Effect of Polyethylene Glycol on Preparation of Magnesium Hydroxide by Electrodeposition

The current research focuses on the mechanism of the surfactant polyethylene glycol (PEG) in the preparation of magnesium hydroxide by electrolysis of a salt lake bischite aqueous solution. The samples were analyzed by a scanning electron microscope (SEM), X-ray diffraction (XRD), Fourier transform...

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Main Authors: Zhichun Cui, Yuezhong Di, Jianping Peng, Yaowu Wang, Naixiang Feng
Format: Article
Language:English
Published: MDPI AG 2022-05-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/15/9/3278
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author Zhichun Cui
Yuezhong Di
Jianping Peng
Yaowu Wang
Naixiang Feng
author_facet Zhichun Cui
Yuezhong Di
Jianping Peng
Yaowu Wang
Naixiang Feng
author_sort Zhichun Cui
collection DOAJ
description The current research focuses on the mechanism of the surfactant polyethylene glycol (PEG) in the preparation of magnesium hydroxide by electrolysis of a salt lake bischite aqueous solution. The samples were analyzed by a scanning electron microscope (SEM), X-ray diffraction (XRD), Fourier transform infrared spectrometer (FT-IR) and laser particle size analyzer. The characterization results show that PEG plays an important role in adjusting the growth mode and morphology of Mg(OH)<sub>2</sub> crystals. The ether group of the PEG molecular chain and the hydroxyl group of Mg(OH)<sub>2</sub> can be combined by a hydrogen bond, which provides a "template" for the growth of Mg(OH)<sub>2</sub>. At the same time, the difference in growth mode and morphology will also affect the economic performance of electrolytic reactions. When the PEG content reaches 0.4 g/L, the particle size of the product is uniform, which can well reduce the polarization of the electrode plate. The cell potential of electrolytic reaction is small, and the economic benefit is high. When the content of PEG is low, it has a low impact on the product and the economic benefits of electrolytic reaction. When the PEG content is higher than 0.4 g/L, the electrode reaction is hindered, resulting in an increase in cell potential.
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spelling doaj.art-d80a8f4338fe481882ee642b8806b8062023-11-23T08:40:53ZengMDPI AGMaterials1996-19442022-05-01159327810.3390/ma15093278Effect of Polyethylene Glycol on Preparation of Magnesium Hydroxide by ElectrodepositionZhichun Cui0Yuezhong Di1Jianping Peng2Yaowu Wang3Naixiang Feng4School of Metallurgy, Northeastern University, Shenyang 110819, ChinaSchool of Metallurgy, Northeastern University, Shenyang 110819, ChinaSchool of Metallurgy, Northeastern University, Shenyang 110819, ChinaSchool of Metallurgy, Northeastern University, Shenyang 110819, ChinaSchool of Metallurgy, Northeastern University, Shenyang 110819, ChinaThe current research focuses on the mechanism of the surfactant polyethylene glycol (PEG) in the preparation of magnesium hydroxide by electrolysis of a salt lake bischite aqueous solution. The samples were analyzed by a scanning electron microscope (SEM), X-ray diffraction (XRD), Fourier transform infrared spectrometer (FT-IR) and laser particle size analyzer. The characterization results show that PEG plays an important role in adjusting the growth mode and morphology of Mg(OH)<sub>2</sub> crystals. The ether group of the PEG molecular chain and the hydroxyl group of Mg(OH)<sub>2</sub> can be combined by a hydrogen bond, which provides a "template" for the growth of Mg(OH)<sub>2</sub>. At the same time, the difference in growth mode and morphology will also affect the economic performance of electrolytic reactions. When the PEG content reaches 0.4 g/L, the particle size of the product is uniform, which can well reduce the polarization of the electrode plate. The cell potential of electrolytic reaction is small, and the economic benefit is high. When the content of PEG is low, it has a low impact on the product and the economic benefits of electrolytic reaction. When the PEG content is higher than 0.4 g/L, the electrode reaction is hindered, resulting in an increase in cell potential.https://www.mdpi.com/1996-1944/15/9/3278magnesium hydroxidepolyethylene glycolelectrodepositionsurfactant
spellingShingle Zhichun Cui
Yuezhong Di
Jianping Peng
Yaowu Wang
Naixiang Feng
Effect of Polyethylene Glycol on Preparation of Magnesium Hydroxide by Electrodeposition
Materials
magnesium hydroxide
polyethylene glycol
electrodeposition
surfactant
title Effect of Polyethylene Glycol on Preparation of Magnesium Hydroxide by Electrodeposition
title_full Effect of Polyethylene Glycol on Preparation of Magnesium Hydroxide by Electrodeposition
title_fullStr Effect of Polyethylene Glycol on Preparation of Magnesium Hydroxide by Electrodeposition
title_full_unstemmed Effect of Polyethylene Glycol on Preparation of Magnesium Hydroxide by Electrodeposition
title_short Effect of Polyethylene Glycol on Preparation of Magnesium Hydroxide by Electrodeposition
title_sort effect of polyethylene glycol on preparation of magnesium hydroxide by electrodeposition
topic magnesium hydroxide
polyethylene glycol
electrodeposition
surfactant
url https://www.mdpi.com/1996-1944/15/9/3278
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AT yuezhongdi effectofpolyethyleneglycolonpreparationofmagnesiumhydroxidebyelectrodeposition
AT jianpingpeng effectofpolyethyleneglycolonpreparationofmagnesiumhydroxidebyelectrodeposition
AT yaowuwang effectofpolyethyleneglycolonpreparationofmagnesiumhydroxidebyelectrodeposition
AT naixiangfeng effectofpolyethyleneglycolonpreparationofmagnesiumhydroxidebyelectrodeposition