The Influence of Hydrogen on Structural and Magnetic Transformations in <i>R</i>Mn<sub>2</sub>H<i><sub>x</sub></i> Hydrides with Laves Phase C15 and C14 Structures—A Review

Laves phases crystallize in simple structures and are very common intermetallic phases that can form from combinations of elements throughout the periodic table, giving a huge number of known examples. A special feature of AB2 or AB5 phases is the ability to absorb hydrogen. This study attempts to c...

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Bibliographic Details
Main Authors: Andrzej Budziak, Joanna Szafraniec
Format: Article
Language:English
Published: MDPI AG 2023-10-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/16/21/7383
Description
Summary:Laves phases crystallize in simple structures and are very common intermetallic phases that can form from combinations of elements throughout the periodic table, giving a huge number of known examples. A special feature of AB2 or AB5 phases is the ability to absorb hydrogen. This study attempts to collect, systematize and summarize the knowledge about <i>R</i>Mn<sub>2</sub>H<i><sub>x</sub></i> (<i>R</i>: Tb, Gd, Ho, Dy, Er, Sm, Nd and Y) hydrides available in the literature that is mainly related to structural and magnetic transformations. Due to the enormous wealth of data, the analysis focused on hydrides with <i>x</i> < 4.5 H/f.u., i.e., hydrides obtained at relatively low pressure (less than a few bars). The hydrides obtained in this way can be treated as potential hydrogen stores, which undoubtedly accounts for their current attractiveness.
ISSN:1996-1073