Solid-Liquid Phase Transfer Catalyzed Selective Reduction of Bifunctional Moieties
In this article, a chemoselective reduction process of various aldehydes to their corresponding alcohols is described. An aqueous solution of various aromatic and allylic aldehydes was treated with NaBH4 and tetrabutylammonium iodide as a phase transfer catalyst by choosing appropriate concentratio...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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Universidade Federal de Mato Grosso do Sul
2021-10-01
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| Series: | Orbital: The Electronic Journal of Chemistry |
| Subjects: | |
| Online Access: | https://periodicos.ufms.br/index.php/orbital/article/view/15554 |
| _version_ | 1797946872534401024 |
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| author | Monika Verma Renu Sharma Ruchi Bharti |
| author_facet | Monika Verma Renu Sharma Ruchi Bharti |
| author_sort | Monika Verma |
| collection | DOAJ |
| description |
In this article, a chemoselective reduction process of various aldehydes to their corresponding alcohols is described. An aqueous solution of various aromatic and allylic aldehydes was treated with NaBH4 and tetrabutylammonium iodide as a phase transfer catalyst by choosing appropriate concentrations to give their respective alcohols in good to moderate yield. This methodology offered several advantages, including simple environmentally benign experimental procedure, good yields, short reaction time, and no toxic by-product.
DOI: http://dx.doi.org/10.17807/orbital.v13i4.1576
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| first_indexed | 2024-04-10T21:18:59Z |
| format | Article |
| id | doaj.art-d5f6ef46b09d4737b04ec85a8394d5c6 |
| institution | Directory Open Access Journal |
| issn | 1984-6428 |
| language | English |
| last_indexed | 2024-04-10T21:18:59Z |
| publishDate | 2021-10-01 |
| publisher | Universidade Federal de Mato Grosso do Sul |
| record_format | Article |
| series | Orbital: The Electronic Journal of Chemistry |
| spelling | doaj.art-d5f6ef46b09d4737b04ec85a8394d5c62023-01-20T10:48:27ZengUniversidade Federal de Mato Grosso do SulOrbital: The Electronic Journal of Chemistry1984-64282021-10-01134Solid-Liquid Phase Transfer Catalyzed Selective Reduction of Bifunctional MoietiesMonika Verma0Renu Sharma1Ruchi Bharti2Chandigarh University, MohaliChandigarh University, MohaliChandigarh University, Mohali In this article, a chemoselective reduction process of various aldehydes to their corresponding alcohols is described. An aqueous solution of various aromatic and allylic aldehydes was treated with NaBH4 and tetrabutylammonium iodide as a phase transfer catalyst by choosing appropriate concentrations to give their respective alcohols in good to moderate yield. This methodology offered several advantages, including simple environmentally benign experimental procedure, good yields, short reaction time, and no toxic by-product. DOI: http://dx.doi.org/10.17807/orbital.v13i4.1576 https://periodicos.ufms.br/index.php/orbital/article/view/15554Phase transfer catalysis; solid liquid phase; chemoselective reductions; Bifunctional Moieties |
| spellingShingle | Monika Verma Renu Sharma Ruchi Bharti Solid-Liquid Phase Transfer Catalyzed Selective Reduction of Bifunctional Moieties Orbital: The Electronic Journal of Chemistry Phase transfer catalysis; solid liquid phase; chemoselective reductions; Bifunctional Moieties |
| title | Solid-Liquid Phase Transfer Catalyzed Selective Reduction of Bifunctional Moieties |
| title_full | Solid-Liquid Phase Transfer Catalyzed Selective Reduction of Bifunctional Moieties |
| title_fullStr | Solid-Liquid Phase Transfer Catalyzed Selective Reduction of Bifunctional Moieties |
| title_full_unstemmed | Solid-Liquid Phase Transfer Catalyzed Selective Reduction of Bifunctional Moieties |
| title_short | Solid-Liquid Phase Transfer Catalyzed Selective Reduction of Bifunctional Moieties |
| title_sort | solid liquid phase transfer catalyzed selective reduction of bifunctional moieties |
| topic | Phase transfer catalysis; solid liquid phase; chemoselective reductions; Bifunctional Moieties |
| url | https://periodicos.ufms.br/index.php/orbital/article/view/15554 |
| work_keys_str_mv | AT monikaverma solidliquidphasetransfercatalyzedselectivereductionofbifunctionalmoieties AT renusharma solidliquidphasetransfercatalyzedselectivereductionofbifunctionalmoieties AT ruchibharti solidliquidphasetransfercatalyzedselectivereductionofbifunctionalmoieties |