Enhanced Visible-Light-Driven Photocatalytic Activity of ZnAl Layered Double Hydroxide by Incorporation of Co2+

Co-doped ZnAl layered double hydroxides (LDH) were papered by coprecipitation. The prepared samples were characterized by multiple techniques including X-ray Diffraction (XRD), Brunauer−Emmett−Teller (BET) surface area, Scanning Electronic Microscopy (SEM), Transmission Electron Microscopy (TEM), X-...

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Main Authors: Deyang Li, Lihui Fan, Min Qi, Yanming Shen, Dongbin Liu, Shifeng Li
Format: Article
Language:English
Published: Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) 2018-12-01
Series:Bulletin of Chemical Reaction Engineering & Catalysis
Subjects:
Online Access:https://journal.bcrec.id/index.php/bcrec/article/view/2168
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author Deyang Li
Lihui Fan
Min Qi
Yanming Shen
Dongbin Liu
Shifeng Li
author_facet Deyang Li
Lihui Fan
Min Qi
Yanming Shen
Dongbin Liu
Shifeng Li
author_sort Deyang Li
collection DOAJ
description Co-doped ZnAl layered double hydroxides (LDH) were papered by coprecipitation. The prepared samples were characterized by multiple techniques including X-ray Diffraction (XRD), Brunauer−Emmett−Teller (BET) surface area, Scanning Electronic Microscopy (SEM), Transmission Electron Microscopy (TEM), X-ray Photoelectron Spectroscopy (XPS) and UV−Vis Diffuse-Reflectance Spectroscopy (UV−Vis DRS). The incorporation of Co2+ into the ZnAl LDH sheets as CrO6 octahedron forms a new  energy level which contributes for the excitation of electrons under visible light. The doped Co2+ at a reasonable content also serves as photo-generated charges separator and improves the visible light photocatalytic activity of ZnAl LDH. A degradation mechanism based on the hydroxyl radical as the active species was proposed.
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spelling doaj.art-d861a3a2b1264a7aa72200b776cf9d142023-09-22T03:45:31ZengMasyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)Bulletin of Chemical Reaction Engineering & Catalysis1978-29932018-12-0113350251110.9767/bcrec.13.3.2168.502-5111613Enhanced Visible-Light-Driven Photocatalytic Activity of ZnAl Layered Double Hydroxide by Incorporation of Co2+Deyang Li0Lihui Fan1Min Qi2Yanming Shen3Dongbin Liu4Shifeng Li5School of Chemical Engineering, Shenyang University of Chemical Technology, ChinaSchool of Chemical Engineering, Shenyang University of Chemical Technology, ChinaSchool of Chemical Engineering, Shenyang University of Chemical Technology, ChinaSchool of Chemical Engineering, Shenyang University of Chemical Technology, ChinaSchool of Chemical Engineering, Shenyang University of Chemical Technology, ChinaSchool of Chemical Engineering, Shenyang University of Chemical Technology, ChinaCo-doped ZnAl layered double hydroxides (LDH) were papered by coprecipitation. The prepared samples were characterized by multiple techniques including X-ray Diffraction (XRD), Brunauer−Emmett−Teller (BET) surface area, Scanning Electronic Microscopy (SEM), Transmission Electron Microscopy (TEM), X-ray Photoelectron Spectroscopy (XPS) and UV−Vis Diffuse-Reflectance Spectroscopy (UV−Vis DRS). The incorporation of Co2+ into the ZnAl LDH sheets as CrO6 octahedron forms a new  energy level which contributes for the excitation of electrons under visible light. The doped Co2+ at a reasonable content also serves as photo-generated charges separator and improves the visible light photocatalytic activity of ZnAl LDH. A degradation mechanism based on the hydroxyl radical as the active species was proposed.https://journal.bcrec.id/index.php/bcrec/article/view/2168layered double hydroxidescobalt-dopingrhb degradationvisible light
spellingShingle Deyang Li
Lihui Fan
Min Qi
Yanming Shen
Dongbin Liu
Shifeng Li
Enhanced Visible-Light-Driven Photocatalytic Activity of ZnAl Layered Double Hydroxide by Incorporation of Co2+
Bulletin of Chemical Reaction Engineering & Catalysis
layered double hydroxides
cobalt-doping
rhb degradation
visible light
title Enhanced Visible-Light-Driven Photocatalytic Activity of ZnAl Layered Double Hydroxide by Incorporation of Co2+
title_full Enhanced Visible-Light-Driven Photocatalytic Activity of ZnAl Layered Double Hydroxide by Incorporation of Co2+
title_fullStr Enhanced Visible-Light-Driven Photocatalytic Activity of ZnAl Layered Double Hydroxide by Incorporation of Co2+
title_full_unstemmed Enhanced Visible-Light-Driven Photocatalytic Activity of ZnAl Layered Double Hydroxide by Incorporation of Co2+
title_short Enhanced Visible-Light-Driven Photocatalytic Activity of ZnAl Layered Double Hydroxide by Incorporation of Co2+
title_sort enhanced visible light driven photocatalytic activity of znal layered double hydroxide by incorporation of co2
topic layered double hydroxides
cobalt-doping
rhb degradation
visible light
url https://journal.bcrec.id/index.php/bcrec/article/view/2168
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AT lihuifan enhancedvisiblelightdrivenphotocatalyticactivityofznallayereddoublehydroxidebyincorporationofco2
AT minqi enhancedvisiblelightdrivenphotocatalyticactivityofznallayereddoublehydroxidebyincorporationofco2
AT yanmingshen enhancedvisiblelightdrivenphotocatalyticactivityofznallayereddoublehydroxidebyincorporationofco2
AT dongbinliu enhancedvisiblelightdrivenphotocatalyticactivityofznallayereddoublehydroxidebyincorporationofco2
AT shifengli enhancedvisiblelightdrivenphotocatalyticactivityofznallayereddoublehydroxidebyincorporationofco2