Hg<sup>2+</sup> Optical Fiber Sensor Based on LSPR Generated by Gold Nanoparticles Embedded in LBL Nano-Assembled Coatings

Mercury is an important contaminant since it is accumulated in the body of living beings, and very small concentrations are very dangerous in the long term. This paper reports the fabrication of a highly sensitive fiber optic sensor using the layer-by-layer nano-assembly technique with gold nanopart...

Full description

Bibliographic Details
Main Authors: María Elena Martínez-Hernández, Javier Goicoechea, Francisco J. Arregui
Format: Article
Language:English
Published: MDPI AG 2019-11-01
Series:Sensors
Subjects:
Online Access:https://www.mdpi.com/1424-8220/19/22/4906
_version_ 1798042150462554112
author María Elena Martínez-Hernández
Javier Goicoechea
Francisco J. Arregui
author_facet María Elena Martínez-Hernández
Javier Goicoechea
Francisco J. Arregui
author_sort María Elena Martínez-Hernández
collection DOAJ
description Mercury is an important contaminant since it is accumulated in the body of living beings, and very small concentrations are very dangerous in the long term. This paper reports the fabrication of a highly sensitive fiber optic sensor using the layer-by-layer nano-assembly technique with gold nanoparticles (AuNPs). The gold nanoparticles were obtained via a water-based synthesis route that use poly acrylic acid (PAA) as stabilizing agent, in the presence of a borane dimethylamine complex (DMAB) as reducing agent, giving PAA-capped AuNPs. The sensing mechanism is based on the alteration of the Localized Surface Plasmon Resonances (LSPR) generated by AuNPs thanks to the strong chemical affinity of metallic mercury towards gold, which lead to amalgam alloys.
first_indexed 2024-04-11T22:31:30Z
format Article
id doaj.art-d60948462e2b4cacb815d7b48cc145f1
institution Directory Open Access Journal
issn 1424-8220
language English
last_indexed 2024-04-11T22:31:30Z
publishDate 2019-11-01
publisher MDPI AG
record_format Article
series Sensors
spelling doaj.art-d60948462e2b4cacb815d7b48cc145f12022-12-22T03:59:22ZengMDPI AGSensors1424-82202019-11-011922490610.3390/s19224906s19224906Hg<sup>2+</sup> Optical Fiber Sensor Based on LSPR Generated by Gold Nanoparticles Embedded in LBL Nano-Assembled CoatingsMaría Elena Martínez-Hernández0Javier Goicoechea1Francisco J. Arregui2Department of Electrical, Electronic and Communication Engineering, Universidad Publica de Navarra, Edif. Los Tejos, Campus Arrosadía, 31006 Pamplona, SpainDepartment of Electrical, Electronic and Communication Engineering, Universidad Publica de Navarra, Edif. Los Tejos, Campus Arrosadía, 31006 Pamplona, SpainDepartment of Electrical, Electronic and Communication Engineering, Universidad Publica de Navarra, Edif. Los Tejos, Campus Arrosadía, 31006 Pamplona, SpainMercury is an important contaminant since it is accumulated in the body of living beings, and very small concentrations are very dangerous in the long term. This paper reports the fabrication of a highly sensitive fiber optic sensor using the layer-by-layer nano-assembly technique with gold nanoparticles (AuNPs). The gold nanoparticles were obtained via a water-based synthesis route that use poly acrylic acid (PAA) as stabilizing agent, in the presence of a borane dimethylamine complex (DMAB) as reducing agent, giving PAA-capped AuNPs. The sensing mechanism is based on the alteration of the Localized Surface Plasmon Resonances (LSPR) generated by AuNPs thanks to the strong chemical affinity of metallic mercury towards gold, which lead to amalgam alloys.https://www.mdpi.com/1424-8220/19/22/4906fiber optic sensorgold nanoparticleslocalized surface plasmon resonancemercuryppb
spellingShingle María Elena Martínez-Hernández
Javier Goicoechea
Francisco J. Arregui
Hg<sup>2+</sup> Optical Fiber Sensor Based on LSPR Generated by Gold Nanoparticles Embedded in LBL Nano-Assembled Coatings
Sensors
fiber optic sensor
gold nanoparticles
localized surface plasmon resonance
mercury
ppb
title Hg<sup>2+</sup> Optical Fiber Sensor Based on LSPR Generated by Gold Nanoparticles Embedded in LBL Nano-Assembled Coatings
title_full Hg<sup>2+</sup> Optical Fiber Sensor Based on LSPR Generated by Gold Nanoparticles Embedded in LBL Nano-Assembled Coatings
title_fullStr Hg<sup>2+</sup> Optical Fiber Sensor Based on LSPR Generated by Gold Nanoparticles Embedded in LBL Nano-Assembled Coatings
title_full_unstemmed Hg<sup>2+</sup> Optical Fiber Sensor Based on LSPR Generated by Gold Nanoparticles Embedded in LBL Nano-Assembled Coatings
title_short Hg<sup>2+</sup> Optical Fiber Sensor Based on LSPR Generated by Gold Nanoparticles Embedded in LBL Nano-Assembled Coatings
title_sort hg sup 2 sup optical fiber sensor based on lspr generated by gold nanoparticles embedded in lbl nano assembled coatings
topic fiber optic sensor
gold nanoparticles
localized surface plasmon resonance
mercury
ppb
url https://www.mdpi.com/1424-8220/19/22/4906
work_keys_str_mv AT mariaelenamartinezhernandez hgsup2supopticalfibersensorbasedonlsprgeneratedbygoldnanoparticlesembeddedinlblnanoassembledcoatings
AT javiergoicoechea hgsup2supopticalfibersensorbasedonlsprgeneratedbygoldnanoparticlesembeddedinlblnanoassembledcoatings
AT franciscojarregui hgsup2supopticalfibersensorbasedonlsprgeneratedbygoldnanoparticlesembeddedinlblnanoassembledcoatings