Nitratotris(triphenylphosphine)copper(I) methanol solvate

The title compound, [Cu(NO3)(C18H15P)3]·CH3OH, is a methanol solvate derivative of nitratotris(triphenylphosphine)copper(I). The complex crystallizes with three triphenylphosphine ligands coordinated to the copper centre, with an O—H...O hydrogen bond observed between the...

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Format: Article
Language:English
Published: International Union of Crystallography 2009-03-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809004620
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collection DOAJ
description The title compound, [Cu(NO3)(C18H15P)3]·CH3OH, is a methanol solvate derivative of nitratotris(triphenylphosphine)copper(I). The complex crystallizes with three triphenylphosphine ligands coordinated to the copper centre, with an O—H...O hydrogen bond observed between the nitrate ligand and the methanol solvent molecule. The coordination around the CuI centre is distorted tetrahedral.
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spelling doaj.art-d78e633280ee4dbebcd0d92e2245b5632022-12-21T21:03:30ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-03-01653m272m27210.1107/S1600536809004620Nitratotris(triphenylphosphine)copper(I) methanol solvateThe title compound, [Cu(NO3)(C18H15P)3]·CH3OH, is a methanol solvate derivative of nitratotris(triphenylphosphine)copper(I). The complex crystallizes with three triphenylphosphine ligands coordinated to the copper centre, with an O—H...O hydrogen bond observed between the nitrate ligand and the methanol solvent molecule. The coordination around the CuI centre is distorted tetrahedral.http://scripts.iucr.org/cgi-bin/paper?S1600536809004620
spellingShingle Nitratotris(triphenylphosphine)copper(I) methanol solvate
Acta Crystallographica Section E
title Nitratotris(triphenylphosphine)copper(I) methanol solvate
title_full Nitratotris(triphenylphosphine)copper(I) methanol solvate
title_fullStr Nitratotris(triphenylphosphine)copper(I) methanol solvate
title_full_unstemmed Nitratotris(triphenylphosphine)copper(I) methanol solvate
title_short Nitratotris(triphenylphosphine)copper(I) methanol solvate
title_sort nitratotris triphenylphosphine copper i methanol solvate
url http://scripts.iucr.org/cgi-bin/paper?S1600536809004620