Construction of conjugated scaffolds driven by mechanochemistry towards energy storage applications
Mechanochemistry has been recognized as an efficient and sustainable methodology to provide a unique driven force and reaction environments under ambient and neat conditions for the construction of functionalized materials possessing promising properties. Among them, highly porous conjugated scaffol...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
KeAi Communications Co. Ltd.
2024-06-01
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| Series: | Green Chemical Engineering |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2666952823000110 |
| _version_ | 1797259667359924224 |
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| author | Juntian Fan Zhenzhen Yang Sheng Dai |
| author_facet | Juntian Fan Zhenzhen Yang Sheng Dai |
| author_sort | Juntian Fan |
| collection | DOAJ |
| description | Mechanochemistry has been recognized as an efficient and sustainable methodology to provide a unique driven force and reaction environments under ambient and neat conditions for the construction of functionalized materials possessing promising properties. Among them, highly porous conjugated scaffolds with attractive electronic conductivities and high surface areas are one of the representative categories exhibiting diverse task-specific applications, especially in electrochemical energy storage. In recent years, the mechanochemistry-driven procedures have been deployed to construct conjugated scaffolds with engineered structures and properties leveraging the tunability in chemical structures of building blocks and polymerization capability of diverse catalysts. Therefore, a thorough review of related works is required to gain an in-depth understanding of the mechanochemical synthesis procedure and property-performance relationship of the as-produced conjugated scaffolds. Herein, the mechanochemistry-driven construction of conjugated porous networks (CPNs), the carbon-based materials (e.g., graphite and graphyne), and carbon supported single atom catalysts (CS-SACs) are discussed and summarized. The electrochemical performance of the afforded conductive scaffolds as electrode materials in supercapacitors and alkali-ion batteries is elucidated. Finally, the challenges and potential opportunities related to the construction of conjugated scaffolds driven by mechanochemistry are also discussed and concluded. |
| first_indexed | 2024-04-24T23:13:04Z |
| format | Article |
| id | doaj.art-d5fc59437cc84ff5ab20c514e81cfe05 |
| institution | Directory Open Access Journal |
| issn | 2666-9528 |
| language | English |
| last_indexed | 2024-04-24T23:13:04Z |
| publishDate | 2024-06-01 |
| publisher | KeAi Communications Co. Ltd. |
| record_format | Article |
| series | Green Chemical Engineering |
| spelling | doaj.art-d5fc59437cc84ff5ab20c514e81cfe052024-03-17T07:59:08ZengKeAi Communications Co. Ltd.Green Chemical Engineering2666-95282024-06-0152155172Construction of conjugated scaffolds driven by mechanochemistry towards energy storage applicationsJuntian Fan0Zhenzhen Yang1Sheng Dai2Department of Chemistry, Institute for Advanced Materials and Manufacturing, University of Tennessee, Knoxville, TN, 37996, USAChemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA; Corresponding author.Department of Chemistry, Institute for Advanced Materials and Manufacturing, University of Tennessee, Knoxville, TN, 37996, USA; Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA; Corresponding author.Mechanochemistry has been recognized as an efficient and sustainable methodology to provide a unique driven force and reaction environments under ambient and neat conditions for the construction of functionalized materials possessing promising properties. Among them, highly porous conjugated scaffolds with attractive electronic conductivities and high surface areas are one of the representative categories exhibiting diverse task-specific applications, especially in electrochemical energy storage. In recent years, the mechanochemistry-driven procedures have been deployed to construct conjugated scaffolds with engineered structures and properties leveraging the tunability in chemical structures of building blocks and polymerization capability of diverse catalysts. Therefore, a thorough review of related works is required to gain an in-depth understanding of the mechanochemical synthesis procedure and property-performance relationship of the as-produced conjugated scaffolds. Herein, the mechanochemistry-driven construction of conjugated porous networks (CPNs), the carbon-based materials (e.g., graphite and graphyne), and carbon supported single atom catalysts (CS-SACs) are discussed and summarized. The electrochemical performance of the afforded conductive scaffolds as electrode materials in supercapacitors and alkali-ion batteries is elucidated. Finally, the challenges and potential opportunities related to the construction of conjugated scaffolds driven by mechanochemistry are also discussed and concluded.http://www.sciencedirect.com/science/article/pii/S2666952823000110MechanochemistryConjugated scaffoldsPorous organic networksAlkali-ion batterySupercapacitor |
| spellingShingle | Juntian Fan Zhenzhen Yang Sheng Dai Construction of conjugated scaffolds driven by mechanochemistry towards energy storage applications Green Chemical Engineering Mechanochemistry Conjugated scaffolds Porous organic networks Alkali-ion battery Supercapacitor |
| title | Construction of conjugated scaffolds driven by mechanochemistry towards energy storage applications |
| title_full | Construction of conjugated scaffolds driven by mechanochemistry towards energy storage applications |
| title_fullStr | Construction of conjugated scaffolds driven by mechanochemistry towards energy storage applications |
| title_full_unstemmed | Construction of conjugated scaffolds driven by mechanochemistry towards energy storage applications |
| title_short | Construction of conjugated scaffolds driven by mechanochemistry towards energy storage applications |
| title_sort | construction of conjugated scaffolds driven by mechanochemistry towards energy storage applications |
| topic | Mechanochemistry Conjugated scaffolds Porous organic networks Alkali-ion battery Supercapacitor |
| url | http://www.sciencedirect.com/science/article/pii/S2666952823000110 |
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