Oxidation-Affected Erosion of Porous Ni-Al Intermetallic Alloy in Combustion Applications: Pore-Scale Simulation

Advanced high-temperature oxidation resistance is a crucial characteristic of metallic materials in porous burners. Extreme combustion conditions could lead to oxidation-affected erosion of porous media at a long-time period of burner operation. In this paper, we numerically simulated oxide scale gr...

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Main Authors: Igor Yakovlev, Daniil Astakhov, Sergey Zambalov, Nikita Pichugin, Anatoly Maznoy
Format: Article
Language:English
Published: MDPI AG 2023-01-01
Series:Metals
Subjects:
Online Access:https://www.mdpi.com/2075-4701/13/2/277
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author Igor Yakovlev
Daniil Astakhov
Sergey Zambalov
Nikita Pichugin
Anatoly Maznoy
author_facet Igor Yakovlev
Daniil Astakhov
Sergey Zambalov
Nikita Pichugin
Anatoly Maznoy
author_sort Igor Yakovlev
collection DOAJ
description Advanced high-temperature oxidation resistance is a crucial characteristic of metallic materials in porous burners. Extreme combustion conditions could lead to oxidation-affected erosion of porous media at a long-time period of burner operation. In this paper, we numerically simulated oxide scale growth at a porous radiant burner fabricated by Ni-Al intermetallic alloy using the combustion synthesis method, focusing on the structure degradation caused by periodic oxide scale spallation. A three-dimensional geometrical model of a porous intermetallic scaffold was obtained by scanning the porous burner using the X-ray CT technique. The surface erosion was modeled by the surface reconstruction based on calculated values of spalled oxide layer thickness. The simulation revealed that the submerged flame results in non-uniform distribution of the temperature at the solid surface. Such non-isothermal conditions lead to a two-times thicker oxide scale at the external surface of the burner. Thin struts of the intermetallic scaffold are prone to oxidation-affected erosion first, which forms discontinues and further fragmentation. The porous scaffold could lose about 50% of initial weight before fragmentation under conditions with intense oxide spallation. In such large structural degradation, the average flow velocity could reduce by a factor of 3, leading to changing of flame stabilization region.
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spelling doaj.art-d6debf721f6244859bb80ca9f9b9682e2023-11-16T22:07:07ZengMDPI AGMetals2075-47012023-01-0113227710.3390/met13020277Oxidation-Affected Erosion of Porous Ni-Al Intermetallic Alloy in Combustion Applications: Pore-Scale SimulationIgor Yakovlev0Daniil Astakhov1Sergey Zambalov2Nikita Pichugin3Anatoly Maznoy4Tomsk Scientific Center of the Siberian Branch of the Russian Academy of Sciences, 10/4, Akademicheskii Prospekt, 634055 Tomsk, RussiaTomsk Scientific Center of the Siberian Branch of the Russian Academy of Sciences, 10/4, Akademicheskii Prospekt, 634055 Tomsk, RussiaTomsk Scientific Center of the Siberian Branch of the Russian Academy of Sciences, 10/4, Akademicheskii Prospekt, 634055 Tomsk, RussiaTomsk Scientific Center of the Siberian Branch of the Russian Academy of Sciences, 10/4, Akademicheskii Prospekt, 634055 Tomsk, RussiaTomsk Scientific Center of the Siberian Branch of the Russian Academy of Sciences, 10/4, Akademicheskii Prospekt, 634055 Tomsk, RussiaAdvanced high-temperature oxidation resistance is a crucial characteristic of metallic materials in porous burners. Extreme combustion conditions could lead to oxidation-affected erosion of porous media at a long-time period of burner operation. In this paper, we numerically simulated oxide scale growth at a porous radiant burner fabricated by Ni-Al intermetallic alloy using the combustion synthesis method, focusing on the structure degradation caused by periodic oxide scale spallation. A three-dimensional geometrical model of a porous intermetallic scaffold was obtained by scanning the porous burner using the X-ray CT technique. The surface erosion was modeled by the surface reconstruction based on calculated values of spalled oxide layer thickness. The simulation revealed that the submerged flame results in non-uniform distribution of the temperature at the solid surface. Such non-isothermal conditions lead to a two-times thicker oxide scale at the external surface of the burner. Thin struts of the intermetallic scaffold are prone to oxidation-affected erosion first, which forms discontinues and further fragmentation. The porous scaffold could lose about 50% of initial weight before fragmentation under conditions with intense oxide spallation. In such large structural degradation, the average flow velocity could reduce by a factor of 3, leading to changing of flame stabilization region.https://www.mdpi.com/2075-4701/13/2/277high temperature oxidationerosionpore-scale simulationcombustion synthesisNi-Alintermetallic alloy
spellingShingle Igor Yakovlev
Daniil Astakhov
Sergey Zambalov
Nikita Pichugin
Anatoly Maznoy
Oxidation-Affected Erosion of Porous Ni-Al Intermetallic Alloy in Combustion Applications: Pore-Scale Simulation
Metals
high temperature oxidation
erosion
pore-scale simulation
combustion synthesis
Ni-Al
intermetallic alloy
title Oxidation-Affected Erosion of Porous Ni-Al Intermetallic Alloy in Combustion Applications: Pore-Scale Simulation
title_full Oxidation-Affected Erosion of Porous Ni-Al Intermetallic Alloy in Combustion Applications: Pore-Scale Simulation
title_fullStr Oxidation-Affected Erosion of Porous Ni-Al Intermetallic Alloy in Combustion Applications: Pore-Scale Simulation
title_full_unstemmed Oxidation-Affected Erosion of Porous Ni-Al Intermetallic Alloy in Combustion Applications: Pore-Scale Simulation
title_short Oxidation-Affected Erosion of Porous Ni-Al Intermetallic Alloy in Combustion Applications: Pore-Scale Simulation
title_sort oxidation affected erosion of porous ni al intermetallic alloy in combustion applications pore scale simulation
topic high temperature oxidation
erosion
pore-scale simulation
combustion synthesis
Ni-Al
intermetallic alloy
url https://www.mdpi.com/2075-4701/13/2/277
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AT sergeyzambalov oxidationaffectederosionofporousnialintermetallicalloyincombustionapplicationsporescalesimulation
AT nikitapichugin oxidationaffectederosionofporousnialintermetallicalloyincombustionapplicationsporescalesimulation
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