Observation of the Specific Heat Jump in the Se-Substituted MoTe<sub>2</sub> Single Crystals

1T’-MoTe<sub>2</sub> has gained considerable attention owing to its topological character. This material undergoes spatial inversion symmetry at 300 K. A structural transition to the T<sub>d</sub> phase, which is represented by a kink in the resistivity, was observed below 25...

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Main Authors: Aoi Kobayashi, Yoshiki Takano, Satoshi Demura
Format: Article
Language:English
Published: MDPI AG 2022-05-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/15/11/3782
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author Aoi Kobayashi
Yoshiki Takano
Satoshi Demura
author_facet Aoi Kobayashi
Yoshiki Takano
Satoshi Demura
author_sort Aoi Kobayashi
collection DOAJ
description 1T’-MoTe<sub>2</sub> has gained considerable attention owing to its topological character. This material undergoes spatial inversion symmetry at 300 K. A structural transition to the T<sub>d</sub> phase, which is represented by a kink in the resistivity, was observed below 250 K without inversion symmetry along the <i>c</i>-axis, while superconductivity was observed at 0.1 K. Substitution of Se into this material suppressed the appearance of the kink structure and increased the superconducting transition temperature to 2 K, which is consistent with previously reported results on polycrystalline samples. However, a specific heat jump was observed in the obtained single crystals, which did not exhibit kink structures in their resistivity. The results suggest that the T<sub>d</sub> structure was not suppressed entirely after Se substitution and that superconductivity was achieved without inversion symmetry.
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spelling doaj.art-d885c17343e44855af62828c11ad90a52023-11-23T14:20:10ZengMDPI AGMaterials1996-19442022-05-011511378210.3390/ma15113782Observation of the Specific Heat Jump in the Se-Substituted MoTe<sub>2</sub> Single CrystalsAoi Kobayashi0Yoshiki Takano1Satoshi Demura2College of Science and Technology, Nihon University, Chiyoda-ku, Tokyo 101-8308, JapanCollege of Science and Technology, Nihon University, Chiyoda-ku, Tokyo 101-8308, JapanCollege of Science and Technology, Nihon University, Chiyoda-ku, Tokyo 101-8308, Japan1T’-MoTe<sub>2</sub> has gained considerable attention owing to its topological character. This material undergoes spatial inversion symmetry at 300 K. A structural transition to the T<sub>d</sub> phase, which is represented by a kink in the resistivity, was observed below 250 K without inversion symmetry along the <i>c</i>-axis, while superconductivity was observed at 0.1 K. Substitution of Se into this material suppressed the appearance of the kink structure and increased the superconducting transition temperature to 2 K, which is consistent with previously reported results on polycrystalline samples. However, a specific heat jump was observed in the obtained single crystals, which did not exhibit kink structures in their resistivity. The results suggest that the T<sub>d</sub> structure was not suppressed entirely after Se substitution and that superconductivity was achieved without inversion symmetry.https://www.mdpi.com/1996-1944/15/11/3782superconductivitytransition metal chalcogenidestransport properties
spellingShingle Aoi Kobayashi
Yoshiki Takano
Satoshi Demura
Observation of the Specific Heat Jump in the Se-Substituted MoTe<sub>2</sub> Single Crystals
Materials
superconductivity
transition metal chalcogenides
transport properties
title Observation of the Specific Heat Jump in the Se-Substituted MoTe<sub>2</sub> Single Crystals
title_full Observation of the Specific Heat Jump in the Se-Substituted MoTe<sub>2</sub> Single Crystals
title_fullStr Observation of the Specific Heat Jump in the Se-Substituted MoTe<sub>2</sub> Single Crystals
title_full_unstemmed Observation of the Specific Heat Jump in the Se-Substituted MoTe<sub>2</sub> Single Crystals
title_short Observation of the Specific Heat Jump in the Se-Substituted MoTe<sub>2</sub> Single Crystals
title_sort observation of the specific heat jump in the se substituted mote sub 2 sub single crystals
topic superconductivity
transition metal chalcogenides
transport properties
url https://www.mdpi.com/1996-1944/15/11/3782
work_keys_str_mv AT aoikobayashi observationofthespecificheatjumpinthesesubstitutedmotesub2subsinglecrystals
AT yoshikitakano observationofthespecificheatjumpinthesesubstitutedmotesub2subsinglecrystals
AT satoshidemura observationofthespecificheatjumpinthesesubstitutedmotesub2subsinglecrystals