Removal of Sodium from Vanadium Tailings by Calcification Roasting in Reducing Atmosphere

Vanadium tailings from vanadium extraction by a sodium roasting process are solid waste and cannot be used in sintering and ironmaking due to their high sodium content. In this paper, a calcification and reduction roasting process was proposed to remove sodium from vanadium tailings. The effects of...

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Main Authors: Chao Wang, Yufeng Guo, Shuai Wang, Feng Chen, Lingzhi Yang, Yu Zheng
Format: Article
Language:English
Published: MDPI AG 2023-01-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/16/3/986
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author Chao Wang
Yufeng Guo
Shuai Wang
Feng Chen
Lingzhi Yang
Yu Zheng
author_facet Chao Wang
Yufeng Guo
Shuai Wang
Feng Chen
Lingzhi Yang
Yu Zheng
author_sort Chao Wang
collection DOAJ
description Vanadium tailings from vanadium extraction by a sodium roasting process are solid waste and cannot be used in sintering and ironmaking due to their high sodium content. In this paper, a calcification and reduction roasting process was proposed to remove sodium from vanadium tailings. The effects of Ca(OH)<sub>2</sub> addition, reduction temperature, and roasting time on the sodium removal behavior and compression strength of pellets were studied. The addition of Ca(OH)<sub>2</sub> and the reduction of iron oxides promoted the sodium-containing phases to transform to be simpler, which could enhance sodium removal. The sodium removal rate was up to 93.47% and the compression strength of the reduced products was 4497 N/P, and the metallized ratio of the product was higher than 70% under the optimal conditions: roasting at 1200 °C for 2 h with the Ca(OH)<sub>2</sub> addition of 35%. The treated product after removing sodium can be recycled in the ironmaking process in a steel company.
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spelling doaj.art-d6494340fcf546c2b362ee5756df445e2023-11-16T17:15:29ZengMDPI AGMaterials1996-19442023-01-0116398610.3390/ma16030986Removal of Sodium from Vanadium Tailings by Calcification Roasting in Reducing AtmosphereChao Wang0Yufeng Guo1Shuai Wang2Feng Chen3Lingzhi Yang4Yu Zheng5School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, ChinaSchool of Minerals Processing and Bioengineering, Central South University, Changsha 410083, ChinaSchool of Minerals Processing and Bioengineering, Central South University, Changsha 410083, ChinaSchool of Minerals Processing and Bioengineering, Central South University, Changsha 410083, ChinaSchool of Minerals Processing and Bioengineering, Central South University, Changsha 410083, ChinaSchool of Minerals Processing and Bioengineering, Central South University, Changsha 410083, ChinaVanadium tailings from vanadium extraction by a sodium roasting process are solid waste and cannot be used in sintering and ironmaking due to their high sodium content. In this paper, a calcification and reduction roasting process was proposed to remove sodium from vanadium tailings. The effects of Ca(OH)<sub>2</sub> addition, reduction temperature, and roasting time on the sodium removal behavior and compression strength of pellets were studied. The addition of Ca(OH)<sub>2</sub> and the reduction of iron oxides promoted the sodium-containing phases to transform to be simpler, which could enhance sodium removal. The sodium removal rate was up to 93.47% and the compression strength of the reduced products was 4497 N/P, and the metallized ratio of the product was higher than 70% under the optimal conditions: roasting at 1200 °C for 2 h with the Ca(OH)<sub>2</sub> addition of 35%. The treated product after removing sodium can be recycled in the ironmaking process in a steel company.https://www.mdpi.com/1996-1944/16/3/986vanadium tailingssolid wastesodium removalreducingCa(OH)<sub>2</sub>phase transformation
spellingShingle Chao Wang
Yufeng Guo
Shuai Wang
Feng Chen
Lingzhi Yang
Yu Zheng
Removal of Sodium from Vanadium Tailings by Calcification Roasting in Reducing Atmosphere
Materials
vanadium tailings
solid waste
sodium removal
reducing
Ca(OH)<sub>2</sub>
phase transformation
title Removal of Sodium from Vanadium Tailings by Calcification Roasting in Reducing Atmosphere
title_full Removal of Sodium from Vanadium Tailings by Calcification Roasting in Reducing Atmosphere
title_fullStr Removal of Sodium from Vanadium Tailings by Calcification Roasting in Reducing Atmosphere
title_full_unstemmed Removal of Sodium from Vanadium Tailings by Calcification Roasting in Reducing Atmosphere
title_short Removal of Sodium from Vanadium Tailings by Calcification Roasting in Reducing Atmosphere
title_sort removal of sodium from vanadium tailings by calcification roasting in reducing atmosphere
topic vanadium tailings
solid waste
sodium removal
reducing
Ca(OH)<sub>2</sub>
phase transformation
url https://www.mdpi.com/1996-1944/16/3/986
work_keys_str_mv AT chaowang removalofsodiumfromvanadiumtailingsbycalcificationroastinginreducingatmosphere
AT yufengguo removalofsodiumfromvanadiumtailingsbycalcificationroastinginreducingatmosphere
AT shuaiwang removalofsodiumfromvanadiumtailingsbycalcificationroastinginreducingatmosphere
AT fengchen removalofsodiumfromvanadiumtailingsbycalcificationroastinginreducingatmosphere
AT lingzhiyang removalofsodiumfromvanadiumtailingsbycalcificationroastinginreducingatmosphere
AT yuzheng removalofsodiumfromvanadiumtailingsbycalcificationroastinginreducingatmosphere