Liquid-liquid equilibrium constant for acetic acid in an olive oil-epoxidized olive oil-acetic acid-hydrogen peroxide-water system
The liquid-liquid equilibrium constant for acetic acid in a quinary system olive oil-epoxidized olive oil-acetic acid-hydrogen peroxide-water was experimentally determined for temperatures and component ratios relevant for in situ epoxidation of plant oils. The values has the constant range...
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| Format: | Article |
| Language: | English |
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Association of Chemical Engineers of Serbia
2016-01-01
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| Series: | Hemijska Industrija |
| Subjects: | |
| Online Access: | http://www.doiserbia.nb.rs/img/doi/0367-598X/2016/0367-598X1500024J.pdf |
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| author | Janković Milovan R. Govedarica Olga M. Sinadinović-Fišer Snežana V. Pavličević Jelena M. Teofilović Vesna B. Vukić Nevena R. |
| author_facet | Janković Milovan R. Govedarica Olga M. Sinadinović-Fišer Snežana V. Pavličević Jelena M. Teofilović Vesna B. Vukić Nevena R. |
| author_sort | Janković Milovan R. |
| collection | DOAJ |
| description | The liquid-liquid equilibrium constant for acetic acid in a quinary system
olive oil-epoxidized olive oil-acetic acid-hydrogen peroxide-water was
experimentally determined for temperatures and component ratios relevant for
in situ epoxidation of plant oils. The values has the constant range from
1.52 to 2.73. To predict the equilibrium constant for acetic acid, the
experimental data were correlated with UNIQUAC (universal quasi chemical) and
NRTL (non-random two liquid) activity coefficient models. For simplified
calculation of the phase equilibrium the insolubility of olive oil and
epoxidized olive oil in the water, as well as insolubility of water and
hydrogen peroxide in the olive oil and epoxidized olive oil, was assumed. The
root mean square deviation (RMSD) of the experimental and calculated values
of the liquid-liquid equilibrium constant for acetic acid is 0.1910 for the
UNIQUAC model and 0.1815 for the NRTL model. For rigorous flash calculation,
when the partitioning of all components between the phases was assumed, the
RMSD for the NRTL model is 0.1749. [Projekat Ministarstva nauke Republike
Srbije, br. 45022] |
| first_indexed | 2024-12-11T04:52:50Z |
| format | Article |
| id | doaj.art-d694613e0f3644ac9d6a2d963af9b320 |
| institution | Directory Open Access Journal |
| issn | 0367-598X 2217-7426 |
| language | English |
| last_indexed | 2024-12-11T04:52:50Z |
| publishDate | 2016-01-01 |
| publisher | Association of Chemical Engineers of Serbia |
| record_format | Article |
| series | Hemijska Industrija |
| spelling | doaj.art-d694613e0f3644ac9d6a2d963af9b3202022-12-22T01:20:20ZengAssociation of Chemical Engineers of SerbiaHemijska Industrija0367-598X2217-74262016-01-0170216517510.2298/HEMIND141210024J0367-598X1500024JLiquid-liquid equilibrium constant for acetic acid in an olive oil-epoxidized olive oil-acetic acid-hydrogen peroxide-water systemJanković Milovan R.0Govedarica Olga M.1Sinadinović-Fišer Snežana V.2Pavličević Jelena M.3Teofilović Vesna B.4Vukić Nevena R.5Faculty of Technology, Novi SadFaculty of Technology, Novi SadFaculty of Technology, Novi SadFaculty of Technology, Novi SadFaculty of Technology, Novi SadFaculty of Technology, Novi SadThe liquid-liquid equilibrium constant for acetic acid in a quinary system olive oil-epoxidized olive oil-acetic acid-hydrogen peroxide-water was experimentally determined for temperatures and component ratios relevant for in situ epoxidation of plant oils. The values has the constant range from 1.52 to 2.73. To predict the equilibrium constant for acetic acid, the experimental data were correlated with UNIQUAC (universal quasi chemical) and NRTL (non-random two liquid) activity coefficient models. For simplified calculation of the phase equilibrium the insolubility of olive oil and epoxidized olive oil in the water, as well as insolubility of water and hydrogen peroxide in the olive oil and epoxidized olive oil, was assumed. The root mean square deviation (RMSD) of the experimental and calculated values of the liquid-liquid equilibrium constant for acetic acid is 0.1910 for the UNIQUAC model and 0.1815 for the NRTL model. For rigorous flash calculation, when the partitioning of all components between the phases was assumed, the RMSD for the NRTL model is 0.1749. [Projekat Ministarstva nauke Republike Srbije, br. 45022]http://www.doiserbia.nb.rs/img/doi/0367-598X/2016/0367-598X1500024J.pdfliquid-liquid equilibriumacetic acidplant oilepoxidation |
| spellingShingle | Janković Milovan R. Govedarica Olga M. Sinadinović-Fišer Snežana V. Pavličević Jelena M. Teofilović Vesna B. Vukić Nevena R. Liquid-liquid equilibrium constant for acetic acid in an olive oil-epoxidized olive oil-acetic acid-hydrogen peroxide-water system Hemijska Industrija liquid-liquid equilibrium acetic acid plant oil epoxidation |
| title | Liquid-liquid equilibrium constant for acetic acid in an olive oil-epoxidized olive oil-acetic acid-hydrogen peroxide-water system |
| title_full | Liquid-liquid equilibrium constant for acetic acid in an olive oil-epoxidized olive oil-acetic acid-hydrogen peroxide-water system |
| title_fullStr | Liquid-liquid equilibrium constant for acetic acid in an olive oil-epoxidized olive oil-acetic acid-hydrogen peroxide-water system |
| title_full_unstemmed | Liquid-liquid equilibrium constant for acetic acid in an olive oil-epoxidized olive oil-acetic acid-hydrogen peroxide-water system |
| title_short | Liquid-liquid equilibrium constant for acetic acid in an olive oil-epoxidized olive oil-acetic acid-hydrogen peroxide-water system |
| title_sort | liquid liquid equilibrium constant for acetic acid in an olive oil epoxidized olive oil acetic acid hydrogen peroxide water system |
| topic | liquid-liquid equilibrium acetic acid plant oil epoxidation |
| url | http://www.doiserbia.nb.rs/img/doi/0367-598X/2016/0367-598X1500024J.pdf |
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