Enhanced Wet Oxidation of Excess Sludge from Pharmaceutical Wastewater Treatment by NaOH

In the present study, enhanced wet oxidation of excess sludge from pharmaceutical wastewater by NaOH as an alkaline homogeneous catalyst was investigated. The experiments were carried out in a stainless-steel batch autoclave reactor. The highest volatile suspended solids (VSS) removal rate, 95.2%, w...

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Main Authors: Yuting Zhu, Xu Zeng, Kaiyu Fang
Format: Article
Language:English
Published: MDPI AG 2023-07-01
Series:Catalysts
Subjects:
Online Access:https://www.mdpi.com/2073-4344/13/7/1070
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author Yuting Zhu
Xu Zeng
Kaiyu Fang
author_facet Yuting Zhu
Xu Zeng
Kaiyu Fang
author_sort Yuting Zhu
collection DOAJ
description In the present study, enhanced wet oxidation of excess sludge from pharmaceutical wastewater by NaOH as an alkaline homogeneous catalyst was investigated. The experiments were carried out in a stainless-steel batch autoclave reactor. The highest volatile suspended solids (VSS) removal rate, 95.2%, was achieved at 260 °C within 60 min with an initial oxygen pressure of 1.0 MPa and NaOH 0.5 g·L<sup>−1</sup>. Simultaneously, the chemical oxygen demand (COD) removal rate of 57.3% was reached. The increase in volatile fatty acids (VFAs) demonstrated that the degradation of sludge was greatly accelerated by NaOH. Interestingly, the production of acetic acid, an intermediate by-product generated from the oxidation of organic compounds, increased significantly. These results illustrated that NaOH is a promising catalyst for the utilization of wet oxidation liquid of excess sludge as a carbon source for the treatment of wastewater.
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spelling doaj.art-d808e4e120b54bf2a63efeae688ecd022023-11-18T18:44:16ZengMDPI AGCatalysts2073-43442023-07-01137107010.3390/catal13071070Enhanced Wet Oxidation of Excess Sludge from Pharmaceutical Wastewater Treatment by NaOHYuting Zhu0Xu Zeng1Kaiyu Fang2State Key Laboratory of Pollution Control and Resource Reuse, College of Environmental Science and Engineering, Tongji University, Shanghai 200092, ChinaState Key Laboratory of Pollution Control and Resource Reuse, College of Environmental Science and Engineering, Tongji University, Shanghai 200092, ChinaState Key Laboratory of Pollution Control and Resource Reuse, College of Environmental Science and Engineering, Tongji University, Shanghai 200092, ChinaIn the present study, enhanced wet oxidation of excess sludge from pharmaceutical wastewater by NaOH as an alkaline homogeneous catalyst was investigated. The experiments were carried out in a stainless-steel batch autoclave reactor. The highest volatile suspended solids (VSS) removal rate, 95.2%, was achieved at 260 °C within 60 min with an initial oxygen pressure of 1.0 MPa and NaOH 0.5 g·L<sup>−1</sup>. Simultaneously, the chemical oxygen demand (COD) removal rate of 57.3% was reached. The increase in volatile fatty acids (VFAs) demonstrated that the degradation of sludge was greatly accelerated by NaOH. Interestingly, the production of acetic acid, an intermediate by-product generated from the oxidation of organic compounds, increased significantly. These results illustrated that NaOH is a promising catalyst for the utilization of wet oxidation liquid of excess sludge as a carbon source for the treatment of wastewater.https://www.mdpi.com/2073-4344/13/7/1070wet oxidationcatalystsodium hydroxidepharmaceutical wastewater
spellingShingle Yuting Zhu
Xu Zeng
Kaiyu Fang
Enhanced Wet Oxidation of Excess Sludge from Pharmaceutical Wastewater Treatment by NaOH
Catalysts
wet oxidation
catalyst
sodium hydroxide
pharmaceutical wastewater
title Enhanced Wet Oxidation of Excess Sludge from Pharmaceutical Wastewater Treatment by NaOH
title_full Enhanced Wet Oxidation of Excess Sludge from Pharmaceutical Wastewater Treatment by NaOH
title_fullStr Enhanced Wet Oxidation of Excess Sludge from Pharmaceutical Wastewater Treatment by NaOH
title_full_unstemmed Enhanced Wet Oxidation of Excess Sludge from Pharmaceutical Wastewater Treatment by NaOH
title_short Enhanced Wet Oxidation of Excess Sludge from Pharmaceutical Wastewater Treatment by NaOH
title_sort enhanced wet oxidation of excess sludge from pharmaceutical wastewater treatment by naoh
topic wet oxidation
catalyst
sodium hydroxide
pharmaceutical wastewater
url https://www.mdpi.com/2073-4344/13/7/1070
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AT xuzeng enhancedwetoxidationofexcesssludgefrompharmaceuticalwastewatertreatmentbynaoh
AT kaiyufang enhancedwetoxidationofexcesssludgefrompharmaceuticalwastewatertreatmentbynaoh