Dichlorido(o-phenylenediamine)palladium(II)
The PdII atom in the title compound, [PdCl2{(C6H4)(NH2)2}], lies on a twofold rotation axis and has a square-planar coordination environment defined by two N atoms of an o-phenylenediamine ligand and two Cl− ions. In the crystal, the planar Pd complex molecules are stacked parallel to the c axis, re...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2017-02-01
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| Series: | IUCrData |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314617001444 |
| Summary: | The PdII atom in the title compound, [PdCl2{(C6H4)(NH2)2}], lies on a twofold rotation axis and has a square-planar coordination environment defined by two N atoms of an o-phenylenediamine ligand and two Cl− ions. In the crystal, the planar Pd complex molecules are stacked parallel to the c axis, resulting in a columnar structure. In the column, an infinite almost straight Pd chain is formed, suggesting weak metal–metal interactions. The crystal packing is stabilized by a three-dimensional N—H...Cl hydrogen-bonding network between the amino groups and the Cl ligands of adjacent molecules. |
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| ISSN: | 2414-3146 |