Formation and Evaluation of Au/ZnO Particles by a Spray Pyrolysis Method

ZnO/Au is expected to exhibit catalytic properties by absorbing ultraviolet and visible light because ZnO and Au nanoparticles can absorb ultraviolet and visible light, respectively. Doping studies on Au nanoparticles on ZnO (ZnO/Au) have been conducted to expand the absorption wavelength range. Thi...

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Main Authors: Lee Youngjun, Fujimoto Toshiyuki, Yamanaka Shinya, Kuga Yoshikazu
Format: Article
Language:English
Published: EDP Sciences 2021-01-01
Series:MATEC Web of Conferences
Online Access:https://www.matec-conferences.org/articles/matecconf/pdf/2021/02/matecconf_apcche21_02010.pdf
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author Lee Youngjun
Fujimoto Toshiyuki
Yamanaka Shinya
Kuga Yoshikazu
author_facet Lee Youngjun
Fujimoto Toshiyuki
Yamanaka Shinya
Kuga Yoshikazu
author_sort Lee Youngjun
collection DOAJ
description ZnO/Au is expected to exhibit catalytic properties by absorbing ultraviolet and visible light because ZnO and Au nanoparticles can absorb ultraviolet and visible light, respectively. Doping studies on Au nanoparticles on ZnO (ZnO/Au) have been conducted to expand the absorption wavelength range. This study generates ZnO/Au particles by an ultrasonic spray pyrolysis method (USP). To prevent particle aggregation, Triton X-100, a non-ionic surfactant, is added, and its effects are examined. The generated ZnO/Au particles are characterized using different methods. SEM reveals the particle size is several micrometers, while XRD analysis indicates that ZnO and a metallic Au crystalline are present. The TEM images of the particles show that the Au crystals are well dispersed in the inner and outer portions of ZnO. UV-Vis spectroscopy confirms that the smaller the Au particle size, the higher the visible absorption peak near 400 nm. Adding Triton X-100 shifts the absorption peak toward the longer wavelength side but improves the aggregation of Au particles.
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spelling doaj.art-d867bdc3aad14d79972a8d32c0a5be372022-12-21T22:25:11ZengEDP SciencesMATEC Web of Conferences2261-236X2021-01-013330201010.1051/matecconf/202133302010matecconf_apcche21_02010Formation and Evaluation of Au/ZnO Particles by a Spray Pyrolysis MethodLee Youngjun0Fujimoto Toshiyuki1Yamanaka Shinya2Kuga Yoshikazu3Division of Engineering, Muroran Institute of TechnologyCollege of Environmental Technology, Muroran Institute of TechnologyCollege of Environmental Technology, Muroran Institute of TechnologyMuroran Institute of TechnologyZnO/Au is expected to exhibit catalytic properties by absorbing ultraviolet and visible light because ZnO and Au nanoparticles can absorb ultraviolet and visible light, respectively. Doping studies on Au nanoparticles on ZnO (ZnO/Au) have been conducted to expand the absorption wavelength range. This study generates ZnO/Au particles by an ultrasonic spray pyrolysis method (USP). To prevent particle aggregation, Triton X-100, a non-ionic surfactant, is added, and its effects are examined. The generated ZnO/Au particles are characterized using different methods. SEM reveals the particle size is several micrometers, while XRD analysis indicates that ZnO and a metallic Au crystalline are present. The TEM images of the particles show that the Au crystals are well dispersed in the inner and outer portions of ZnO. UV-Vis spectroscopy confirms that the smaller the Au particle size, the higher the visible absorption peak near 400 nm. Adding Triton X-100 shifts the absorption peak toward the longer wavelength side but improves the aggregation of Au particles.https://www.matec-conferences.org/articles/matecconf/pdf/2021/02/matecconf_apcche21_02010.pdf
spellingShingle Lee Youngjun
Fujimoto Toshiyuki
Yamanaka Shinya
Kuga Yoshikazu
Formation and Evaluation of Au/ZnO Particles by a Spray Pyrolysis Method
MATEC Web of Conferences
title Formation and Evaluation of Au/ZnO Particles by a Spray Pyrolysis Method
title_full Formation and Evaluation of Au/ZnO Particles by a Spray Pyrolysis Method
title_fullStr Formation and Evaluation of Au/ZnO Particles by a Spray Pyrolysis Method
title_full_unstemmed Formation and Evaluation of Au/ZnO Particles by a Spray Pyrolysis Method
title_short Formation and Evaluation of Au/ZnO Particles by a Spray Pyrolysis Method
title_sort formation and evaluation of au zno particles by a spray pyrolysis method
url https://www.matec-conferences.org/articles/matecconf/pdf/2021/02/matecconf_apcche21_02010.pdf
work_keys_str_mv AT leeyoungjun formationandevaluationofauznoparticlesbyaspraypyrolysismethod
AT fujimototoshiyuki formationandevaluationofauznoparticlesbyaspraypyrolysismethod
AT yamanakashinya formationandevaluationofauznoparticlesbyaspraypyrolysismethod
AT kugayoshikazu formationandevaluationofauznoparticlesbyaspraypyrolysismethod