Complexes of some 3d-metals with a Schiff base derived from 5-acetamido-1,3,4-thiadiazole-2-sulphonamide and their biological activity
Using a bidentate ligand, a Schiff base of 5-acetamido-1,3,4- thiadiazole-2-sulphonamide, complexes of transition metals having the general formula ML2, where M = Mn(II), Fe(II), Ni(II) and Cu(II), were synthesized. The complexes were characterized by elemental analysis, molar conductivity, magn...
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| Format: | Article |
| Language: | English |
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Serbian Chemical Society
2011-01-01
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| Series: | Journal of the Serbian Chemical Society |
| Subjects: | |
| Online Access: | http://www.doiserbia.nb.rs/img/doi/0352-5139/2011/0352-51391100118M.pdf |
| _version_ | 1818766518082600960 |
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| author | Mitu Liviu Ghosh Suparna Malik Suman |
| author_facet | Mitu Liviu Ghosh Suparna Malik Suman |
| author_sort | Mitu Liviu |
| collection | DOAJ |
| description | Using a bidentate ligand, a Schiff base of 5-acetamido-1,3,4- thiadiazole-2-sulphonamide, complexes of transition metals having the general formula ML2, where M = Mn(II), Fe(II), Ni(II) and Cu(II), were synthesized. The complexes were characterized by elemental analysis, molar conductivity, magnetic moment, electronic, ESR and IR spectroscopy, and particle size analysis. The conductivity data of the complexes suggests their non-electrolytic nature. The stability constants and free energy change for the complexes were calculated. Spectral studies and magnetic susceptibility measurements revealed an octahedral geometry for all the complexes. The ligand and its complexes were screened for their fungicidal activity against Aspergillus niger and A. flavus. |
| first_indexed | 2024-12-18T08:35:15Z |
| format | Article |
| id | doaj.art-d7fc10a6e1c84ae28cd1171f370af802 |
| institution | Directory Open Access Journal |
| issn | 0352-5139 |
| language | English |
| last_indexed | 2024-12-18T08:35:15Z |
| publishDate | 2011-01-01 |
| publisher | Serbian Chemical Society |
| record_format | Article |
| series | Journal of the Serbian Chemical Society |
| spelling | doaj.art-d7fc10a6e1c84ae28cd1171f370af8022022-12-21T21:14:20ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51392011-01-0176101387139410.2298/JSC110111118MComplexes of some 3d-metals with a Schiff base derived from 5-acetamido-1,3,4-thiadiazole-2-sulphonamide and their biological activityMitu LiviuGhosh SuparnaMalik SumanUsing a bidentate ligand, a Schiff base of 5-acetamido-1,3,4- thiadiazole-2-sulphonamide, complexes of transition metals having the general formula ML2, where M = Mn(II), Fe(II), Ni(II) and Cu(II), were synthesized. The complexes were characterized by elemental analysis, molar conductivity, magnetic moment, electronic, ESR and IR spectroscopy, and particle size analysis. The conductivity data of the complexes suggests their non-electrolytic nature. The stability constants and free energy change for the complexes were calculated. Spectral studies and magnetic susceptibility measurements revealed an octahedral geometry for all the complexes. The ligand and its complexes were screened for their fungicidal activity against Aspergillus niger and A. flavus.http://www.doiserbia.nb.rs/img/doi/0352-5139/2011/0352-51391100118M.pdfSchiff baseconductivitynon-electrolyticstability constantfungicidal activity |
| spellingShingle | Mitu Liviu Ghosh Suparna Malik Suman Complexes of some 3d-metals with a Schiff base derived from 5-acetamido-1,3,4-thiadiazole-2-sulphonamide and their biological activity Journal of the Serbian Chemical Society Schiff base conductivity non-electrolytic stability constant fungicidal activity |
| title | Complexes of some 3d-metals with a Schiff base derived from 5-acetamido-1,3,4-thiadiazole-2-sulphonamide and their biological activity |
| title_full | Complexes of some 3d-metals with a Schiff base derived from 5-acetamido-1,3,4-thiadiazole-2-sulphonamide and their biological activity |
| title_fullStr | Complexes of some 3d-metals with a Schiff base derived from 5-acetamido-1,3,4-thiadiazole-2-sulphonamide and their biological activity |
| title_full_unstemmed | Complexes of some 3d-metals with a Schiff base derived from 5-acetamido-1,3,4-thiadiazole-2-sulphonamide and their biological activity |
| title_short | Complexes of some 3d-metals with a Schiff base derived from 5-acetamido-1,3,4-thiadiazole-2-sulphonamide and their biological activity |
| title_sort | complexes of some 3d metals with a schiff base derived from 5 acetamido 1 3 4 thiadiazole 2 sulphonamide and their biological activity |
| topic | Schiff base conductivity non-electrolytic stability constant fungicidal activity |
| url | http://www.doiserbia.nb.rs/img/doi/0352-5139/2011/0352-51391100118M.pdf |
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