Effect of ZrO2 addition on the BO6 vibration modes of [(Bi0.5Na0.5)TiO3 – SrTiO3 – BaTiO3] perovskite structure for enhancement energy storage properties
In the present study, (Bi0.35Na0.35Sr0.2Ba0.1) (Ti1-xZrx) O3 (abbreviate BBSNTZx) (0.0 ≤ x ≤ 0.1) bulk ceramics were selected to enhance their energy storage performance and relaxor degree by suppression of TiO6 (Orthorhombic-phase) vibration mode. As a result, a significant effect of Zr4+ on the di...
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| Format: | Article |
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Elsevier
2024-03-01
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| Series: | Results in Physics |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S221137972400127X |
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| author | Mohammed Ezzeldien Abeer M. Beagan P.A. Alvi Abd El-razek Mahmoud |
| author_facet | Mohammed Ezzeldien Abeer M. Beagan P.A. Alvi Abd El-razek Mahmoud |
| author_sort | Mohammed Ezzeldien |
| collection | DOAJ |
| description | In the present study, (Bi0.35Na0.35Sr0.2Ba0.1) (Ti1-xZrx) O3 (abbreviate BBSNTZx) (0.0 ≤ x ≤ 0.1) bulk ceramics were selected to enhance their energy storage performance and relaxor degree by suppression of TiO6 (Orthorhombic-phase) vibration mode. As a result, a significant effect of Zr4+ on the dilution of O-phase and growth of R-phase has been observed. The addition of Zr4+ induced decreasing the tolerance factor value (τ) from 0.994 to 0.988, which agrees with FT-IR results. Along with the variation of crystal structure, the broad permittivity peak increased via the amount of Zr4+ increases, which was confirmed by increasing the diffusive coefficient (γ) from 1.524 to 1.877. Pure BBSNT anti-ferroelectric –ceramic exhibited high Wrec = 0.57 J/cm3 with moderate ƞ = 83 % at lower electric field (E = 60 kV/cm). The value of ƞ can be enhanced up to 93 % at Zr = 0.1, attributed to enhanced relaxor phase and polar nanoregions contributions.Furthermore, the temperature and frequency stability of the energy storage properties can be enhanced simultaneously by the addition of Zr ions. The suppression of converse piezoelectric coefficient (d*33) attributed to decreasing the non-revisable 180° domain switching at high Zr content. The present study introduces useful guidelines for understanding the correlation between BO6 octahedral tilting vibration mode and ferroelectric properties of the perovskite structure. Furthermore, the energy storage properties can be enhanced by the suppression of TiO6 vibration modes, which is confirmed by decreasing the O/R volume fraction, subsequently enhancing the relaxor degree. |
| first_indexed | 2024-03-08T02:01:53Z |
| format | Article |
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| institution | Directory Open Access Journal |
| issn | 2211-3797 |
| language | English |
| last_indexed | 2024-04-24T23:18:11Z |
| publishDate | 2024-03-01 |
| publisher | Elsevier |
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| series | Results in Physics |
| spelling | doaj.art-d82f2ccd4d7f4ee187e9d75ed1f4b75c2024-03-17T07:53:31ZengElsevierResults in Physics2211-37972024-03-0158107445Effect of ZrO2 addition on the BO6 vibration modes of [(Bi0.5Na0.5)TiO3 – SrTiO3 – BaTiO3] perovskite structure for enhancement energy storage propertiesMohammed Ezzeldien0Abeer M. Beagan1P.A. Alvi2Abd El-razek Mahmoud3Metallurgy and Material Science Tests Lab., Physics Department, Faculty of Science, South Valley University, Qena 83523, Egypt; Corresponding authors.Department of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi ArabiaDepartment of Physical Science, Banasthali Vidyapith, Banasthali, Rajasthan 304022, IndiaFerroelectric and Piezoelectric Lab, Physics Department, Faculty of Science, South Valley University, Qena 83523, Egypt; Corresponding authors.In the present study, (Bi0.35Na0.35Sr0.2Ba0.1) (Ti1-xZrx) O3 (abbreviate BBSNTZx) (0.0 ≤ x ≤ 0.1) bulk ceramics were selected to enhance their energy storage performance and relaxor degree by suppression of TiO6 (Orthorhombic-phase) vibration mode. As a result, a significant effect of Zr4+ on the dilution of O-phase and growth of R-phase has been observed. The addition of Zr4+ induced decreasing the tolerance factor value (τ) from 0.994 to 0.988, which agrees with FT-IR results. Along with the variation of crystal structure, the broad permittivity peak increased via the amount of Zr4+ increases, which was confirmed by increasing the diffusive coefficient (γ) from 1.524 to 1.877. Pure BBSNT anti-ferroelectric –ceramic exhibited high Wrec = 0.57 J/cm3 with moderate ƞ = 83 % at lower electric field (E = 60 kV/cm). The value of ƞ can be enhanced up to 93 % at Zr = 0.1, attributed to enhanced relaxor phase and polar nanoregions contributions.Furthermore, the temperature and frequency stability of the energy storage properties can be enhanced simultaneously by the addition of Zr ions. The suppression of converse piezoelectric coefficient (d*33) attributed to decreasing the non-revisable 180° domain switching at high Zr content. The present study introduces useful guidelines for understanding the correlation between BO6 octahedral tilting vibration mode and ferroelectric properties of the perovskite structure. Furthermore, the energy storage properties can be enhanced by the suppression of TiO6 vibration modes, which is confirmed by decreasing the O/R volume fraction, subsequently enhancing the relaxor degree.http://www.sciencedirect.com/science/article/pii/S221137972400127XEnergy storageRelaxor dielectric ceramicsBO6 vibration modeBreakdown strengthDomain switching |
| spellingShingle | Mohammed Ezzeldien Abeer M. Beagan P.A. Alvi Abd El-razek Mahmoud Effect of ZrO2 addition on the BO6 vibration modes of [(Bi0.5Na0.5)TiO3 – SrTiO3 – BaTiO3] perovskite structure for enhancement energy storage properties Results in Physics Energy storage Relaxor dielectric ceramics BO6 vibration mode Breakdown strength Domain switching |
| title | Effect of ZrO2 addition on the BO6 vibration modes of [(Bi0.5Na0.5)TiO3 – SrTiO3 – BaTiO3] perovskite structure for enhancement energy storage properties |
| title_full | Effect of ZrO2 addition on the BO6 vibration modes of [(Bi0.5Na0.5)TiO3 – SrTiO3 – BaTiO3] perovskite structure for enhancement energy storage properties |
| title_fullStr | Effect of ZrO2 addition on the BO6 vibration modes of [(Bi0.5Na0.5)TiO3 – SrTiO3 – BaTiO3] perovskite structure for enhancement energy storage properties |
| title_full_unstemmed | Effect of ZrO2 addition on the BO6 vibration modes of [(Bi0.5Na0.5)TiO3 – SrTiO3 – BaTiO3] perovskite structure for enhancement energy storage properties |
| title_short | Effect of ZrO2 addition on the BO6 vibration modes of [(Bi0.5Na0.5)TiO3 – SrTiO3 – BaTiO3] perovskite structure for enhancement energy storage properties |
| title_sort | effect of zro2 addition on the bo6 vibration modes of bi0 5na0 5 tio3 srtio3 batio3 perovskite structure for enhancement energy storage properties |
| topic | Energy storage Relaxor dielectric ceramics BO6 vibration mode Breakdown strength Domain switching |
| url | http://www.sciencedirect.com/science/article/pii/S221137972400127X |
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