Effect of Dispersing Carbon Nanotube in Aqueous Solution by Poly-Carboxylic-Based Surfactants on Mechanical and Microstructural Properties as Cementitious Composites

The development of high-performance concrete using carbon nanotubes (CNTs), which is used in various industries owing to its excellent mechanical properties, has attracted much attention, leading to ongoing research in this area. However, when mixing CNTs into cement paste, there has been limited fo...

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Main Authors: Won-Woo Kim, Jae-Heum Moon, Seung-Tae Lee
Format: Article
Language:English
Published: MDPI AG 2023-10-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/16/21/6880
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author Won-Woo Kim
Jae-Heum Moon
Seung-Tae Lee
author_facet Won-Woo Kim
Jae-Heum Moon
Seung-Tae Lee
author_sort Won-Woo Kim
collection DOAJ
description The development of high-performance concrete using carbon nanotubes (CNTs), which is used in various industries owing to its excellent mechanical properties, has attracted much attention, leading to ongoing research in this area. However, when mixing CNTs into cement paste, there has been limited focus on the dispersibility, and, in most cases, aqueous dispersions of CNTs used in other industrial sectors are used. Because CNTs form the structures of bundles or aggregates owing to their high aspect ratio and van der Waals force between particles, the desired dispersibility cannot be obtained when mixing CNTs in powder form with other materials. Therefore, in this study, we examined the applicability of CNT aqueous dispersions using PC-based plasticizer used in concrete. Aqueous dispersions of CNT using PC-based surfactants are prepared and their properties are compared with those of a PVP-based aqueous dispersion. To analyze the mechanical properties, the compressive strength and flexural strength are measured on the 28th day. Then, the dispersibility and microstructure are analyzed using scanning electron microscopy image analysis, thermogravimetric analysis, and BET (Brunauer–Emmett–Teller) analysis. The analysis results show the enhancement of mechanical properties due to the mixing of the CNT dispersion, and the results confirm the applicability of the proposed CNT aqueous dispersions using PC-based surfactants.
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spelling doaj.art-d7e946608fde47a3a83ec20aaefd3bc82023-11-10T15:07:12ZengMDPI AGMaterials1996-19442023-10-011621688010.3390/ma16216880Effect of Dispersing Carbon Nanotube in Aqueous Solution by Poly-Carboxylic-Based Surfactants on Mechanical and Microstructural Properties as Cementitious CompositesWon-Woo Kim0Jae-Heum Moon1Seung-Tae Lee2KICT (Korea Institute of Civil Engineering and Building Technology), Goyang-si 10223, Republic of KoreaKICT (Korea Institute of Civil Engineering and Building Technology), Goyang-si 10223, Republic of KoreaDepartment of Civil Engineering, Kunsan National University, Gunsan-si 54150, Republic of KoreaThe development of high-performance concrete using carbon nanotubes (CNTs), which is used in various industries owing to its excellent mechanical properties, has attracted much attention, leading to ongoing research in this area. However, when mixing CNTs into cement paste, there has been limited focus on the dispersibility, and, in most cases, aqueous dispersions of CNTs used in other industrial sectors are used. Because CNTs form the structures of bundles or aggregates owing to their high aspect ratio and van der Waals force between particles, the desired dispersibility cannot be obtained when mixing CNTs in powder form with other materials. Therefore, in this study, we examined the applicability of CNT aqueous dispersions using PC-based plasticizer used in concrete. Aqueous dispersions of CNT using PC-based surfactants are prepared and their properties are compared with those of a PVP-based aqueous dispersion. To analyze the mechanical properties, the compressive strength and flexural strength are measured on the 28th day. Then, the dispersibility and microstructure are analyzed using scanning electron microscopy image analysis, thermogravimetric analysis, and BET (Brunauer–Emmett–Teller) analysis. The analysis results show the enhancement of mechanical properties due to the mixing of the CNT dispersion, and the results confirm the applicability of the proposed CNT aqueous dispersions using PC-based surfactants.https://www.mdpi.com/1996-1944/16/21/6880CNTcarbon nanotubesurfactantcement compositemicrostructuremechanical properties
spellingShingle Won-Woo Kim
Jae-Heum Moon
Seung-Tae Lee
Effect of Dispersing Carbon Nanotube in Aqueous Solution by Poly-Carboxylic-Based Surfactants on Mechanical and Microstructural Properties as Cementitious Composites
Materials
CNT
carbon nanotube
surfactant
cement composite
microstructure
mechanical properties
title Effect of Dispersing Carbon Nanotube in Aqueous Solution by Poly-Carboxylic-Based Surfactants on Mechanical and Microstructural Properties as Cementitious Composites
title_full Effect of Dispersing Carbon Nanotube in Aqueous Solution by Poly-Carboxylic-Based Surfactants on Mechanical and Microstructural Properties as Cementitious Composites
title_fullStr Effect of Dispersing Carbon Nanotube in Aqueous Solution by Poly-Carboxylic-Based Surfactants on Mechanical and Microstructural Properties as Cementitious Composites
title_full_unstemmed Effect of Dispersing Carbon Nanotube in Aqueous Solution by Poly-Carboxylic-Based Surfactants on Mechanical and Microstructural Properties as Cementitious Composites
title_short Effect of Dispersing Carbon Nanotube in Aqueous Solution by Poly-Carboxylic-Based Surfactants on Mechanical and Microstructural Properties as Cementitious Composites
title_sort effect of dispersing carbon nanotube in aqueous solution by poly carboxylic based surfactants on mechanical and microstructural properties as cementitious composites
topic CNT
carbon nanotube
surfactant
cement composite
microstructure
mechanical properties
url https://www.mdpi.com/1996-1944/16/21/6880
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