"Preparation of high vinyl polybutadiene/sepiolite nanocomposite
High vinyl polybutadiene / sepiolite nanocomposites were prepared by in-situ polymerization using sepiolite as catalyst carrier for the coordination polymerization of butadiene catalyzed by molybdenum-based catalyst. Compared with pure MoCl5, the catalytic system of MoCl5 supported by sepiolite coul...
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| Format: | Article |
| Language: | zho |
| Published: |
Editorial Office of China Synthetic Rubber Industry
2022-07-01
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| Series: | Hecheng xiangjiao gongye |
| Subjects: | |
| Online Access: | http://hcxjgy.paperopen.com/oa/DArticle.aspx?type=view&id=202204013 |
| _version_ | 1811221767846363136 |
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| author | WANG Xiao-tong, XIE Ting-hao, TANG Jian, HUA Jing |
| author_facet | WANG Xiao-tong, XIE Ting-hao, TANG Jian, HUA Jing |
| author_sort | WANG Xiao-tong, XIE Ting-hao, TANG Jian, HUA Jing |
| collection | DOAJ |
| description | High vinyl polybutadiene / sepiolite nanocomposites were prepared by in-situ polymerization using sepiolite as catalyst carrier for the coordination polymerization of butadiene catalyzed by molybdenum-based catalyst. Compared with pure MoCl5, the catalytic system of MoCl5 supported by sepiolite could improve the activity of polymerization while the directivity remained unchang. Scanning electron microscope observation showed that the sepiolite in the in-situ composite had good peeling and dispersion in the polymer matrix. The test of rubber processing analyzer showed that the dispersion of silica in the matrix could be significantly improved by introducing 1% (mass fraction) sepiolite in the process of rubber mixing. In this way, high vinyl polybutadiene / sepiolite nanocomposites with higher polymerization activity and better processability could be prepared. |
| first_indexed | 2024-04-12T08:06:06Z |
| format | Article |
| id | doaj.art-d67682f13eb24c429f02e89d8204147d |
| institution | Directory Open Access Journal |
| issn | 1000-1255 |
| language | zho |
| last_indexed | 2024-04-12T08:06:06Z |
| publishDate | 2022-07-01 |
| publisher | Editorial Office of China Synthetic Rubber Industry |
| record_format | Article |
| series | Hecheng xiangjiao gongye |
| spelling | doaj.art-d67682f13eb24c429f02e89d8204147d2022-12-22T03:41:10ZzhoEditorial Office of China Synthetic Rubber IndustryHecheng xiangjiao gongye1000-12552022-07-0145432932910.19908/j.cnki.ISSN1000-1255.2022.03.0329"Preparation of high vinyl polybutadiene/sepiolite nanocomposite WANG Xiao-tong, XIE Ting-hao, TANG Jian, HUA Jing0Key Laboratory of Rubber-Plastics Materials and Engineering of Ministry of Education/Shandong Provincial Key Laboratory of Rubber and Plastics, Qingdao University of Science and Technology, Qingdao 266042, ChinaHigh vinyl polybutadiene / sepiolite nanocomposites were prepared by in-situ polymerization using sepiolite as catalyst carrier for the coordination polymerization of butadiene catalyzed by molybdenum-based catalyst. Compared with pure MoCl5, the catalytic system of MoCl5 supported by sepiolite could improve the activity of polymerization while the directivity remained unchang. Scanning electron microscope observation showed that the sepiolite in the in-situ composite had good peeling and dispersion in the polymer matrix. The test of rubber processing analyzer showed that the dispersion of silica in the matrix could be significantly improved by introducing 1% (mass fraction) sepiolite in the process of rubber mixing. In this way, high vinyl polybutadiene / sepiolite nanocomposites with higher polymerization activity and better processability could be prepared.http://hcxjgy.paperopen.com/oa/DArticle.aspx?type=view&id=202204013high vinyl polybutadienesepiolitemolybdenum-based catalystnanocompositepolymerization activityprocessability |
| spellingShingle | WANG Xiao-tong, XIE Ting-hao, TANG Jian, HUA Jing "Preparation of high vinyl polybutadiene/sepiolite nanocomposite Hecheng xiangjiao gongye high vinyl polybutadiene sepiolite molybdenum-based catalyst nanocomposite polymerization activity processability |
| title | "Preparation of high vinyl polybutadiene/sepiolite nanocomposite |
| title_full | "Preparation of high vinyl polybutadiene/sepiolite nanocomposite |
| title_fullStr | "Preparation of high vinyl polybutadiene/sepiolite nanocomposite |
| title_full_unstemmed | "Preparation of high vinyl polybutadiene/sepiolite nanocomposite |
| title_short | "Preparation of high vinyl polybutadiene/sepiolite nanocomposite |
| title_sort | preparation of high vinyl polybutadiene sepiolite nanocomposite |
| topic | high vinyl polybutadiene sepiolite molybdenum-based catalyst nanocomposite polymerization activity processability |
| url | http://hcxjgy.paperopen.com/oa/DArticle.aspx?type=view&id=202204013 |
| work_keys_str_mv | AT wangxiaotongxietinghaotangjianhuajing preparationofhighvinylpolybutadienesepiolitenanocomposite |