Recent Advances in Molecular-Imprinting-Based Solid-Phase Extraction of Antibiotics Residues Coupled With Chromatographic Analysis
Abuse and residues of antibiotics cause great harm to organisms and the environment. Appropriate sample pretreatment is usually required for sensitive determination, because of the low content presence of a variety of antibiotics in complicated matrices. Molecular-imprinting-based solid-phase extrac...
| Main Authors: | , , , , , , , , , |
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| Format: | Article |
| Language: | English |
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Frontiers Media S.A.
2021-08-01
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| Series: | Frontiers in Environmental Chemistry |
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| Online Access: | https://www.frontiersin.org/articles/10.3389/fenvc.2021.703961/full |
| _version_ | 1797966793415852032 |
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| author | Dani Sun Dani Sun Zhihua Song Yue Zhang Yue Zhang Yixiao Wang Yixiao Wang Min Lv Huitao Liu Liyan Wang Liyan Wang Wenhui Lu Jinhua Li Jinhua Li Jinhua Li Lingxin Chen Lingxin Chen |
| author_facet | Dani Sun Dani Sun Zhihua Song Yue Zhang Yue Zhang Yixiao Wang Yixiao Wang Min Lv Huitao Liu Liyan Wang Liyan Wang Wenhui Lu Jinhua Li Jinhua Li Jinhua Li Lingxin Chen Lingxin Chen |
| author_sort | Dani Sun |
| collection | DOAJ |
| description | Abuse and residues of antibiotics cause great harm to organisms and the environment. Appropriate sample pretreatment is usually required for sensitive determination, because of the low content presence of a variety of antibiotics in complicated matrices. Molecular-imprinting-based solid-phase extraction (MISPE) has been widely used for sample pretreatment of antibiotics, using molecularly imprinted polymers (MIPs) as adsorbents. Herein, we comprehensively review the recent advances of MISPE of antibiotics, followed by chromatographic analysis. Various solid-phase extraction (SPE) modes based on MIPs are briefly introduced, such as conventional SPE, dispersive SPE, magnetic SPE, matrix solid-phase dispersion, and pipette-tip SPE. Then, several emerging preparation techniques for antibiotics MIPs are summarized including surface imprinting, nanoimprinting, living/controlled radical polymerization, multitemplate imprinting, multifunctional monomer imprinting, and dummy template imprinting. Subsequently, applications of MISPE to analysis of a variety of antibiotics residues since 2018 are overviewed, including sulfonamides, quinolones, tetracycline, and others. Finally, the preparation and application of antibiotics MIPs are prospected. |
| first_indexed | 2024-04-11T02:19:49Z |
| format | Article |
| id | doaj.art-d71bad0415d64f3a93bf0d6ea731d805 |
| institution | Directory Open Access Journal |
| issn | 2673-4486 |
| language | English |
| last_indexed | 2024-04-11T02:19:49Z |
| publishDate | 2021-08-01 |
| publisher | Frontiers Media S.A. |
| record_format | Article |
| series | Frontiers in Environmental Chemistry |
| spelling | doaj.art-d71bad0415d64f3a93bf0d6ea731d8052023-01-03T00:12:15ZengFrontiers Media S.A.Frontiers in Environmental Chemistry2673-44862021-08-01210.3389/fenvc.2021.703961703961Recent Advances in Molecular-Imprinting-Based Solid-Phase Extraction of Antibiotics Residues Coupled With Chromatographic AnalysisDani Sun0Dani Sun1Zhihua Song2Yue Zhang3Yue Zhang4Yixiao Wang5Yixiao Wang6Min Lv7Huitao Liu8Liyan Wang9Liyan Wang10Wenhui Lu11Jinhua Li12Jinhua Li13Jinhua Li14Lingxin Chen15Lingxin Chen16College of Chemistry and Chemical Engineering, Yantai University, Yantai, ChinaCAS Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Shandong Key Laboratory of Coastal Environmental Processes, Research Center for Coastal Environmental Engineering and Technology, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai, ChinaSchool of Pharmacy, Collaborative Innovation Center of Advanced Drug Delivery System and Biotech Drugs in Universities of Shandong, Key Laboratory of Molecular Pharmacology and Drug Evaluation (Yantai University), Ministry of Education, Yantai University, Yantai, ChinaCAS Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Shandong Key Laboratory of Coastal Environmental Processes, Research Center for Coastal Environmental Engineering and Technology, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai, ChinaSchool of Pharmacy, Collaborative Innovation Center of Advanced Drug Delivery System and Biotech Drugs in Universities of Shandong, Key Laboratory of Molecular Pharmacology and Drug Evaluation (Yantai University), Ministry of Education, Yantai University, Yantai, ChinaCAS Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Shandong Key Laboratory of Coastal Environmental Processes, Research Center for Coastal Environmental Engineering and Technology, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai, ChinaSchool of Source and Environment, University of Chinese Academy of Sciences, Beijing, ChinaCAS Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Shandong Key Laboratory of Coastal Environmental Processes, Research Center for Coastal Environmental Engineering and Technology, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai, ChinaCollege of Chemistry and Chemical Engineering, Yantai University, Yantai, ChinaCAS Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Shandong Key Laboratory of Coastal Environmental Processes, Research Center for Coastal Environmental Engineering and Technology, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai, ChinaSchool of Source and Environment, University of Chinese Academy of Sciences, Beijing, ChinaSchool of Light Industry and Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, ChinaCollege of Chemistry and Chemical Engineering, Yantai University, Yantai, ChinaCAS Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Shandong Key Laboratory of Coastal Environmental Processes, Research Center for Coastal Environmental Engineering and Technology, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai, ChinaSchool of Source and Environment, University of Chinese Academy of Sciences, Beijing, ChinaCAS Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Shandong Key Laboratory of Coastal Environmental Processes, Research Center for Coastal Environmental Engineering and Technology, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai, ChinaSchool of Source and Environment, University of Chinese Academy of Sciences, Beijing, ChinaAbuse and residues of antibiotics cause great harm to organisms and the environment. Appropriate sample pretreatment is usually required for sensitive determination, because of the low content presence of a variety of antibiotics in complicated matrices. Molecular-imprinting-based solid-phase extraction (MISPE) has been widely used for sample pretreatment of antibiotics, using molecularly imprinted polymers (MIPs) as adsorbents. Herein, we comprehensively review the recent advances of MISPE of antibiotics, followed by chromatographic analysis. Various solid-phase extraction (SPE) modes based on MIPs are briefly introduced, such as conventional SPE, dispersive SPE, magnetic SPE, matrix solid-phase dispersion, and pipette-tip SPE. Then, several emerging preparation techniques for antibiotics MIPs are summarized including surface imprinting, nanoimprinting, living/controlled radical polymerization, multitemplate imprinting, multifunctional monomer imprinting, and dummy template imprinting. Subsequently, applications of MISPE to analysis of a variety of antibiotics residues since 2018 are overviewed, including sulfonamides, quinolones, tetracycline, and others. Finally, the preparation and application of antibiotics MIPs are prospected.https://www.frontiersin.org/articles/10.3389/fenvc.2021.703961/fullmolecularly imprinted polymersantibioticssample preparationsolid-phase extractionreviewimprinting technique |
| spellingShingle | Dani Sun Dani Sun Zhihua Song Yue Zhang Yue Zhang Yixiao Wang Yixiao Wang Min Lv Huitao Liu Liyan Wang Liyan Wang Wenhui Lu Jinhua Li Jinhua Li Jinhua Li Lingxin Chen Lingxin Chen Recent Advances in Molecular-Imprinting-Based Solid-Phase Extraction of Antibiotics Residues Coupled With Chromatographic Analysis Frontiers in Environmental Chemistry molecularly imprinted polymers antibiotics sample preparation solid-phase extraction review imprinting technique |
| title | Recent Advances in Molecular-Imprinting-Based Solid-Phase Extraction of Antibiotics Residues Coupled With Chromatographic Analysis |
| title_full | Recent Advances in Molecular-Imprinting-Based Solid-Phase Extraction of Antibiotics Residues Coupled With Chromatographic Analysis |
| title_fullStr | Recent Advances in Molecular-Imprinting-Based Solid-Phase Extraction of Antibiotics Residues Coupled With Chromatographic Analysis |
| title_full_unstemmed | Recent Advances in Molecular-Imprinting-Based Solid-Phase Extraction of Antibiotics Residues Coupled With Chromatographic Analysis |
| title_short | Recent Advances in Molecular-Imprinting-Based Solid-Phase Extraction of Antibiotics Residues Coupled With Chromatographic Analysis |
| title_sort | recent advances in molecular imprinting based solid phase extraction of antibiotics residues coupled with chromatographic analysis |
| topic | molecularly imprinted polymers antibiotics sample preparation solid-phase extraction review imprinting technique |
| url | https://www.frontiersin.org/articles/10.3389/fenvc.2021.703961/full |
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