1,4-Diazoniabicyclo[2.2.2]octane bis(2-chlorobenzoate)
The title compound, C6H14N22+·2C7H4ClO2−, contains trimeric units linked by N—H...O hydrogen bonds. The carboxylate groups of the 2-chlorobenzoate anions form dihedral angles of 66.1 (1) and 76.1 (1)° with the respective chlorobenzene rings t...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808020096 |
| _version_ | 1818083211843993600 |
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| author | Signe Skovsgaard Andrew D. Bond |
| author_facet | Signe Skovsgaard Andrew D. Bond |
| author_sort | Signe Skovsgaard |
| collection | DOAJ |
| description | The title compound, C6H14N22+·2C7H4ClO2−, contains trimeric units linked by N—H...O hydrogen bonds. The carboxylate groups of the 2-chlorobenzoate anions form dihedral angles of 66.1 (1) and 76.1 (1)° with the respective chlorobenzene rings to which they are bound. The hydrogen-bonded trimers are arranged in layers in the (200) planes and the chlorobenzoate anions form edge-to-face interactions between layers, with dihedral angles of 61.9 (1) and 49.8 (1)° and centroid–centroid distances of 4.85 (1) and 4.65 (1) Å, respectively, for two crystallographically distinct interactions. |
| first_indexed | 2024-12-10T19:34:24Z |
| format | Article |
| id | doaj.art-d88ad4ffde684086a39aa3df94db6c5f |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T19:34:24Z |
| publishDate | 2008-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-d88ad4ffde684086a39aa3df94db6c5f2022-12-22T01:36:10ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-08-01648o1416o141610.1107/S16005368080200961,4-Diazoniabicyclo[2.2.2]octane bis(2-chlorobenzoate)Signe SkovsgaardAndrew D. BondThe title compound, C6H14N22+·2C7H4ClO2−, contains trimeric units linked by N—H...O hydrogen bonds. The carboxylate groups of the 2-chlorobenzoate anions form dihedral angles of 66.1 (1) and 76.1 (1)° with the respective chlorobenzene rings to which they are bound. The hydrogen-bonded trimers are arranged in layers in the (200) planes and the chlorobenzoate anions form edge-to-face interactions between layers, with dihedral angles of 61.9 (1) and 49.8 (1)° and centroid–centroid distances of 4.85 (1) and 4.65 (1) Å, respectively, for two crystallographically distinct interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536808020096 |
| spellingShingle | Signe Skovsgaard Andrew D. Bond 1,4-Diazoniabicyclo[2.2.2]octane bis(2-chlorobenzoate) Acta Crystallographica Section E |
| title | 1,4-Diazoniabicyclo[2.2.2]octane bis(2-chlorobenzoate) |
| title_full | 1,4-Diazoniabicyclo[2.2.2]octane bis(2-chlorobenzoate) |
| title_fullStr | 1,4-Diazoniabicyclo[2.2.2]octane bis(2-chlorobenzoate) |
| title_full_unstemmed | 1,4-Diazoniabicyclo[2.2.2]octane bis(2-chlorobenzoate) |
| title_short | 1,4-Diazoniabicyclo[2.2.2]octane bis(2-chlorobenzoate) |
| title_sort | 1 4 diazoniabicyclo 2 2 2 octane bis 2 chlorobenzoate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808020096 |
| work_keys_str_mv | AT signeskovsgaard 14diazoniabicyclo222octanebis2chlorobenzoate AT andrewdbond 14diazoniabicyclo222octanebis2chlorobenzoate |