In Situ Ruthenium Catalyst Modification for the Conversion of Furfural to 1,2-Pentanediol
Exploiting biomass to synthesise compounds that may replace fossil-based ones is of high interest in order to reduce dependence on non-renewable resources. 1,2-pentanediol and 1,5-pentanediol can be produced from furfural, furfuryl alcohol or tetrahydrofurfuryl alcohol following a metal catalysed hy...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2022-01-01
|
| Series: | Nanomaterials |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2079-4991/12/3/328 |
| _version_ | 1797485921828864000 |
|---|---|
| author | Lauriane Bruna Miquel Cardona-Farreny Vincent Colliere Karine Philippot M. Rosa Axet |
| author_facet | Lauriane Bruna Miquel Cardona-Farreny Vincent Colliere Karine Philippot M. Rosa Axet |
| author_sort | Lauriane Bruna |
| collection | DOAJ |
| description | Exploiting biomass to synthesise compounds that may replace fossil-based ones is of high interest in order to reduce dependence on non-renewable resources. 1,2-pentanediol and 1,5-pentanediol can be produced from furfural, furfuryl alcohol or tetrahydrofurfuryl alcohol following a metal catalysed hydrogenation/C-O cleavage procedure. Colloidal ruthenium nanoparticles stabilized with polyvinylpyrrolidone in situ modified with different organic compounds are able to produce 1,2-pentanediol directly from furfural in a 36% of selectivity at 125 °C under 20 bar of H<sub>2</sub> pressure. |
| first_indexed | 2024-03-09T23:25:46Z |
| format | Article |
| id | doaj.art-d8912635fa964531b0fe17c0ce6489d2 |
| institution | Directory Open Access Journal |
| issn | 2079-4991 |
| language | English |
| last_indexed | 2024-03-09T23:25:46Z |
| publishDate | 2022-01-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Nanomaterials |
| spelling | doaj.art-d8912635fa964531b0fe17c0ce6489d22023-11-23T17:18:57ZengMDPI AGNanomaterials2079-49912022-01-0112332810.3390/nano12030328In Situ Ruthenium Catalyst Modification for the Conversion of Furfural to 1,2-PentanediolLauriane Bruna0Miquel Cardona-Farreny1Vincent Colliere2Karine Philippot3M. Rosa Axet4CNRS, LCC (Laboratoire de Chimie de Coordination), Université de Toulouse, UPS, INPT, 205 Route de Narbonne, CEDEX 04, 31077 Toulouse, FranceCNRS, LCC (Laboratoire de Chimie de Coordination), Université de Toulouse, UPS, INPT, 205 Route de Narbonne, CEDEX 04, 31077 Toulouse, FranceCNRS, LCC (Laboratoire de Chimie de Coordination), Université de Toulouse, UPS, INPT, 205 Route de Narbonne, CEDEX 04, 31077 Toulouse, FranceCNRS, LCC (Laboratoire de Chimie de Coordination), Université de Toulouse, UPS, INPT, 205 Route de Narbonne, CEDEX 04, 31077 Toulouse, FranceCNRS, LCC (Laboratoire de Chimie de Coordination), Université de Toulouse, UPS, INPT, 205 Route de Narbonne, CEDEX 04, 31077 Toulouse, FranceExploiting biomass to synthesise compounds that may replace fossil-based ones is of high interest in order to reduce dependence on non-renewable resources. 1,2-pentanediol and 1,5-pentanediol can be produced from furfural, furfuryl alcohol or tetrahydrofurfuryl alcohol following a metal catalysed hydrogenation/C-O cleavage procedure. Colloidal ruthenium nanoparticles stabilized with polyvinylpyrrolidone in situ modified with different organic compounds are able to produce 1,2-pentanediol directly from furfural in a 36% of selectivity at 125 °C under 20 bar of H<sub>2</sub> pressure.https://www.mdpi.com/2079-4991/12/3/328nanocatalysisrutheniumfurfuralbiomasspentanediol |
| spellingShingle | Lauriane Bruna Miquel Cardona-Farreny Vincent Colliere Karine Philippot M. Rosa Axet In Situ Ruthenium Catalyst Modification for the Conversion of Furfural to 1,2-Pentanediol Nanomaterials nanocatalysis ruthenium furfural biomass pentanediol |
| title | In Situ Ruthenium Catalyst Modification for the Conversion of Furfural to 1,2-Pentanediol |
| title_full | In Situ Ruthenium Catalyst Modification for the Conversion of Furfural to 1,2-Pentanediol |
| title_fullStr | In Situ Ruthenium Catalyst Modification for the Conversion of Furfural to 1,2-Pentanediol |
| title_full_unstemmed | In Situ Ruthenium Catalyst Modification for the Conversion of Furfural to 1,2-Pentanediol |
| title_short | In Situ Ruthenium Catalyst Modification for the Conversion of Furfural to 1,2-Pentanediol |
| title_sort | in situ ruthenium catalyst modification for the conversion of furfural to 1 2 pentanediol |
| topic | nanocatalysis ruthenium furfural biomass pentanediol |
| url | https://www.mdpi.com/2079-4991/12/3/328 |
| work_keys_str_mv | AT laurianebruna insiturutheniumcatalystmodificationfortheconversionoffurfuralto12pentanediol AT miquelcardonafarreny insiturutheniumcatalystmodificationfortheconversionoffurfuralto12pentanediol AT vincentcolliere insiturutheniumcatalystmodificationfortheconversionoffurfuralto12pentanediol AT karinephilippot insiturutheniumcatalystmodificationfortheconversionoffurfuralto12pentanediol AT mrosaaxet insiturutheniumcatalystmodificationfortheconversionoffurfuralto12pentanediol |