[2-(1H-Benzimidazol-2-yl-κN3)aniline-κN]dichloridozinc

In the title benzimidazole mononuclear complex, [ZnCl2(C13H11N3)], the ZnII ion is four-coordinated in a distorted tetrahedral geometry by an imidazole N, an amino N and two Cl atoms. The dihedral angle between the benzimidazole and benzene rings is 9.57 (1)°. In the cryst...

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Main Authors: Naser Eltaher Eltayeb, Siang Guan Teoh, Suchada Chantrapromma, Hoong-Kun Fun
Format: Article
Language:English
Published: International Union of Crystallography 2011-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811026572
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author Naser Eltaher Eltayeb
Siang Guan Teoh
Suchada Chantrapromma
Hoong-Kun Fun
author_facet Naser Eltaher Eltayeb
Siang Guan Teoh
Suchada Chantrapromma
Hoong-Kun Fun
author_sort Naser Eltaher Eltayeb
collection DOAJ
description In the title benzimidazole mononuclear complex, [ZnCl2(C13H11N3)], the ZnII ion is four-coordinated in a distorted tetrahedral geometry by an imidazole N, an amino N and two Cl atoms. The dihedral angle between the benzimidazole and benzene rings is 9.57 (1)°. In the crystal, molecules are linked by weak N—H...Cl hydrogen bonds into layers parallel to the bc plane. π–π interactions with centroid–centroid distances in the range 3.4452 (8)–3.8074 (8) Å are also observed.
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spelling doaj.art-d624e812ed5b40a3bbf840e1e40a82992022-12-22T01:36:10ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-08-01678m1062m106310.1107/S1600536811026572[2-(1H-Benzimidazol-2-yl-κN3)aniline-κN]dichloridozincNaser Eltaher EltayebSiang Guan TeohSuchada ChantraprommaHoong-Kun FunIn the title benzimidazole mononuclear complex, [ZnCl2(C13H11N3)], the ZnII ion is four-coordinated in a distorted tetrahedral geometry by an imidazole N, an amino N and two Cl atoms. The dihedral angle between the benzimidazole and benzene rings is 9.57 (1)°. In the crystal, molecules are linked by weak N—H...Cl hydrogen bonds into layers parallel to the bc plane. π–π interactions with centroid–centroid distances in the range 3.4452 (8)–3.8074 (8) Å are also observed.http://scripts.iucr.org/cgi-bin/paper?S1600536811026572
spellingShingle Naser Eltaher Eltayeb
Siang Guan Teoh
Suchada Chantrapromma
Hoong-Kun Fun
[2-(1H-Benzimidazol-2-yl-κN3)aniline-κN]dichloridozinc
Acta Crystallographica Section E
title [2-(1H-Benzimidazol-2-yl-κN3)aniline-κN]dichloridozinc
title_full [2-(1H-Benzimidazol-2-yl-κN3)aniline-κN]dichloridozinc
title_fullStr [2-(1H-Benzimidazol-2-yl-κN3)aniline-κN]dichloridozinc
title_full_unstemmed [2-(1H-Benzimidazol-2-yl-κN3)aniline-κN]dichloridozinc
title_short [2-(1H-Benzimidazol-2-yl-κN3)aniline-κN]dichloridozinc
title_sort 2 1h benzimidazol 2 yl amp 954 n3 aniline amp 954 n dichloridozinc
url http://scripts.iucr.org/cgi-bin/paper?S1600536811026572
work_keys_str_mv AT nasereltahereltayeb 21hbenzimidazol2ylamp954n3anilineamp954ndichloridozinc
AT siangguanteoh 21hbenzimidazol2ylamp954n3anilineamp954ndichloridozinc
AT suchadachantrapromma 21hbenzimidazol2ylamp954n3anilineamp954ndichloridozinc
AT hoongkunfun 21hbenzimidazol2ylamp954n3anilineamp954ndichloridozinc