Bis(4-hydroxyphenyl) 1,4-phenylenebiscarbamate

The title compound, C20H16N2O6 (systematic name: 4-hydroxyphenyl N-{4-[(4-hydroxyphenoxycarbonyl)amino]phenyl}carbamate), contains two urethane groups substituting the central benzene ring in para positions. The molecule is centrosymmetric, and displays a twisted conformation for the three aromatic...

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Bibliographic Details
Main Authors: Isabel Martínez-de la Luz, Delia López-Velázquez, Sylvain Bernès, Jenaro L. Varela Caselis
Format: Article
Language:English
Published: International Union of Crystallography 2022-09-01
Series:IUCrData
Subjects:
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314622009191
Description
Summary:The title compound, C20H16N2O6 (systematic name: 4-hydroxyphenyl N-{4-[(4-hydroxyphenoxycarbonyl)amino]phenyl}carbamate), contains two urethane groups substituting the central benzene ring in para positions. The molecule is centrosymmetric, and displays a twisted conformation for the three aromatic rings [the dihedral angle between central benzene ring and the urethane group is 33.4 (6)°, and that between the latter and the terminal ring is 65.1 (1)°]. In the crystal, a three-dimensional framework is formed through O—H...O and N—H...O hydrogen bonds involving the hydroxy and urethane functional groups, respectively.
ISSN:2414-3146