Recent applications of porphyrins as photocatalysts in organic synthesis: batch and continuous flow approaches
In this review we present relevant and recent applications of porphyrin derivatives as photocatalysts in organic synthesis, involving both single electron transfer (SET) and energy transfer (ET) mechanistic approaches. We demonstrate that these highly conjugated photosensitizers show increasing pote...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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Beilstein-Institut
2020-05-01
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| Series: | Beilstein Journal of Organic Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.3762/bjoc.16.83 |
| _version_ | 1818967116103024640 |
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| author | Rodrigo Costa e Silva Luely Oliveira da Silva Aloisio de Andrade Bartolomeu Timothy John Brocksom Kleber Thiago de Oliveira |
| author_facet | Rodrigo Costa e Silva Luely Oliveira da Silva Aloisio de Andrade Bartolomeu Timothy John Brocksom Kleber Thiago de Oliveira |
| author_sort | Rodrigo Costa e Silva |
| collection | DOAJ |
| description | In this review we present relevant and recent applications of porphyrin derivatives as photocatalysts in organic synthesis, involving both single electron transfer (SET) and energy transfer (ET) mechanistic approaches. We demonstrate that these highly conjugated photosensitizers show increasing potential in photocatalysis since they combine both photo- and electrochemical properties which can substitute available metalloorganic photocatalysts. Batch and continuous-flow approaches are presented highlighting the relevance of enabling technologies for the renewal of porphyrin applications in photocatalysis. Finally, the reaction scale in which the methodologies were developed are highlighted since this is an important parameter in the authors’ opinion. |
| first_indexed | 2024-12-20T13:43:40Z |
| format | Article |
| id | doaj.art-d7b6bc8baaec4ddbb39b563568da5b5d |
| institution | Directory Open Access Journal |
| issn | 1860-5397 |
| language | English |
| last_indexed | 2024-12-20T13:43:40Z |
| publishDate | 2020-05-01 |
| publisher | Beilstein-Institut |
| record_format | Article |
| series | Beilstein Journal of Organic Chemistry |
| spelling | doaj.art-d7b6bc8baaec4ddbb39b563568da5b5d2022-12-21T19:38:44ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972020-05-0116191795510.3762/bjoc.16.831860-5397-16-83Recent applications of porphyrins as photocatalysts in organic synthesis: batch and continuous flow approachesRodrigo Costa e Silva0Luely Oliveira da Silva1Aloisio de Andrade Bartolomeu2Timothy John Brocksom3Kleber Thiago de Oliveira4Departamento de Química, Universidade Federal de São Carlos, São Carlos, SP, 13565-905, BrazilDepartamento de Química, Universidade Federal de São Carlos, São Carlos, SP, 13565-905, BrazilDepartamento de Química, Universidade Federal de São Carlos, São Carlos, SP, 13565-905, BrazilDepartamento de Química, Universidade Federal de São Carlos, São Carlos, SP, 13565-905, BrazilDepartamento de Química, Universidade Federal de São Carlos, São Carlos, SP, 13565-905, BrazilIn this review we present relevant and recent applications of porphyrin derivatives as photocatalysts in organic synthesis, involving both single electron transfer (SET) and energy transfer (ET) mechanistic approaches. We demonstrate that these highly conjugated photosensitizers show increasing potential in photocatalysis since they combine both photo- and electrochemical properties which can substitute available metalloorganic photocatalysts. Batch and continuous-flow approaches are presented highlighting the relevance of enabling technologies for the renewal of porphyrin applications in photocatalysis. Finally, the reaction scale in which the methodologies were developed are highlighted since this is an important parameter in the authors’ opinion.https://doi.org/10.3762/bjoc.16.83energy transferphotocatalysisphotooxygenationphotoredoxporphyrins |
| spellingShingle | Rodrigo Costa e Silva Luely Oliveira da Silva Aloisio de Andrade Bartolomeu Timothy John Brocksom Kleber Thiago de Oliveira Recent applications of porphyrins as photocatalysts in organic synthesis: batch and continuous flow approaches Beilstein Journal of Organic Chemistry energy transfer photocatalysis photooxygenation photoredox porphyrins |
| title | Recent applications of porphyrins as photocatalysts in organic synthesis: batch and continuous flow approaches |
| title_full | Recent applications of porphyrins as photocatalysts in organic synthesis: batch and continuous flow approaches |
| title_fullStr | Recent applications of porphyrins as photocatalysts in organic synthesis: batch and continuous flow approaches |
| title_full_unstemmed | Recent applications of porphyrins as photocatalysts in organic synthesis: batch and continuous flow approaches |
| title_short | Recent applications of porphyrins as photocatalysts in organic synthesis: batch and continuous flow approaches |
| title_sort | recent applications of porphyrins as photocatalysts in organic synthesis batch and continuous flow approaches |
| topic | energy transfer photocatalysis photooxygenation photoredox porphyrins |
| url | https://doi.org/10.3762/bjoc.16.83 |
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