Anodic Bubble Behavior in a Laboratory Scale Transparent Electrolytic Cell for Aluminum Electrolysis

In the Hall-Héroult process for extracting aluminum, the evolution and dynamics of anodic bubbles have a significant influence on the efficiency of the overall electrolysis process. In this study, the behavior of the bubbles beneath the carbon anode in cryolite-alumina molten salt was stu...

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Main Authors: Yipeng Huang, Zhaowen Wang, Youjian Yang, Bingliang Gao, Zhongning Shi, Xianwei Hu
Format: Article
Language:English
Published: MDPI AG 2018-10-01
Series:Metals
Subjects:
Online Access:http://www.mdpi.com/2075-4701/8/10/806
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author Yipeng Huang
Zhaowen Wang
Youjian Yang
Bingliang Gao
Zhongning Shi
Xianwei Hu
author_facet Yipeng Huang
Zhaowen Wang
Youjian Yang
Bingliang Gao
Zhongning Shi
Xianwei Hu
author_sort Yipeng Huang
collection DOAJ
description In the Hall-Héroult process for extracting aluminum, the evolution and dynamics of anodic bubbles have a significant influence on the efficiency of the overall electrolysis process. In this study, the behavior of the bubbles beneath the carbon anode in cryolite-alumina molten salt was studied for the first time using a laboratory-scale transparent electrolysis cell to view the anode from the bottom. The bubble dynamics and the relevant characteristic parameters of bubbles were obtained using video cameras and image processing. It was found that the bubbles were observed to preferentially generate at several areas on the underside of the anode and the morphologies of coalesced bubbles show excellent similarity. Moreover, the behavior of gas on carbon and graphite anodes was significantly different, where the carbon anode favored the forming of larger bubbles. These observations confirmed different types of carbon anodes cause different bubble behavior. These findings are expected to be useful in optimizing the aluminum electrolysis process on an industrial scale.
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spelling doaj.art-d5e9c6a2a1da48158c717ab050771b0a2022-12-21T22:51:03ZengMDPI AGMetals2075-47012018-10-0181080610.3390/met8100806met8100806Anodic Bubble Behavior in a Laboratory Scale Transparent Electrolytic Cell for Aluminum ElectrolysisYipeng Huang0Zhaowen Wang1Youjian Yang2Bingliang Gao3Zhongning Shi4Xianwei Hu5School of Metallurgy, Northeastern University, 3-11 Wenhua Road, Heping District, Shenyang 110819, ChinaSchool of Metallurgy, Northeastern University, 3-11 Wenhua Road, Heping District, Shenyang 110819, ChinaSchool of Metallurgy, Northeastern University, 3-11 Wenhua Road, Heping District, Shenyang 110819, ChinaSchool of Metallurgy, Northeastern University, 3-11 Wenhua Road, Heping District, Shenyang 110819, ChinaSchool of Metallurgy, Northeastern University, 3-11 Wenhua Road, Heping District, Shenyang 110819, ChinaSchool of Metallurgy, Northeastern University, 3-11 Wenhua Road, Heping District, Shenyang 110819, ChinaIn the Hall-Héroult process for extracting aluminum, the evolution and dynamics of anodic bubbles have a significant influence on the efficiency of the overall electrolysis process. In this study, the behavior of the bubbles beneath the carbon anode in cryolite-alumina molten salt was studied for the first time using a laboratory-scale transparent electrolysis cell to view the anode from the bottom. The bubble dynamics and the relevant characteristic parameters of bubbles were obtained using video cameras and image processing. It was found that the bubbles were observed to preferentially generate at several areas on the underside of the anode and the morphologies of coalesced bubbles show excellent similarity. Moreover, the behavior of gas on carbon and graphite anodes was significantly different, where the carbon anode favored the forming of larger bubbles. These observations confirmed different types of carbon anodes cause different bubble behavior. These findings are expected to be useful in optimizing the aluminum electrolysis process on an industrial scale.http://www.mdpi.com/2075-4701/8/10/806aluminum electrolysisanodic bubbletransparent electrolysis cellscarbon anode
spellingShingle Yipeng Huang
Zhaowen Wang
Youjian Yang
Bingliang Gao
Zhongning Shi
Xianwei Hu
Anodic Bubble Behavior in a Laboratory Scale Transparent Electrolytic Cell for Aluminum Electrolysis
Metals
aluminum electrolysis
anodic bubble
transparent electrolysis cells
carbon anode
title Anodic Bubble Behavior in a Laboratory Scale Transparent Electrolytic Cell for Aluminum Electrolysis
title_full Anodic Bubble Behavior in a Laboratory Scale Transparent Electrolytic Cell for Aluminum Electrolysis
title_fullStr Anodic Bubble Behavior in a Laboratory Scale Transparent Electrolytic Cell for Aluminum Electrolysis
title_full_unstemmed Anodic Bubble Behavior in a Laboratory Scale Transparent Electrolytic Cell for Aluminum Electrolysis
title_short Anodic Bubble Behavior in a Laboratory Scale Transparent Electrolytic Cell for Aluminum Electrolysis
title_sort anodic bubble behavior in a laboratory scale transparent electrolytic cell for aluminum electrolysis
topic aluminum electrolysis
anodic bubble
transparent electrolysis cells
carbon anode
url http://www.mdpi.com/2075-4701/8/10/806
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