Dichlorido(4,4′-di-tert-butyl-2,2′-bipyridine-κ2N,N′)palladium(II) dimethyl sulfoxide monosolvate monohydrate
The title compound, [PdCl2(C18H24N2)]·(CH3)2SO·H2O, the PdII ion is in a distorted square-planar geometry. The Pd—N bond distances are 2.022 (2) and 2.027 (2) Å, the Pd—Cl bond distances are 2.2880 (7) and 2.2833 (7) Å, and the ligand bite angle is 80.07 (9)°. The dimethyl sulfoxide and water molecu...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814009453 |
| _version_ | 1828882630142066688 |
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| author | Ricardo A. Gutiérrez-Márquez Carmela Crisóstomo-Lucas Reyna Reyes-Martínez Simón Hernández-Ortega David Morales-Morales |
| author_facet | Ricardo A. Gutiérrez-Márquez Carmela Crisóstomo-Lucas Reyna Reyes-Martínez Simón Hernández-Ortega David Morales-Morales |
| author_sort | Ricardo A. Gutiérrez-Márquez |
| collection | DOAJ |
| description | The title compound, [PdCl2(C18H24N2)]·(CH3)2SO·H2O, the PdII ion is in a distorted square-planar geometry. The Pd—N bond distances are 2.022 (2) and 2.027 (2) Å, the Pd—Cl bond distances are 2.2880 (7) and 2.2833 (7) Å, and the ligand bite angle is 80.07 (9)°. The dimethyl sulfoxide and water molecules form linear chains along [100] by O—H...O and O—H...S hydrogen bonds, generating eight- and 12-membered rings. C—H...Cl interactions link the chains, forming a three-dimensional arrangement. In addition, the 4,4-di-tert-butyl-2,2′-bipyridine ligand exhibits π–π stacking interactions [centroid–centroid distances = 3.8741 (15) and 3.8353 (15) Å]. The DMSO solvent is disordered and was refined with an occupancy ratio of 0.866 (3):0.134 (3). |
| first_indexed | 2024-12-13T10:31:56Z |
| format | Article |
| id | doaj.art-d5fc249130974bdd94fb4375b4c449e5 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:31:56Z |
| publishDate | 2014-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-d5fc249130974bdd94fb4375b4c449e52022-12-21T23:50:50ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-06-01706m200m20110.1107/S1600536814009453pj2010Dichlorido(4,4′-di-tert-butyl-2,2′-bipyridine-κ2N,N′)palladium(II) dimethyl sulfoxide monosolvate monohydrateRicardo A. Gutiérrez-Márquez0Carmela Crisóstomo-Lucas1Reyna Reyes-Martínez2Simón Hernández-Ortega3David Morales-Morales4Instituto de Química, Universidad Nacional Autónoma de México, Circuito exterior, Ciudad Universitaria, México, DF, 04510, MexicoInstituto de Química, Universidad Nacional Autónoma de México, Circuito exterior, Ciudad Universitaria, México, DF, 04510, MexicoInstituto de Química, Universidad Nacional Autónoma de México, Circuito exterior, Ciudad Universitaria, México, DF, 04510, MexicoInstituto de Química, Universidad Nacional Autónoma de México, Circuito exterior, Ciudad Universitaria, México, DF, 04510, MexicoInstituto de Química, Universidad Nacional Autónoma de México, Circuito exterior, Ciudad Universitaria, México, DF, 04510, MexicoThe title compound, [PdCl2(C18H24N2)]·(CH3)2SO·H2O, the PdII ion is in a distorted square-planar geometry. The Pd—N bond distances are 2.022 (2) and 2.027 (2) Å, the Pd—Cl bond distances are 2.2880 (7) and 2.2833 (7) Å, and the ligand bite angle is 80.07 (9)°. The dimethyl sulfoxide and water molecules form linear chains along [100] by O—H...O and O—H...S hydrogen bonds, generating eight- and 12-membered rings. C—H...Cl interactions link the chains, forming a three-dimensional arrangement. In addition, the 4,4-di-tert-butyl-2,2′-bipyridine ligand exhibits π–π stacking interactions [centroid–centroid distances = 3.8741 (15) and 3.8353 (15) Å]. The DMSO solvent is disordered and was refined with an occupancy ratio of 0.866 (3):0.134 (3).http://scripts.iucr.org/cgi-bin/paper?S1600536814009453 |
| spellingShingle | Ricardo A. Gutiérrez-Márquez Carmela Crisóstomo-Lucas Reyna Reyes-Martínez Simón Hernández-Ortega David Morales-Morales Dichlorido(4,4′-di-tert-butyl-2,2′-bipyridine-κ2N,N′)palladium(II) dimethyl sulfoxide monosolvate monohydrate Acta Crystallographica Section E |
| title | Dichlorido(4,4′-di-tert-butyl-2,2′-bipyridine-κ2N,N′)palladium(II) dimethyl sulfoxide monosolvate monohydrate |
| title_full | Dichlorido(4,4′-di-tert-butyl-2,2′-bipyridine-κ2N,N′)palladium(II) dimethyl sulfoxide monosolvate monohydrate |
| title_fullStr | Dichlorido(4,4′-di-tert-butyl-2,2′-bipyridine-κ2N,N′)palladium(II) dimethyl sulfoxide monosolvate monohydrate |
| title_full_unstemmed | Dichlorido(4,4′-di-tert-butyl-2,2′-bipyridine-κ2N,N′)palladium(II) dimethyl sulfoxide monosolvate monohydrate |
| title_short | Dichlorido(4,4′-di-tert-butyl-2,2′-bipyridine-κ2N,N′)palladium(II) dimethyl sulfoxide monosolvate monohydrate |
| title_sort | dichlorido 4 4 di tert butyl 2 2 bipyridine κ2n n palladium ii dimethyl sulfoxide monosolvate monohydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536814009453 |
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