N-(3-Chloro-4-methylphenyl)succinamic acid
In the crystal structure of the title compound, C11H12ClNO3, the asymmetric unit contains two independent molecules. The N—H bond in the amide segment is anti to the meta-Cl atom in the benzene ring, in both molecules. The amide and carboxyl C=O bonds are also anti to each other and an...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-03-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812007623 |
| _version_ | 1819104847417311232 |
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| author | Sabine Foro U. Chaithanya B. Thimme Gowda |
| author_facet | Sabine Foro U. Chaithanya B. Thimme Gowda |
| author_sort | Sabine Foro |
| collection | DOAJ |
| description | In the crystal structure of the title compound, C11H12ClNO3, the asymmetric unit contains two independent molecules. The N—H bond in the amide segment is anti to the meta-Cl atom in the benzene ring, in both molecules. The amide and carboxyl C=O bonds are also anti to each other and anti to the H atoms on the adjacent –CH2 groups. Furthermore, the C=O and O—H bonds of the acid group are in syn positions with respect to each other. The dihedral angles between the benzene ring and the amide group are 40.6 (2) and 44.9 (3)° in the two independent molecules. In the crystal, molecules are packed into sheets parallel to the (11-3) plane through O—H...O and N—H...O hydrogen bonds. |
| first_indexed | 2024-12-22T02:12:51Z |
| format | Article |
| id | doaj.art-d67b9a2ca72944fe96dcb132522be8f1 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-22T02:12:51Z |
| publishDate | 2012-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-d67b9a2ca72944fe96dcb132522be8f12022-12-21T18:42:21ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-03-01683o835o83510.1107/S1600536812007623N-(3-Chloro-4-methylphenyl)succinamic acidSabine ForoU. ChaithanyaB. Thimme GowdaIn the crystal structure of the title compound, C11H12ClNO3, the asymmetric unit contains two independent molecules. The N—H bond in the amide segment is anti to the meta-Cl atom in the benzene ring, in both molecules. The amide and carboxyl C=O bonds are also anti to each other and anti to the H atoms on the adjacent –CH2 groups. Furthermore, the C=O and O—H bonds of the acid group are in syn positions with respect to each other. The dihedral angles between the benzene ring and the amide group are 40.6 (2) and 44.9 (3)° in the two independent molecules. In the crystal, molecules are packed into sheets parallel to the (11-3) plane through O—H...O and N—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536812007623 |
| spellingShingle | Sabine Foro U. Chaithanya B. Thimme Gowda N-(3-Chloro-4-methylphenyl)succinamic acid Acta Crystallographica Section E |
| title | N-(3-Chloro-4-methylphenyl)succinamic acid |
| title_full | N-(3-Chloro-4-methylphenyl)succinamic acid |
| title_fullStr | N-(3-Chloro-4-methylphenyl)succinamic acid |
| title_full_unstemmed | N-(3-Chloro-4-methylphenyl)succinamic acid |
| title_short | N-(3-Chloro-4-methylphenyl)succinamic acid |
| title_sort | n 3 chloro 4 methylphenyl succinamic acid |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812007623 |
| work_keys_str_mv | AT sabineforo n3chloro4methylphenylsuccinamicacid AT uchaithanya n3chloro4methylphenylsuccinamicacid AT bthimmegowda n3chloro4methylphenylsuccinamicacid |