Crystal structure of tetrakis(tetrahydrofuran-κO)bis(trifluoromethanesulfonato-κO)iron(II)
The title compound, [Fe(CF3SO3)2(C4H8O)4], is octahedral with two trifluoromethanesulfonate ligands in trans positions and four tetrahydrofurane molecules in the equatorial plane. By the conformation of the ligands the complex is chiral in the crystal packing. The compound crystallizes in the Sohnck...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2019-10-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989019013094 |
| _version_ | 1798024505273090048 |
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| author | Charl F. Riemersma Emily C. Monkcom Robertus J. M. Klein Gebbink Martin Lutz |
| author_facet | Charl F. Riemersma Emily C. Monkcom Robertus J. M. Klein Gebbink Martin Lutz |
| author_sort | Charl F. Riemersma |
| collection | DOAJ |
| description | The title compound, [Fe(CF3SO3)2(C4H8O)4], is octahedral with two trifluoromethanesulfonate ligands in trans positions and four tetrahydrofurane molecules in the equatorial plane. By the conformation of the ligands the complex is chiral in the crystal packing. The compound crystallizes in the Sohncke space group P212121 and is enantiomerically pure. The packing of the molecules is determined by weak C—H...O hydrogen bonds. The crystal studied was refined as a two-component inversion twin. |
| first_indexed | 2024-04-11T18:03:32Z |
| format | Article |
| id | doaj.art-d81f48efd4634e1cafdf5e950770bc08 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-04-11T18:03:32Z |
| publishDate | 2019-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-d81f48efd4634e1cafdf5e950770bc082022-12-22T04:10:24ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902019-10-0175101548155110.1107/S2056989019013094vn2153Crystal structure of tetrakis(tetrahydrofuran-κO)bis(trifluoromethanesulfonato-κO)iron(II)Charl F. Riemersma0Emily C. Monkcom1Robertus J. M. Klein Gebbink2Martin Lutz3Organic Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Faculty of Science, Utrecht University, Universiteitsweg 99, 3584 CG Utrecht, The NetherlandsOrganic Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Faculty of Science, Utrecht University, Universiteitsweg 99, 3584 CG Utrecht, The NetherlandsOrganic Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Faculty of Science, Utrecht University, Universiteitsweg 99, 3584 CG Utrecht, The NetherlandsBijvoet Center for Biomolecular Research, Crystal and Structural Chemistry, Faculty of Science, Utrecht University, Padualaan 8, 3584 CH Utrecht, The NetherlandsThe title compound, [Fe(CF3SO3)2(C4H8O)4], is octahedral with two trifluoromethanesulfonate ligands in trans positions and four tetrahydrofurane molecules in the equatorial plane. By the conformation of the ligands the complex is chiral in the crystal packing. The compound crystallizes in the Sohncke space group P212121 and is enantiomerically pure. The packing of the molecules is determined by weak C—H...O hydrogen bonds. The crystal studied was refined as a two-component inversion twin.http://scripts.iucr.org/cgi-bin/paper?S2056989019013094crystal structurehigh-spin iron(II)split-mosaic model |
| spellingShingle | Charl F. Riemersma Emily C. Monkcom Robertus J. M. Klein Gebbink Martin Lutz Crystal structure of tetrakis(tetrahydrofuran-κO)bis(trifluoromethanesulfonato-κO)iron(II) Acta Crystallographica Section E: Crystallographic Communications crystal structure high-spin iron(II) split-mosaic model |
| title | Crystal structure of tetrakis(tetrahydrofuran-κO)bis(trifluoromethanesulfonato-κO)iron(II) |
| title_full | Crystal structure of tetrakis(tetrahydrofuran-κO)bis(trifluoromethanesulfonato-κO)iron(II) |
| title_fullStr | Crystal structure of tetrakis(tetrahydrofuran-κO)bis(trifluoromethanesulfonato-κO)iron(II) |
| title_full_unstemmed | Crystal structure of tetrakis(tetrahydrofuran-κO)bis(trifluoromethanesulfonato-κO)iron(II) |
| title_short | Crystal structure of tetrakis(tetrahydrofuran-κO)bis(trifluoromethanesulfonato-κO)iron(II) |
| title_sort | crystal structure of tetrakis tetrahydrofuran κo bis trifluoromethanesulfonato κo iron ii |
| topic | crystal structure high-spin iron(II) split-mosaic model |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989019013094 |
| work_keys_str_mv | AT charlfriemersma crystalstructureoftetrakistetrahydrofurankobistrifluoromethanesulfonatokoironii AT emilycmonkcom crystalstructureoftetrakistetrahydrofurankobistrifluoromethanesulfonatokoironii AT robertusjmkleingebbink crystalstructureoftetrakistetrahydrofurankobistrifluoromethanesulfonatokoironii AT martinlutz crystalstructureoftetrakistetrahydrofurankobistrifluoromethanesulfonatokoironii |