Nitratotris(triphenylphosphine)copper(I) methanol solvate

The title compound, [Cu(NO3)(C18H15P)3]·CH3OH, is a methanol solvate derivative of nitratotris(triphenylphosphine)copper(I). The complex crystallizes with three triphenylphosphine ligands coordinated to the copper centre, with an O—H...O hydrogen bond observed between the...

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Bibliographic Details
Format: Article
Language:English
Published: International Union of Crystallography 2009-03-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809004620
Description
Summary:The title compound, [Cu(NO3)(C18H15P)3]·CH3OH, is a methanol solvate derivative of nitratotris(triphenylphosphine)copper(I). The complex crystallizes with three triphenylphosphine ligands coordinated to the copper centre, with an O—H...O hydrogen bond observed between the nitrate ligand and the methanol solvent molecule. The coordination around the CuI centre is distorted tetrahedral.
ISSN:1600-5368