Carbon-dot confined in graphene-analogous boron nitride for enhanced oxidative desulfurization
As of late, graphene-like boron nitride (g-BN), has been created another schedule as aerobic catalysis, and have a profound effect on the key performance of the catalyst. In this paper, C-nanodots with low resistivity, were bounded through g-BN (C-dots/g-BN) to help electron versatility by a straigh...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2022-09-01
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| Series: | Arabian Journal of Chemistry |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S1878535222004002 |
| _version_ | 1811223954311872512 |
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| author | Toktam Pedram-rad Zarrin Es'haghi Ali Ahmadpour Malihe Samadi Kazemi Ali Akbar Mohammadi |
| author_facet | Toktam Pedram-rad Zarrin Es'haghi Ali Ahmadpour Malihe Samadi Kazemi Ali Akbar Mohammadi |
| author_sort | Toktam Pedram-rad |
| collection | DOAJ |
| description | As of late, graphene-like boron nitride (g-BN), has been created another schedule as aerobic catalysis, and have a profound effect on the key performance of the catalyst. In this paper, C-nanodots with low resistivity, were bounded through g-BN (C-dots/g-BN) to help electron versatility by a straight forward one-pot pathway. C-dots were bounded in graphene-analogous boron nitride (g-BN) via a one-step, in situ process at increased temperature, which could upgrade the interactions of C-dots and control the dimensions of C-dots in the scope of nearly 4–5 nm. The results demonstrated that C-dots/g-BN has a superior execution in high-impact oxidation of dibenzothiophene (DBT) in fuel oil with a reactant movement of 93.5%. Estimation showed that hydroxyl radicals produced from H2O2 as a result of the interaction with C-dots ended up a proficient catalyst in the framework. The C-dots had a synergetic impact to enhance the proficiency of H2O2 in the catalyst. The portrayal results showed that piece of the DBT was oxidized to its comparing sulfoxide which requires less oxidant than sulfone. Both of the oxidation items could be extracted in the oil phase on the catalyst. |
| first_indexed | 2024-04-12T08:41:06Z |
| format | Article |
| id | doaj.art-d8786f8d6510414f87bdaa5393556792 |
| institution | Directory Open Access Journal |
| issn | 1878-5352 |
| language | English |
| last_indexed | 2024-04-12T08:41:06Z |
| publishDate | 2022-09-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Arabian Journal of Chemistry |
| spelling | doaj.art-d8786f8d6510414f87bdaa53935567922022-12-22T03:39:53ZengElsevierArabian Journal of Chemistry1878-53522022-09-01159104084Carbon-dot confined in graphene-analogous boron nitride for enhanced oxidative desulfurizationToktam Pedram-rad0Zarrin Es'haghi1Ali Ahmadpour2Malihe Samadi Kazemi3Ali Akbar Mohammadi4Department of Chemistry, Payame Noor University (PNU), 19395-4697, IranDepartment of Chemistry, Payame Noor University (PNU), 19395-4697, Iran; Corresponding authors.Department of Chemical Engineering, Faculty of Engineering, Ferdowsi University of Mashhad, IranDepartment of Chemistry, Faculty of Sciences, Bojnourd Branch, Islamic Azad University, Bojnourd, IranDepartment of Environmental Health Engineering, Neyshabur University of Medical Sciences, Neyshabur, IranAs of late, graphene-like boron nitride (g-BN), has been created another schedule as aerobic catalysis, and have a profound effect on the key performance of the catalyst. In this paper, C-nanodots with low resistivity, were bounded through g-BN (C-dots/g-BN) to help electron versatility by a straight forward one-pot pathway. C-dots were bounded in graphene-analogous boron nitride (g-BN) via a one-step, in situ process at increased temperature, which could upgrade the interactions of C-dots and control the dimensions of C-dots in the scope of nearly 4–5 nm. The results demonstrated that C-dots/g-BN has a superior execution in high-impact oxidation of dibenzothiophene (DBT) in fuel oil with a reactant movement of 93.5%. Estimation showed that hydroxyl radicals produced from H2O2 as a result of the interaction with C-dots ended up a proficient catalyst in the framework. The C-dots had a synergetic impact to enhance the proficiency of H2O2 in the catalyst. The portrayal results showed that piece of the DBT was oxidized to its comparing sulfoxide which requires less oxidant than sulfone. Both of the oxidation items could be extracted in the oil phase on the catalyst.http://www.sciencedirect.com/science/article/pii/S1878535222004002Graphene-like boron nitrideC-nanodotDibenzothiopheneFuel oil |
| spellingShingle | Toktam Pedram-rad Zarrin Es'haghi Ali Ahmadpour Malihe Samadi Kazemi Ali Akbar Mohammadi Carbon-dot confined in graphene-analogous boron nitride for enhanced oxidative desulfurization Arabian Journal of Chemistry Graphene-like boron nitride C-nanodot Dibenzothiophene Fuel oil |
| title | Carbon-dot confined in graphene-analogous boron nitride for enhanced oxidative desulfurization |
| title_full | Carbon-dot confined in graphene-analogous boron nitride for enhanced oxidative desulfurization |
| title_fullStr | Carbon-dot confined in graphene-analogous boron nitride for enhanced oxidative desulfurization |
| title_full_unstemmed | Carbon-dot confined in graphene-analogous boron nitride for enhanced oxidative desulfurization |
| title_short | Carbon-dot confined in graphene-analogous boron nitride for enhanced oxidative desulfurization |
| title_sort | carbon dot confined in graphene analogous boron nitride for enhanced oxidative desulfurization |
| topic | Graphene-like boron nitride C-nanodot Dibenzothiophene Fuel oil |
| url | http://www.sciencedirect.com/science/article/pii/S1878535222004002 |
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