Major, minor and trace element composition of cloudwater and rainwater at Plynlimon

The composition of cloudwater samples collected at Plynlimon, Mid Wales by the Institute of Hydrology is described based on one of the most comprehensive chemical records for deposition in the UK. Comparison with bulk rainwater samples for the same area demonstrates a tenfold enrichment of most elem...

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Main Authors: J. Wilkinson, B. Reynolds, C. Neal, S. Hill, M. Neal, M. Harrow
Format: Article
Language:English
Published: Copernicus Publications 1997-01-01
Series:Hydrology and Earth System Sciences
Online Access:http://www.hydrol-earth-syst-sci.net/1/557/1997/hess-1-557-1997.pdf
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author J. Wilkinson
B. Reynolds
B. Reynolds
C. Neal
S. Hill
M. Neal
M. Harrow
author_facet J. Wilkinson
B. Reynolds
B. Reynolds
C. Neal
S. Hill
M. Neal
M. Harrow
author_sort J. Wilkinson
collection DOAJ
description The composition of cloudwater samples collected at Plynlimon, Mid Wales by the Institute of Hydrology is described based on one of the most comprehensive chemical records for deposition in the UK. Comparison with bulk rainwater samples for the same area demonstrates a tenfold enrichment of most elements in cloudwater. Large variations in cloudwater composition occur due to variations in marine and terrestrial/anthropogenic sources, general weather patterns, atmospheric circulation and seasonal effects. All trace metal concentrations are associated with anthropogenic contamination. The lanthanides La, Cc and Pr, and Y are highly correlated in ratios associated with lithogenic sources and fossil fuel combustion. Outliers suggest the influence of catalysts used in the petrochemical cracking process. Plantation forestry significantly enhances the annual deposition of solutes from cloudwater; between 15 and 40% of most constituents to upland forested catchments and around 50% for NO<sub>3</sub>, B and Cd come from cloud deposition. In upland moorland areas, only 10% of the annual deposited load of inorganic constituents comes from cloudwater.
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spelling doaj.art-d6900b51b4b842b48b85e6c2e4ee7fb82022-12-22T03:51:20ZengCopernicus PublicationsHydrology and Earth System Sciences1027-56061607-79381997-01-0113557569Major, minor and trace element composition of cloudwater and rainwater at PlynlimonJ. WilkinsonB. ReynoldsB. ReynoldsC. NealS. HillM. NealM. HarrowThe composition of cloudwater samples collected at Plynlimon, Mid Wales by the Institute of Hydrology is described based on one of the most comprehensive chemical records for deposition in the UK. Comparison with bulk rainwater samples for the same area demonstrates a tenfold enrichment of most elements in cloudwater. Large variations in cloudwater composition occur due to variations in marine and terrestrial/anthropogenic sources, general weather patterns, atmospheric circulation and seasonal effects. All trace metal concentrations are associated with anthropogenic contamination. The lanthanides La, Cc and Pr, and Y are highly correlated in ratios associated with lithogenic sources and fossil fuel combustion. Outliers suggest the influence of catalysts used in the petrochemical cracking process. Plantation forestry significantly enhances the annual deposition of solutes from cloudwater; between 15 and 40% of most constituents to upland forested catchments and around 50% for NO<sub>3</sub>, B and Cd come from cloud deposition. In upland moorland areas, only 10% of the annual deposited load of inorganic constituents comes from cloudwater.http://www.hydrol-earth-syst-sci.net/1/557/1997/hess-1-557-1997.pdf
spellingShingle J. Wilkinson
B. Reynolds
B. Reynolds
C. Neal
S. Hill
M. Neal
M. Harrow
Major, minor and trace element composition of cloudwater and rainwater at Plynlimon
Hydrology and Earth System Sciences
title Major, minor and trace element composition of cloudwater and rainwater at Plynlimon
title_full Major, minor and trace element composition of cloudwater and rainwater at Plynlimon
title_fullStr Major, minor and trace element composition of cloudwater and rainwater at Plynlimon
title_full_unstemmed Major, minor and trace element composition of cloudwater and rainwater at Plynlimon
title_short Major, minor and trace element composition of cloudwater and rainwater at Plynlimon
title_sort major minor and trace element composition of cloudwater and rainwater at plynlimon
url http://www.hydrol-earth-syst-sci.net/1/557/1997/hess-1-557-1997.pdf
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