Photoinduced Photocatalyst-Free Cascade Cyclization of Alkynes with Sodium Sulfinates for the Synthesis of Benzothiophenes and Thioflavones

The subject of this investigation is a new method for the construction of sulfonylated heterocycles which overcomes the limitations of classical approaches using a cheap feedstock sulfonylating agent, especially under photocatalyst- and metal-free conditions.

Bibliographic Details
Main Authors: Hongqiang Dong, Chunli Chen, Jinlei Zhao, Yigang Ji, Wenchao Yang
Format: Article
Language:English
Published: MDPI AG 2023-05-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/28/11/4436
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author Hongqiang Dong
Chunli Chen
Jinlei Zhao
Yigang Ji
Wenchao Yang
author_facet Hongqiang Dong
Chunli Chen
Jinlei Zhao
Yigang Ji
Wenchao Yang
author_sort Hongqiang Dong
collection DOAJ
description The subject of this investigation is a new method for the construction of sulfonylated heterocycles which overcomes the limitations of classical approaches using a cheap feedstock sulfonylating agent, especially under photocatalyst- and metal-free conditions.
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spelling doaj.art-d8389b3a4f4b421092111f7b359f44d32023-11-18T08:16:37ZengMDPI AGMolecules1420-30492023-05-012811443610.3390/molecules28114436Photoinduced Photocatalyst-Free Cascade Cyclization of Alkynes with Sodium Sulfinates for the Synthesis of Benzothiophenes and ThioflavonesHongqiang Dong0Chunli Chen1Jinlei Zhao2Yigang Ji3Wenchao Yang4The Open Research Fund of the National and Local Joint Engineering Laboratory of High Efficiency and Superior-Quality Cultivation and Fruit Deep Processing Technology of Characteristic Fruit Trees in South Xinjiang, College of Agriculture, Tarim University, Alaer 843300, ChinaThe Open Research Fund of the National and Local Joint Engineering Laboratory of High Efficiency and Superior-Quality Cultivation and Fruit Deep Processing Technology of Characteristic Fruit Trees in South Xinjiang, College of Agriculture, Tarim University, Alaer 843300, ChinaNational Engineering Research Center of Low-Carbon Processing and Utilization of Forest Biomass, Nanjing Forestry University, Nanjing 210037, ChinaJiangsu Key Laboratory of Biofuctional Molecules, Department of Life Sciences and Chemistry, Jiangsu Second Normal University, Nanjing 210013, ChinaGuangling College and School of Plant Protection, Yangzhou University, Yangzhou 225009, ChinaThe subject of this investigation is a new method for the construction of sulfonylated heterocycles which overcomes the limitations of classical approaches using a cheap feedstock sulfonylating agent, especially under photocatalyst- and metal-free conditions.https://www.mdpi.com/1420-3049/28/11/4436sulfonylationsodium sulfinatesradicalcyclizationalkynes
spellingShingle Hongqiang Dong
Chunli Chen
Jinlei Zhao
Yigang Ji
Wenchao Yang
Photoinduced Photocatalyst-Free Cascade Cyclization of Alkynes with Sodium Sulfinates for the Synthesis of Benzothiophenes and Thioflavones
Molecules
sulfonylation
sodium sulfinates
radical
cyclization
alkynes
title Photoinduced Photocatalyst-Free Cascade Cyclization of Alkynes with Sodium Sulfinates for the Synthesis of Benzothiophenes and Thioflavones
title_full Photoinduced Photocatalyst-Free Cascade Cyclization of Alkynes with Sodium Sulfinates for the Synthesis of Benzothiophenes and Thioflavones
title_fullStr Photoinduced Photocatalyst-Free Cascade Cyclization of Alkynes with Sodium Sulfinates for the Synthesis of Benzothiophenes and Thioflavones
title_full_unstemmed Photoinduced Photocatalyst-Free Cascade Cyclization of Alkynes with Sodium Sulfinates for the Synthesis of Benzothiophenes and Thioflavones
title_short Photoinduced Photocatalyst-Free Cascade Cyclization of Alkynes with Sodium Sulfinates for the Synthesis of Benzothiophenes and Thioflavones
title_sort photoinduced photocatalyst free cascade cyclization of alkynes with sodium sulfinates for the synthesis of benzothiophenes and thioflavones
topic sulfonylation
sodium sulfinates
radical
cyclization
alkynes
url https://www.mdpi.com/1420-3049/28/11/4436
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AT yigangji photoinducedphotocatalystfreecascadecyclizationofalkyneswithsodiumsulfinatesforthesynthesisofbenzothiophenesandthioflavones
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