Equilibrium Adsorption of Two-Component Organic Solutes from Aqueous Solutions on Activated Carbon

The adsorption equilibria of the mixtures phenol-indol, indol- p -nitrophenol ( p NP), α-picoline-phenol from aqueous solution on activated carbon, mainly Hydraffin 71 and BHT 023/82 have been studied. Significant displacement of one solute by the other was observed. The designation of the more stro...

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Main Authors: A. Seidel, G. Reschke, S. Friedrich, D. Gelbin
Format: Article
Language:English
Published: SAGE Publications 1986-09-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1177/026361748600300309
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author A. Seidel
G. Reschke
S. Friedrich
D. Gelbin
author_facet A. Seidel
G. Reschke
S. Friedrich
D. Gelbin
author_sort A. Seidel
collection DOAJ
description The adsorption equilibria of the mixtures phenol-indol, indol- p -nitrophenol ( p NP), α-picoline-phenol from aqueous solution on activated carbon, mainly Hydraffin 71 and BHT 023/82 have been studied. Significant displacement of one solute by the other was observed. The designation of the more strongly adsorbed component depends on the relative concentration of the two solutes in the mixture and on the pH. Predictive equations for calculating mixture equilibria solely on the basis of single solute isotherms do not agree well with the experimental values; the introduction of empirical parameters determined by curve-fitting is necessary. A multi-Redlich-Peterson equation is derived, which yields a satisfactory representation of most of the present binary solute adsorption data.
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spelling doaj.art-d5f0e231deaa4c2588ad1c7d364502b12024-03-02T00:06:45ZengSAGE PublicationsAdsorption Science & Technology0263-61742048-40381986-09-01310.1177/026361748600300309Equilibrium Adsorption of Two-Component Organic Solutes from Aqueous Solutions on Activated CarbonA. SeidelG. ReschkeS. Friedrich0D. Gelbin Department of Mathematics, Karl-Marx University, Leipzig, GDRThe adsorption equilibria of the mixtures phenol-indol, indol- p -nitrophenol ( p NP), α-picoline-phenol from aqueous solution on activated carbon, mainly Hydraffin 71 and BHT 023/82 have been studied. Significant displacement of one solute by the other was observed. The designation of the more strongly adsorbed component depends on the relative concentration of the two solutes in the mixture and on the pH. Predictive equations for calculating mixture equilibria solely on the basis of single solute isotherms do not agree well with the experimental values; the introduction of empirical parameters determined by curve-fitting is necessary. A multi-Redlich-Peterson equation is derived, which yields a satisfactory representation of most of the present binary solute adsorption data.https://doi.org/10.1177/026361748600300309
spellingShingle A. Seidel
G. Reschke
S. Friedrich
D. Gelbin
Equilibrium Adsorption of Two-Component Organic Solutes from Aqueous Solutions on Activated Carbon
Adsorption Science & Technology
title Equilibrium Adsorption of Two-Component Organic Solutes from Aqueous Solutions on Activated Carbon
title_full Equilibrium Adsorption of Two-Component Organic Solutes from Aqueous Solutions on Activated Carbon
title_fullStr Equilibrium Adsorption of Two-Component Organic Solutes from Aqueous Solutions on Activated Carbon
title_full_unstemmed Equilibrium Adsorption of Two-Component Organic Solutes from Aqueous Solutions on Activated Carbon
title_short Equilibrium Adsorption of Two-Component Organic Solutes from Aqueous Solutions on Activated Carbon
title_sort equilibrium adsorption of two component organic solutes from aqueous solutions on activated carbon
url https://doi.org/10.1177/026361748600300309
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