Recent Synthetic Approaches Toward Non-anomeric Spiroketals in Natural Products

Recent Synthetic Approaches Toward Non-anomeric Spiroketals in Natural Products

Many natural products of biological interest contain [6,5]- and [6,6]-spiroketal moieties that can adopt various configurations, benefiting or not from anomeric conformation stabilizing effects. The spiroketal fragments are often important for the biological activity of the compounds containing them...

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Bibliographic Details
Main Authors: Sandrine Gerber-Lemaire, Pierre Vogel, Sylvain Favre
Format: Article
Language:English
Published: MDPI AG 2008-10-01
Series:Molecules
Subjects:
Spiroketal
anomeric interaction
non-anomeric interaction
thermodynamic equilibration
kinetic control
spirocyclization
anomeric effect
gauche effect
Online Access:http://www.mdpi.com/1420-3049/13/10/2570/

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