Synthesis, characterization, thermal
This work explains the synthesis of a new azo-Schiff base compound, derived from condensation between N-ethylcarbazole-3-carbaldehyde and 1,3-diaminopropane, followed by azo coupling reaction with the diazonium salt of 2-amino-4-methyl phenol. The newly synthesized azo-Schiff base was further reacte...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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Elsevier
2017-09-01
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| Series: | Arabian Journal of Chemistry |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S187853521500324X |
| _version_ | 1818479733259632640 |
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| author | Selma Bal Joseph Donald Connolly |
| author_facet | Selma Bal Joseph Donald Connolly |
| author_sort | Selma Bal |
| collection | DOAJ |
| description | This work explains the synthesis of a new azo-Schiff base compound, derived from condensation between N-ethylcarbazole-3-carbaldehyde and 1,3-diaminopropane, followed by azo coupling reaction with the diazonium salt of 2-amino-4-methyl phenol. The newly synthesized azo-Schiff base was further reacted with the acetate salts of Copper, Cobalt and Nickel to give three coordination compounds. All synthesized compounds have been characterized through spectral analysis. The coordination compounds have been examined for their thermal and catalytic features. Good and moderate yields were obtained for the oxidation of styrene and cyclohexene. Thermal features of the ligand and its complexes have been explained and the results obtained have supported the proposed structures. |
| first_indexed | 2024-12-10T11:14:39Z |
| format | Article |
| id | doaj.art-d773b34613d24041bb5fe2642a869060 |
| institution | Directory Open Access Journal |
| issn | 1878-5352 |
| language | English |
| last_indexed | 2024-12-10T11:14:39Z |
| publishDate | 2017-09-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Arabian Journal of Chemistry |
| spelling | doaj.art-d773b34613d24041bb5fe2642a8690602022-12-22T01:51:15ZengElsevierArabian Journal of Chemistry1878-53522017-09-0110676176810.1016/j.arabjc.2015.11.012Synthesis, characterization, thermalSelma Bal0Joseph Donald Connolly1Department of Chemistry, Kahramanmaras Sutcu Imam University, Kahramanmaras 46100, TurkeyChemistry Department, Glasgow University, Joseph Black Building, G12 8QQ, United KingdomThis work explains the synthesis of a new azo-Schiff base compound, derived from condensation between N-ethylcarbazole-3-carbaldehyde and 1,3-diaminopropane, followed by azo coupling reaction with the diazonium salt of 2-amino-4-methyl phenol. The newly synthesized azo-Schiff base was further reacted with the acetate salts of Copper, Cobalt and Nickel to give three coordination compounds. All synthesized compounds have been characterized through spectral analysis. The coordination compounds have been examined for their thermal and catalytic features. Good and moderate yields were obtained for the oxidation of styrene and cyclohexene. Thermal features of the ligand and its complexes have been explained and the results obtained have supported the proposed structures.http://www.sciencedirect.com/science/article/pii/S187853521500324XAzo-imine ligandComplexThermalCatalysis |
| spellingShingle | Selma Bal Joseph Donald Connolly Synthesis, characterization, thermal Arabian Journal of Chemistry Azo-imine ligand Complex Thermal Catalysis |
| title | Synthesis, characterization, thermal |
| title_full | Synthesis, characterization, thermal |
| title_fullStr | Synthesis, characterization, thermal |
| title_full_unstemmed | Synthesis, characterization, thermal |
| title_short | Synthesis, characterization, thermal |
| title_sort | synthesis characterization thermal |
| topic | Azo-imine ligand Complex Thermal Catalysis |
| url | http://www.sciencedirect.com/science/article/pii/S187853521500324X |
| work_keys_str_mv | AT selmabal synthesischaracterizationthermal AT josephdonaldconnolly synthesischaracterizationthermal |