Construction of mesoporous bimetallic (Ni, Co) organic framework microspheres for lithium-ion capacitors
Rational design of appropriate negative electrode materials with high rates and long cycle life is essential to construct advanced lithium-ion capacitors (LICs). Herein, we solvothermally synthesize the bimetallic (Ni, Co) organic framework (NiCo-MOF) microspheres by using the polyvinylpyrrolidone a...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2021-04-01
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| Series: | Electrochemistry Communications |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S1388248121000904 |
| _version_ | 1819298042353811456 |
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| author | Jinyang Zhang Yuyan Wang Yamin Zhang Fakhr uz Zaman Linrui Hou Changzhou Yuan |
| author_facet | Jinyang Zhang Yuyan Wang Yamin Zhang Fakhr uz Zaman Linrui Hou Changzhou Yuan |
| author_sort | Jinyang Zhang |
| collection | DOAJ |
| description | Rational design of appropriate negative electrode materials with high rates and long cycle life is essential to construct advanced lithium-ion capacitors (LICs). Herein, we solvothermally synthesize the bimetallic (Ni, Co) organic framework (NiCo-MOF) microspheres by using the polyvinylpyrrolidone as a structure-directing agent towards advanced LICs as a battery-type negative electrode. Benefiting from its rigid structure stability, high crystallinity, rich electroactive sites and high-content mesopores, the NiCo-MOF electrode obtains a large reversible capacity of ~557.1 mAh g−1 at 0.1 A g−1. Furthermore, the NiCo-MOF based LICs display a high SC of ~58.2 F g−1 at ~1.0 A g−1, along with an exceptional capacitance retention over 8500 cycles at 1.0 A g−1. More significantly, the contribution here will stimulate extensive development of versatile MOF microspheres for next-generation LICs and beyond. |
| first_indexed | 2024-12-24T05:23:36Z |
| format | Article |
| id | doaj.art-d8182403b0964b7385e890355a619b02 |
| institution | Directory Open Access Journal |
| issn | 1388-2481 |
| language | English |
| last_indexed | 2024-12-24T05:23:36Z |
| publishDate | 2021-04-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Electrochemistry Communications |
| spelling | doaj.art-d8182403b0964b7385e890355a619b022022-12-21T17:13:24ZengElsevierElectrochemistry Communications1388-24812021-04-01125107006Construction of mesoporous bimetallic (Ni, Co) organic framework microspheres for lithium-ion capacitorsJinyang Zhang0Yuyan Wang1Yamin Zhang2Fakhr uz Zaman3Linrui Hou4Changzhou Yuan5School of Materials Science & Engineering, University of Jinan, Jinan 250022, PR ChinaSchool of Materials Science & Engineering, University of Jinan, Jinan 250022, PR ChinaSchool of Materials Science & Engineering, University of Jinan, Jinan 250022, PR ChinaSchool of Materials Science & Engineering, University of Jinan, Jinan 250022, PR ChinaSchool of Materials Science & Engineering, University of Jinan, Jinan 250022, PR ChinaCorresponding author.; School of Materials Science & Engineering, University of Jinan, Jinan 250022, PR ChinaRational design of appropriate negative electrode materials with high rates and long cycle life is essential to construct advanced lithium-ion capacitors (LICs). Herein, we solvothermally synthesize the bimetallic (Ni, Co) organic framework (NiCo-MOF) microspheres by using the polyvinylpyrrolidone as a structure-directing agent towards advanced LICs as a battery-type negative electrode. Benefiting from its rigid structure stability, high crystallinity, rich electroactive sites and high-content mesopores, the NiCo-MOF electrode obtains a large reversible capacity of ~557.1 mAh g−1 at 0.1 A g−1. Furthermore, the NiCo-MOF based LICs display a high SC of ~58.2 F g−1 at ~1.0 A g−1, along with an exceptional capacitance retention over 8500 cycles at 1.0 A g−1. More significantly, the contribution here will stimulate extensive development of versatile MOF microspheres for next-generation LICs and beyond.http://www.sciencedirect.com/science/article/pii/S1388248121000904Bimetallic organic frameworksPolyvinylpyrrolidonePorous microspheresNegative electrodesLithium-ion capacitors |
| spellingShingle | Jinyang Zhang Yuyan Wang Yamin Zhang Fakhr uz Zaman Linrui Hou Changzhou Yuan Construction of mesoporous bimetallic (Ni, Co) organic framework microspheres for lithium-ion capacitors Electrochemistry Communications Bimetallic organic frameworks Polyvinylpyrrolidone Porous microspheres Negative electrodes Lithium-ion capacitors |
| title | Construction of mesoporous bimetallic (Ni, Co) organic framework microspheres for lithium-ion capacitors |
| title_full | Construction of mesoporous bimetallic (Ni, Co) organic framework microspheres for lithium-ion capacitors |
| title_fullStr | Construction of mesoporous bimetallic (Ni, Co) organic framework microspheres for lithium-ion capacitors |
| title_full_unstemmed | Construction of mesoporous bimetallic (Ni, Co) organic framework microspheres for lithium-ion capacitors |
| title_short | Construction of mesoporous bimetallic (Ni, Co) organic framework microspheres for lithium-ion capacitors |
| title_sort | construction of mesoporous bimetallic ni co organic framework microspheres for lithium ion capacitors |
| topic | Bimetallic organic frameworks Polyvinylpyrrolidone Porous microspheres Negative electrodes Lithium-ion capacitors |
| url | http://www.sciencedirect.com/science/article/pii/S1388248121000904 |
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