Enhanced Visible-Light-Driven Photocatalytic Activity of ZnAl Layered Double Hydroxide by Incorporation of Co2+
Co-doped ZnAl layered double hydroxides (LDH) were papered by coprecipitation. The prepared samples were characterized by multiple techniques including X-ray Diffraction (XRD), Brunauer−Emmett−Teller (BET) surface area, Scanning Electronic Microscopy (SEM), Transmission Electron Microscopy (TEM), X-...
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Format: | Article |
Language: | English |
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Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
2018-12-01
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Series: | Bulletin of Chemical Reaction Engineering & Catalysis |
Subjects: | |
Online Access: | https://journal.bcrec.id/index.php/bcrec/article/view/2168 |
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author | Deyang Li Lihui Fan Min Qi Yanming Shen Dongbin Liu Shifeng Li |
author_facet | Deyang Li Lihui Fan Min Qi Yanming Shen Dongbin Liu Shifeng Li |
author_sort | Deyang Li |
collection | DOAJ |
description | Co-doped ZnAl layered double hydroxides (LDH) were papered by coprecipitation. The prepared samples were characterized by multiple techniques including X-ray Diffraction (XRD), Brunauer−Emmett−Teller (BET) surface area, Scanning Electronic Microscopy (SEM), Transmission Electron Microscopy (TEM), X-ray Photoelectron Spectroscopy (XPS) and UV−Vis Diffuse-Reflectance Spectroscopy (UV−Vis DRS). The incorporation of Co2+ into the ZnAl LDH sheets as CrO6 octahedron forms a new energy level which contributes for the excitation of electrons under visible light. The doped Co2+ at a reasonable content also serves as photo-generated charges separator and improves the visible light photocatalytic activity of ZnAl LDH. A degradation mechanism based on the hydroxyl radical as the active species was proposed. |
first_indexed | 2024-03-11T22:50:10Z |
format | Article |
id | doaj.art-d861a3a2b1264a7aa72200b776cf9d14 |
institution | Directory Open Access Journal |
issn | 1978-2993 |
language | English |
last_indexed | 2024-03-11T22:50:10Z |
publishDate | 2018-12-01 |
publisher | Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) |
record_format | Article |
series | Bulletin of Chemical Reaction Engineering & Catalysis |
spelling | doaj.art-d861a3a2b1264a7aa72200b776cf9d142023-09-22T03:45:31ZengMasyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)Bulletin of Chemical Reaction Engineering & Catalysis1978-29932018-12-0113350251110.9767/bcrec.13.3.2168.502-5111613Enhanced Visible-Light-Driven Photocatalytic Activity of ZnAl Layered Double Hydroxide by Incorporation of Co2+Deyang Li0Lihui Fan1Min Qi2Yanming Shen3Dongbin Liu4Shifeng Li5School of Chemical Engineering, Shenyang University of Chemical Technology, ChinaSchool of Chemical Engineering, Shenyang University of Chemical Technology, ChinaSchool of Chemical Engineering, Shenyang University of Chemical Technology, ChinaSchool of Chemical Engineering, Shenyang University of Chemical Technology, ChinaSchool of Chemical Engineering, Shenyang University of Chemical Technology, ChinaSchool of Chemical Engineering, Shenyang University of Chemical Technology, ChinaCo-doped ZnAl layered double hydroxides (LDH) were papered by coprecipitation. The prepared samples were characterized by multiple techniques including X-ray Diffraction (XRD), Brunauer−Emmett−Teller (BET) surface area, Scanning Electronic Microscopy (SEM), Transmission Electron Microscopy (TEM), X-ray Photoelectron Spectroscopy (XPS) and UV−Vis Diffuse-Reflectance Spectroscopy (UV−Vis DRS). The incorporation of Co2+ into the ZnAl LDH sheets as CrO6 octahedron forms a new energy level which contributes for the excitation of electrons under visible light. The doped Co2+ at a reasonable content also serves as photo-generated charges separator and improves the visible light photocatalytic activity of ZnAl LDH. A degradation mechanism based on the hydroxyl radical as the active species was proposed.https://journal.bcrec.id/index.php/bcrec/article/view/2168layered double hydroxidescobalt-dopingrhb degradationvisible light |
spellingShingle | Deyang Li Lihui Fan Min Qi Yanming Shen Dongbin Liu Shifeng Li Enhanced Visible-Light-Driven Photocatalytic Activity of ZnAl Layered Double Hydroxide by Incorporation of Co2+ Bulletin of Chemical Reaction Engineering & Catalysis layered double hydroxides cobalt-doping rhb degradation visible light |
title | Enhanced Visible-Light-Driven Photocatalytic Activity of ZnAl Layered Double Hydroxide by Incorporation of Co2+ |
title_full | Enhanced Visible-Light-Driven Photocatalytic Activity of ZnAl Layered Double Hydroxide by Incorporation of Co2+ |
title_fullStr | Enhanced Visible-Light-Driven Photocatalytic Activity of ZnAl Layered Double Hydroxide by Incorporation of Co2+ |
title_full_unstemmed | Enhanced Visible-Light-Driven Photocatalytic Activity of ZnAl Layered Double Hydroxide by Incorporation of Co2+ |
title_short | Enhanced Visible-Light-Driven Photocatalytic Activity of ZnAl Layered Double Hydroxide by Incorporation of Co2+ |
title_sort | enhanced visible light driven photocatalytic activity of znal layered double hydroxide by incorporation of co2 |
topic | layered double hydroxides cobalt-doping rhb degradation visible light |
url | https://journal.bcrec.id/index.php/bcrec/article/view/2168 |
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