Growth and Spectroscopy of Yb:YMgB<sub>5</sub>O<sub>10</sub> Crystal
A transparent Yb:YMgB<sub>5</sub>O<sub>10</sub> single crystal with dimensions up to 25 × 23 × 25 mm and weight 10.337 g was grown using a high-temperature solution growth on dipped seeds technique with a K<sub>2</sub>Mo<sub>3</sub>O<sub>10</s...
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MDPI AG
2022-07-01
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| author | Konstantin N. Gorbachenya Anatol S. Yasukevich Andrey I. Lazarchuk Victor E. Kisel Nikolay V. Kuleshov Elena A. Volkova Victor V. Maltsev Elizaveta V. Koporulina Vasiliy O. Yapaskurt Nikolai N. Kuzmin Dmitry A. Ksenofontov Diana D. Mitina Anna I. Jiliaeva |
| author_facet | Konstantin N. Gorbachenya Anatol S. Yasukevich Andrey I. Lazarchuk Victor E. Kisel Nikolay V. Kuleshov Elena A. Volkova Victor V. Maltsev Elizaveta V. Koporulina Vasiliy O. Yapaskurt Nikolai N. Kuzmin Dmitry A. Ksenofontov Diana D. Mitina Anna I. Jiliaeva |
| author_sort | Konstantin N. Gorbachenya |
| collection | DOAJ |
| description | A transparent Yb:YMgB<sub>5</sub>O<sub>10</sub> single crystal with dimensions up to 25 × 23 × 25 mm and weight 10.337 g was grown using a high-temperature solution growth on dipped seeds technique with a K<sub>2</sub>Mo<sub>3</sub>O<sub>10</sub> solvent. The Yb<sup>3+</sup> concentration was calculated to be 4.7 at.% (<i>N<sub>Yb</sub></i> = 3.71 × 10<sup>20</sup> atoms/cm<sup>3</sup>) with a distribution coefficient <i>K<sub>d</sub></i> of 0.59. The grown crystal was characterized by means of PXRD, TGA-DSC and ATR-FTIR techniques. The spectroscopic characteristics of the Yb:YMgB<sub>5</sub>O<sub>10</sub> crystal were demonstrated. Absorption cross-section spectra were produced. The luminescence spectra of the Yb:YMgB<sub>5</sub>O<sub>10</sub> crystal were measured in the spectral range of 950–1100 nm. The luminescence kinetics of the <sup>2</sup>F<sub>5/2</sub> energy level were investigated and the lifetime was determined. |
| first_indexed | 2024-03-09T12:03:10Z |
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| institution | Directory Open Access Journal |
| issn | 2073-4352 |
| language | English |
| last_indexed | 2024-03-09T12:03:10Z |
| publishDate | 2022-07-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Crystals |
| spelling | doaj.art-d882ed8e403d4a9aa2f5ad3ba66e60ea2023-11-30T23:01:38ZengMDPI AGCrystals2073-43522022-07-0112798610.3390/cryst12070986Growth and Spectroscopy of Yb:YMgB<sub>5</sub>O<sub>10</sub> CrystalKonstantin N. Gorbachenya0Anatol S. Yasukevich1Andrey I. Lazarchuk2Victor E. Kisel3Nikolay V. Kuleshov4Elena A. Volkova5Victor V. Maltsev6Elizaveta V. Koporulina7Vasiliy O. Yapaskurt8Nikolai N. Kuzmin9Dmitry A. Ksenofontov10Diana D. Mitina11Anna I. Jiliaeva12Center for Optical Materials and Technologies, Belarusian National Technical University, Nezalezhnasti Ave., 65, 220013 Minsk, BelarusCenter for Optical Materials and Technologies, Belarusian National Technical University, Nezalezhnasti Ave., 65, 220013 Minsk, BelarusCenter for Optical Materials and Technologies, Belarusian National Technical University, Nezalezhnasti Ave., 65, 220013 Minsk, BelarusCenter for Optical Materials and Technologies, Belarusian National Technical University, Nezalezhnasti Ave., 65, 220013 Minsk, BelarusCenter for Optical Materials and Technologies, Belarusian National Technical University, Nezalezhnasti Ave., 65, 220013 Minsk, BelarusDepartment of Crystallography and Crystal Chemistry, Faculty of Geology, Moscow State University, 119234 Moscow, RussiaDepartment of Crystallography and Crystal Chemistry, Faculty of Geology, Moscow State University, 119234 Moscow, RussiaDepartment of Crystallography and Crystal Chemistry, Faculty of Geology, Moscow State University, 119234 Moscow, RussiaLaboratory of Local Methods for the Study of Matter, Faculty of Geology, Moscow State University, 119234 Moscow, RussiaDepartment of Crystallography and Crystal Chemistry, Faculty of Geology, Moscow State University, 119234 Moscow, RussiaDepartment of Crystallography and Crystal Chemistry, Faculty of Geology, Moscow State University, 119234 Moscow, RussiaDepartment of Crystallography and Crystal Chemistry, Faculty of Geology, Moscow State University, 119234 Moscow, RussiaDepartment of Crystallography and Crystal Chemistry, Faculty of Geology, Moscow State University, 119234 Moscow, RussiaA transparent Yb:YMgB<sub>5</sub>O<sub>10</sub> single crystal with dimensions up to 25 × 23 × 25 mm and weight 10.337 g was grown using a high-temperature solution growth on dipped seeds technique with a K<sub>2</sub>Mo<sub>3</sub>O<sub>10</sub> solvent. The Yb<sup>3+</sup> concentration was calculated to be 4.7 at.% (<i>N<sub>Yb</sub></i> = 3.71 × 10<sup>20</sup> atoms/cm<sup>3</sup>) with a distribution coefficient <i>K<sub>d</sub></i> of 0.59. The grown crystal was characterized by means of PXRD, TGA-DSC and ATR-FTIR techniques. The spectroscopic characteristics of the Yb:YMgB<sub>5</sub>O<sub>10</sub> crystal were demonstrated. Absorption cross-section spectra were produced. The luminescence spectra of the Yb:YMgB<sub>5</sub>O<sub>10</sub> crystal were measured in the spectral range of 950–1100 nm. The luminescence kinetics of the <sup>2</sup>F<sub>5/2</sub> energy level were investigated and the lifetime was determined.https://www.mdpi.com/2073-4352/12/7/986ytterbiumspectroscopyrare-earth pentaborateflux growthATR-FTIR spectroscopy |
| spellingShingle | Konstantin N. Gorbachenya Anatol S. Yasukevich Andrey I. Lazarchuk Victor E. Kisel Nikolay V. Kuleshov Elena A. Volkova Victor V. Maltsev Elizaveta V. Koporulina Vasiliy O. Yapaskurt Nikolai N. Kuzmin Dmitry A. Ksenofontov Diana D. Mitina Anna I. Jiliaeva Growth and Spectroscopy of Yb:YMgB<sub>5</sub>O<sub>10</sub> Crystal Crystals ytterbium spectroscopy rare-earth pentaborate flux growth ATR-FTIR spectroscopy |
| title | Growth and Spectroscopy of Yb:YMgB<sub>5</sub>O<sub>10</sub> Crystal |
| title_full | Growth and Spectroscopy of Yb:YMgB<sub>5</sub>O<sub>10</sub> Crystal |
| title_fullStr | Growth and Spectroscopy of Yb:YMgB<sub>5</sub>O<sub>10</sub> Crystal |
| title_full_unstemmed | Growth and Spectroscopy of Yb:YMgB<sub>5</sub>O<sub>10</sub> Crystal |
| title_short | Growth and Spectroscopy of Yb:YMgB<sub>5</sub>O<sub>10</sub> Crystal |
| title_sort | growth and spectroscopy of yb ymgb sub 5 sub o sub 10 sub crystal |
| topic | ytterbium spectroscopy rare-earth pentaborate flux growth ATR-FTIR spectroscopy |
| url | https://www.mdpi.com/2073-4352/12/7/986 |
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