Nitratotris(triphenylphosphine)copper(I) methanol solvate
The title compound, [Cu(NO3)(C18H15P)3]·CH3OH, is a methanol solvate derivative of nitratotris(triphenylphosphine)copper(I). The complex crystallizes with three triphenylphosphine ligands coordinated to the copper centre, with an O—H...O hydrogen bond observed between the...
Format: | Article |
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Language: | English |
Published: |
International Union of Crystallography
2009-03-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809004620 |
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collection | DOAJ |
description | The title compound, [Cu(NO3)(C18H15P)3]·CH3OH, is a methanol solvate derivative of nitratotris(triphenylphosphine)copper(I). The complex crystallizes with three triphenylphosphine ligands coordinated to the copper centre, with an O—H...O hydrogen bond observed between the nitrate ligand and the methanol solvent molecule. The coordination around the CuI centre is distorted tetrahedral. |
first_indexed | 2024-12-18T15:16:28Z |
format | Article |
id | doaj.art-d78e633280ee4dbebcd0d92e2245b563 |
institution | Directory Open Access Journal |
issn | 1600-5368 |
language | English |
last_indexed | 2024-12-18T15:16:28Z |
publishDate | 2009-03-01 |
publisher | International Union of Crystallography |
record_format | Article |
series | Acta Crystallographica Section E |
spelling | doaj.art-d78e633280ee4dbebcd0d92e2245b5632022-12-21T21:03:30ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-03-01653m272m27210.1107/S1600536809004620Nitratotris(triphenylphosphine)copper(I) methanol solvateThe title compound, [Cu(NO3)(C18H15P)3]·CH3OH, is a methanol solvate derivative of nitratotris(triphenylphosphine)copper(I). The complex crystallizes with three triphenylphosphine ligands coordinated to the copper centre, with an O—H...O hydrogen bond observed between the nitrate ligand and the methanol solvent molecule. The coordination around the CuI centre is distorted tetrahedral.http://scripts.iucr.org/cgi-bin/paper?S1600536809004620 |
spellingShingle | Nitratotris(triphenylphosphine)copper(I) methanol solvate Acta Crystallographica Section E |
title | Nitratotris(triphenylphosphine)copper(I) methanol solvate |
title_full | Nitratotris(triphenylphosphine)copper(I) methanol solvate |
title_fullStr | Nitratotris(triphenylphosphine)copper(I) methanol solvate |
title_full_unstemmed | Nitratotris(triphenylphosphine)copper(I) methanol solvate |
title_short | Nitratotris(triphenylphosphine)copper(I) methanol solvate |
title_sort | nitratotris triphenylphosphine copper i methanol solvate |
url | http://scripts.iucr.org/cgi-bin/paper?S1600536809004620 |