6,6′-[(3,3′-Di-tert-butyl-5,5′-dimethoxy-1,1′-biphenyl-2,2′-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepine) benzene monosolvate
The crystal structure of the benzene monosolvate of the well known organic diphosphite ligand BIPHEPHOS, C46H44O8P2·C6H6, is reported for the first time. Single crystals of BIPHEPHOS were obtained from a benzene solution after layering with n-heptane at room temperature. One specific property of thi...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2019-12-01
|
| Series: | IUCrData |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314619016365 |
| _version_ | 1818554210019442688 |
|---|---|
| author | Benedict N. Leidecker Christoph Kubis Anke Spannenberg Robert Franke Armin Börner |
| author_facet | Benedict N. Leidecker Christoph Kubis Anke Spannenberg Robert Franke Armin Börner |
| author_sort | Benedict N. Leidecker |
| collection | DOAJ |
| description | The crystal structure of the benzene monosolvate of the well known organic diphosphite ligand BIPHEPHOS, C46H44O8P2·C6H6, is reported for the first time. Single crystals of BIPHEPHOS were obtained from a benzene solution after layering with n-heptane at room temperature. One specific property of this type of diphosphite structure is the twisting of the biphenyl units. In the crystal, C—H...π contacts and π–π stacking interactions [centroid-to-centroid distance = 3.8941 (15) Å] are observed. |
| first_indexed | 2024-12-12T09:36:22Z |
| format | Article |
| id | doaj.art-d872a59938114d3d89f4629f39f5f53e |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-12T09:36:22Z |
| publishDate | 2019-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-d872a59938114d3d89f4629f39f5f53e2022-12-22T00:28:43ZengInternational Union of CrystallographyIUCrData2414-31462019-12-01412x19163610.1107/S2414314619016365rz40356,6′-[(3,3′-Di-tert-butyl-5,5′-dimethoxy-1,1′-biphenyl-2,2′-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepine) benzene monosolvateBenedict N. Leidecker0Christoph Kubis1Anke Spannenberg2Robert Franke3Armin Börner4Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock, GermanyLeibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock, GermanyLeibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock, GermanyEvonik Performance Materials GmbH, Paul-Baumann-Str. 1, 45772 Marl, GermanyLeibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock, GermanyThe crystal structure of the benzene monosolvate of the well known organic diphosphite ligand BIPHEPHOS, C46H44O8P2·C6H6, is reported for the first time. Single crystals of BIPHEPHOS were obtained from a benzene solution after layering with n-heptane at room temperature. One specific property of this type of diphosphite structure is the twisting of the biphenyl units. In the crystal, C—H...π contacts and π–π stacking interactions [centroid-to-centroid distance = 3.8941 (15) Å] are observed.http://scripts.iucr.org/cgi-bin/paper?S2414314619016365crystal structurediphosphitebiphephosbiphenyl unit |
| spellingShingle | Benedict N. Leidecker Christoph Kubis Anke Spannenberg Robert Franke Armin Börner 6,6′-[(3,3′-Di-tert-butyl-5,5′-dimethoxy-1,1′-biphenyl-2,2′-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepine) benzene monosolvate IUCrData crystal structure diphosphite biphephos biphenyl unit |
| title | 6,6′-[(3,3′-Di-tert-butyl-5,5′-dimethoxy-1,1′-biphenyl-2,2′-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepine) benzene monosolvate |
| title_full | 6,6′-[(3,3′-Di-tert-butyl-5,5′-dimethoxy-1,1′-biphenyl-2,2′-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepine) benzene monosolvate |
| title_fullStr | 6,6′-[(3,3′-Di-tert-butyl-5,5′-dimethoxy-1,1′-biphenyl-2,2′-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepine) benzene monosolvate |
| title_full_unstemmed | 6,6′-[(3,3′-Di-tert-butyl-5,5′-dimethoxy-1,1′-biphenyl-2,2′-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepine) benzene monosolvate |
| title_short | 6,6′-[(3,3′-Di-tert-butyl-5,5′-dimethoxy-1,1′-biphenyl-2,2′-diyl)bis(oxy)]bis(dibenzo[d,f][1,3,2]dioxaphosphepine) benzene monosolvate |
| title_sort | 6 6 3 3 di tert butyl 5 5 dimethoxy 1 1 biphenyl 2 2 diyl bis oxy bis dibenzo d f 1 3 2 dioxaphosphepine benzene monosolvate |
| topic | crystal structure diphosphite biphephos biphenyl unit |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314619016365 |
| work_keys_str_mv | AT benedictnleidecker 6633ditertbutyl55dimethoxy11biphenyl22diylbisoxybisdibenzodf132dioxaphosphepinebenzenemonosolvate AT christophkubis 6633ditertbutyl55dimethoxy11biphenyl22diylbisoxybisdibenzodf132dioxaphosphepinebenzenemonosolvate AT ankespannenberg 6633ditertbutyl55dimethoxy11biphenyl22diylbisoxybisdibenzodf132dioxaphosphepinebenzenemonosolvate AT robertfranke 6633ditertbutyl55dimethoxy11biphenyl22diylbisoxybisdibenzodf132dioxaphosphepinebenzenemonosolvate AT arminborner 6633ditertbutyl55dimethoxy11biphenyl22diylbisoxybisdibenzodf132dioxaphosphepinebenzenemonosolvate |