Efficient Recovery of Cu from Wasted CPU Sockets by Slurry Electrolysis

In order to maximize the reuse of used electronic component resources, while reducing environmental pollution, Cu metal was recycled from wasted CPU sockets by the reformative slurry electrolysis method. However, the influences on the regulation of the Cu recovery rate and purity from waste CPU slot...

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Main Authors: Wenjing Chen, Manning Li, Jiancheng Tang
Format: Article
Language:English
Published: MDPI AG 2023-03-01
Series:Metals
Subjects:
Online Access:https://www.mdpi.com/2075-4701/13/4/643
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author Wenjing Chen
Manning Li
Jiancheng Tang
author_facet Wenjing Chen
Manning Li
Jiancheng Tang
author_sort Wenjing Chen
collection DOAJ
description In order to maximize the reuse of used electronic component resources, while reducing environmental pollution, Cu metal was recycled from wasted CPU sockets by the reformative slurry electrolysis method. However, the influences on the regulation of the Cu recovery rate and purity from waste CPU slots, by slurry electrolysis, has not been systematically elucidated in previous studies. In this work, the effects of H<sub>2</sub>SO<sub>4</sub> concentration, slurry density, NH<sub>4</sub>Cl concentration, current density, and reaction time, on the recovery rate and purity of Cu in slurry electrolysis, were researched by systematic experimental methods. The results showed that the recycled metal elements were mainly present as powders from the cathode, rather than in the electrolyte. Moreover, the metallic elements in the cathode powder consisted of mostly Cu and small amounts of Sn and Ni. The recovery rate and purity of Cu were up to 96.19% and 93.72%, respectively, with the optimum conditions being: an H<sub>2</sub>SO<sub>4</sub> concentration of 2 mol/L, slurry density of 30 g/L, NH<sub>4</sub>Cl concentration of 90 g/L, current density of 80 mA/cm<sup>2</sup>, and reaction time of 7 h. Compared with previous studies, the Cu recovered in this experiment was present in the cathode powder, which was more convenient for the subsequent processing. Meanwhile, the recovery rate of Cu was effectively improved. This is an important guideline for the subsequent application of slurry electrolysis for Cu recovery.
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spelling doaj.art-d72ff31f219147d89008c2bbe06316ee2023-11-17T20:25:35ZengMDPI AGMetals2075-47012023-03-0113464310.3390/met13040643Efficient Recovery of Cu from Wasted CPU Sockets by Slurry ElectrolysisWenjing Chen0Manning Li1Jiancheng Tang2School of Physics and Materials Science, Nanchang University, Nanchang 330031, ChinaSchool of Advanced Manufacturing, Nanchang University, Nanchang 330031, ChinaSchool of Physics and Materials Science, Nanchang University, Nanchang 330031, ChinaIn order to maximize the reuse of used electronic component resources, while reducing environmental pollution, Cu metal was recycled from wasted CPU sockets by the reformative slurry electrolysis method. However, the influences on the regulation of the Cu recovery rate and purity from waste CPU slots, by slurry electrolysis, has not been systematically elucidated in previous studies. In this work, the effects of H<sub>2</sub>SO<sub>4</sub> concentration, slurry density, NH<sub>4</sub>Cl concentration, current density, and reaction time, on the recovery rate and purity of Cu in slurry electrolysis, were researched by systematic experimental methods. The results showed that the recycled metal elements were mainly present as powders from the cathode, rather than in the electrolyte. Moreover, the metallic elements in the cathode powder consisted of mostly Cu and small amounts of Sn and Ni. The recovery rate and purity of Cu were up to 96.19% and 93.72%, respectively, with the optimum conditions being: an H<sub>2</sub>SO<sub>4</sub> concentration of 2 mol/L, slurry density of 30 g/L, NH<sub>4</sub>Cl concentration of 90 g/L, current density of 80 mA/cm<sup>2</sup>, and reaction time of 7 h. Compared with previous studies, the Cu recovered in this experiment was present in the cathode powder, which was more convenient for the subsequent processing. Meanwhile, the recovery rate of Cu was effectively improved. This is an important guideline for the subsequent application of slurry electrolysis for Cu recovery.https://www.mdpi.com/2075-4701/13/4/643wasted CPU socketslurry electrolysisrecovery rate of Cupurity of Cucurrent densityslurry density
spellingShingle Wenjing Chen
Manning Li
Jiancheng Tang
Efficient Recovery of Cu from Wasted CPU Sockets by Slurry Electrolysis
Metals
wasted CPU socket
slurry electrolysis
recovery rate of Cu
purity of Cu
current density
slurry density
title Efficient Recovery of Cu from Wasted CPU Sockets by Slurry Electrolysis
title_full Efficient Recovery of Cu from Wasted CPU Sockets by Slurry Electrolysis
title_fullStr Efficient Recovery of Cu from Wasted CPU Sockets by Slurry Electrolysis
title_full_unstemmed Efficient Recovery of Cu from Wasted CPU Sockets by Slurry Electrolysis
title_short Efficient Recovery of Cu from Wasted CPU Sockets by Slurry Electrolysis
title_sort efficient recovery of cu from wasted cpu sockets by slurry electrolysis
topic wasted CPU socket
slurry electrolysis
recovery rate of Cu
purity of Cu
current density
slurry density
url https://www.mdpi.com/2075-4701/13/4/643
work_keys_str_mv AT wenjingchen efficientrecoveryofcufromwastedcpusocketsbyslurryelectrolysis
AT manningli efficientrecoveryofcufromwastedcpusocketsbyslurryelectrolysis
AT jianchengtang efficientrecoveryofcufromwastedcpusocketsbyslurryelectrolysis