_format | Article |
series | Acta Crystallographica Section E |
spelling | doaj.art-d5a38aa4829949d5b473203c08c8c5b12022-12-22T04:05:50ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641m174m17410.1107/S1600536807065622catena-Poly[[nickel(II)-μ3-1,1-dicyanoethene-2,2-dithiolato-κ4S,S′:N:N′-bis[(15-crown-5)magnesium(II)]-μ3-1,1-dicyanoethene-2,2-dithiolato-κ4N:N′:S,S′] dichloride]Junli YangChengjuan LiDacheng LiDaqi WangThe reaction of MgCl2, NiCl2, and Na2(i-mnt) (i-mnt is 1,1-dicyanothene-2,2-dithiolate) with 15-crown-5 (15-C-5) leads to an infinite chain polymer, {[NiMg2(C4N2S2)2(C10H20O5)2]Cl2}n or {[Mg(15-C-5)]2[Ni(i-mnt)2]Cl2}n, which consists of two [Mg(15-C-5)]2+ complex cations, one [Ni(i-mnt)2]2− complex anion and two Cl− ions per formula unit. In the [Ni(i-mnt)2]2− complex anion, Ni2+ is located on a crystallographic mirror plane with a slightly distorted square-planar coordination by four S atoms. In the [Mg(15-C-5)]2+ complex cations, the Mg and one O atom of the crown lie on mirror planes and the Mg atoms are in sevenfold coordination environments of five O atoms from the crown and two N atoms from two i-mnt anions. The bridging of the two complexes via the Mg—N bonds leads to the formation of one-dimensional chains along the a axis.http://scripts.iucr.org/cgi-bin/paper?S1600536807065622 |
spellingShingle | Junli Yang Chengjuan Li Dacheng Li Daqi Wang catena-Poly[[nickel(II)-μ3-1,1-dicyanoethene-2,2-dithiolato-κ4S,S′:N:N′-bis[(15-crown-5)magnesium(II)]-μ3-1,1-dicyanoethene-2,2-dithiolato-κ4N:N′:S,S′] dichloride] Acta Crystallographica Section E |
title | catena-Poly[[nickel(II)-μ3-1,1-dicyanoethene-2,2-dithiolato-κ4S,S′:N:N′-bis[(15-crown-5)magnesium(II)]-μ3-1,1-dicyanoethene-2,2-dithiolato-κ4N:N′:S,S′] dichloride] |
title_full | catena-Poly[[nickel(II)-μ3-1,1-dicyanoethene-2,2-dithiolato-κ4S,S′:N:N′-bis[(15-crown-5)magnesium(II)]-μ3-1,1-dicyanoethene-2,2-dithiolato-κ4N:N′:S,S′] dichloride] |
title_fullStr | catena-Poly[[nickel(II)-μ3-1,1-dicyanoethene-2,2-dithiolato-κ4S,S′:N:N′-bis[(15-crown-5)magnesium(II)]-μ3-1,1-dicyanoethene-2,2-dithiolato-κ4N:N′:S,S′] dichloride] |
title_full_unstemmed | catena-Poly[[nickel(II)-μ3-1,1-dicyanoethene-2,2-dithiolato-κ4S,S′:N:N′-bis[(15-crown-5)magnesium(II)]-μ3-1,1-dicyanoethene-2,2-dithiolato-κ4N:N′:S,S′] dichloride] |
title_short | catena-Poly[[nickel(II)-μ3-1,1-dicyanoethene-2,2-dithiolato-κ4S,S′:N:N′-bis[(15-crown-5)magnesium(II)]-μ3-1,1-dicyanoethene-2,2-dithiolato-κ4N:N′:S,S′] dichloride] |
title_sort | catena poly nickel ii 956 3 1 1 dicyanoethene 2 2 dithiolato 954 4s s 8242 n n 8242 bis 15 crown 5 magnesium ii 956 3 1 1 dicyanoethene 2 2 dithiolato 954 4n n 8242 s s 8242 dichloride |
url | http://scripts.iucr.org/cgi-bin/paper?S1600536807065622 |
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