The impact of diurnal variability in sea surface temperature on the central Atlantic air-sea CO<sub>2</sub> flux

The effect of diurnal variations in sea surface temperature (SST) on the air-sea flux of CO<sub>2</sub> over the central Atlantic ocean and Mediterranean Sea (60 S–60 N, 60 W–45 E) is evaluated for 2005–2006. We use high spatial resolution hourly satellite ocean skin temperature data to...

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Main Authors: M. J. Filipiak, C. D. Jeffery, C. J. Merchant, H. Kettle, C. L. Gentemann
Format: Article
Language:English
Published: Copernicus Publications 2009-01-01
Series:Atmospheric Chemistry and Physics
Online Access:http://www.atmos-chem-phys.net/9/529/2009/acp-9-529-2009.pdf
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author M. J. Filipiak
C. D. Jeffery
C. J. Merchant
H. Kettle
C. L. Gentemann
author_facet M. J. Filipiak
C. D. Jeffery
C. J. Merchant
H. Kettle
C. L. Gentemann
author_sort M. J. Filipiak
collection DOAJ
description The effect of diurnal variations in sea surface temperature (SST) on the air-sea flux of CO<sub>2</sub> over the central Atlantic ocean and Mediterranean Sea (60 S–60 N, 60 W–45 E) is evaluated for 2005–2006. We use high spatial resolution hourly satellite ocean skin temperature data to determine the diurnal warming (ΔSST). The CO<sub>2</sub> flux is then computed using three different temperature fields – a foundation temperature (<i>T<sub>f</sub></i>, measured at a depth where there is no diurnal variation), <i>T</i><sub><i>f</i></sub>, plus the hourly ΔSST and <i>T<sub>f</sub></i>, plus the monthly average of the ΔSSTs. This is done in conjunction with a physically-based parameterisation for the gas transfer velocity (NOAA-COARE). The differences between the fluxes evaluated for these three different temperature fields quantify the effects of both diurnal warming and diurnal covariations. We find that including diurnal warming increases the CO<sub>2</sub> flux out of this region of the Atlantic for 2005–2006 from 9.6 Tg C a<sup>&minus;1</sup> to 30.4 Tg C a<sup>&minus;1</sup> (hourly ΔSST) and 31.2 Tg C a<sup>&minus;1</sup> (monthly average of ΔSST measurements). Diurnal warming in this region, therefore, has a large impact on the annual net CO<sub>2</sub> flux but diurnal covariations are negligible. However, in this region of the Atlantic the uptake and outgassing of CO<sub>2</sub> is approximately balanced over the annual cycle, so although we find diurnal warming has a very large effect here, the Atlantic as a whole is a very strong carbon sink (e.g. &minus;920 Tg C a<sup>&minus;1</sup> Takahashi et al., 2002) making this is a small contribution to the Atlantic carbon budget.
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spelling doaj.art-d5cccf21689f4ad49d851c18d307a0372022-12-22T02:58:51ZengCopernicus PublicationsAtmospheric Chemistry and Physics1680-73161680-73242009-01-0192529541The impact of diurnal variability in sea surface temperature on the central Atlantic air-sea CO<sub>2</sub> fluxM. J. FilipiakC. D. JefferyC. J. MerchantH. KettleC. L. GentemannThe effect of diurnal variations in sea surface temperature (SST) on the air-sea flux of CO<sub>2</sub> over the central Atlantic ocean and Mediterranean Sea (60 S–60 N, 60 W–45 E) is evaluated for 2005–2006. We use high spatial resolution hourly satellite ocean skin temperature data to determine the diurnal warming (ΔSST). The CO<sub>2</sub> flux is then computed using three different temperature fields – a foundation temperature (<i>T<sub>f</sub></i>, measured at a depth where there is no diurnal variation), <i>T</i><sub><i>f</i></sub>, plus the hourly ΔSST and <i>T<sub>f</sub></i>, plus the monthly average of the ΔSSTs. This is done in conjunction with a physically-based parameterisation for the gas transfer velocity (NOAA-COARE). The differences between the fluxes evaluated for these three different temperature fields quantify the effects of both diurnal warming and diurnal covariations. We find that including diurnal warming increases the CO<sub>2</sub> flux out of this region of the Atlantic for 2005–2006 from 9.6 Tg C a<sup>&minus;1</sup> to 30.4 Tg C a<sup>&minus;1</sup> (hourly ΔSST) and 31.2 Tg C a<sup>&minus;1</sup> (monthly average of ΔSST measurements). Diurnal warming in this region, therefore, has a large impact on the annual net CO<sub>2</sub> flux but diurnal covariations are negligible. However, in this region of the Atlantic the uptake and outgassing of CO<sub>2</sub> is approximately balanced over the annual cycle, so although we find diurnal warming has a very large effect here, the Atlantic as a whole is a very strong carbon sink (e.g. &minus;920 Tg C a<sup>&minus;1</sup> Takahashi et al., 2002) making this is a small contribution to the Atlantic carbon budget.http://www.atmos-chem-phys.net/9/529/2009/acp-9-529-2009.pdf
spellingShingle M. J. Filipiak
C. D. Jeffery
C. J. Merchant
H. Kettle
C. L. Gentemann
The impact of diurnal variability in sea surface temperature on the central Atlantic air-sea CO<sub>2</sub> flux
Atmospheric Chemistry and Physics
title The impact of diurnal variability in sea surface temperature on the central Atlantic air-sea CO<sub>2</sub> flux
title_full The impact of diurnal variability in sea surface temperature on the central Atlantic air-sea CO<sub>2</sub> flux
title_fullStr The impact of diurnal variability in sea surface temperature on the central Atlantic air-sea CO<sub>2</sub> flux
title_full_unstemmed The impact of diurnal variability in sea surface temperature on the central Atlantic air-sea CO<sub>2</sub> flux
title_short The impact of diurnal variability in sea surface temperature on the central Atlantic air-sea CO<sub>2</sub> flux
title_sort impact of diurnal variability in sea surface temperature on the central atlantic air sea co sub 2 sub flux
url http://www.atmos-chem-phys.net/9/529/2009/acp-9-529-2009.pdf
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